CsI(T1) scintillator crystal including co-dopants antiomy and bismuth to reduce afterglow, and a radiation detection apparatus including the scintillation crystal
A scintillation crystal can include a cesium halide that is co-doped with thallium and another element. In an embodiment, the scintillation crystal can include CsI:Tl, Me, where Me represents co-doped Sb and Bi. In a particular embodiment, the scintillation crystal may have a cesium iodide host material, a first dopant including a thallium, a second dopant including an antimony, and a third dopant including a bismuth.
1. A scintillator crystal comprising:
a cesium iodide host material;
a first dopant comprising a thallium, a molar concentration of said first dopant being less than 10%;
a second dopant comprising an antimony, wherein a concentration of the second dopant in the scintillator crystal is greater than 0.02 ppm and no greater than 1.3 ppm; and
a third dopant comprising bismuth, wherein a concentration of the third dopant in the scintillator crystal is greater than 0.027 ppm and no greater than 5.2 ppm, wherein the scintillator crystal has a reduced afterglow below 0.1% at 100 ms, and wherein an absolute light output is greater than 55000 ph/MeV.
2. The scintillator crystal of claim 1 , wherein the absolute light output of the scintillator crystal is greater than 55300 ph/MeV.
3. The scintillator crystal of claim 1 , wherein the absolute light output of the scintillator crystal is greater than 55400 ph/MeV.
4. The scintillator crystal of claim 1 , wherein the absolute light output of the scintillator crystal is greater than 55500 ph/MeV.
5. The scintillator crystal of claim 1 , wherein the reduced afterglow of the scintillator crystal is below 0.09% at 100 ms.
6. The scintillator crystal of claim 1 , wherein the reduced afterglow of the scintillator crystal is below 0.08% at 100 ms.
7. A scintillator crystal comprising:
a cesium iodide host material;
a first dopant comprising a thallium, a molar concentration of said first dopant being less than 10%;
a second dopant comprising an antimony, wherein a concentration of the second dopant in the scintillator crystal is greater than 0.02 ppm and no greater than 1.3 ppm; and
a third dopant comprising bismuth, wherein a concentration of the third dopant in the scintillator crystal is greater than 0.027 ppm and no greater than 5.2 ppm, wherein the scintillator crystal has a reduced afterglow below 0.2% at 500 ms, and wherein a absolute light output is greater than 55000 ph/MeV.
8. The scintillator crystal of claim 7 , wherein the reduced afterglow of the scintillator crystal is below 0.05% at 500 ms.
9. The scintillator crystal of claim 7 , wherein the reduced afterglow of the scintillator crystal is below 0.07% at 500 ms.
10. The scintillator crystal of claim 7 , wherein the reduced afterglow of the scintillator crystal is below 0.09% at 500 ms.
11. The scintillator crystal of claim 7 , wherein the reduced afterglow of the scintillator crystal is below 0.1% at 500 ms.
12. The scintillator crystal of claim 7 , wherein the second dopant comprises trivalent antimony and the third dopant comprises trivalent bismuth.
13. The scintillator crystal of claim 7 , wherein the second dopant comprises pentavalent antimony and the third dopant comprises pentavalent bismuth.
14. A radiation detection apparatus comprising:
a housing; and
a scintillator within the housing, the scintillator comprising:
a cesium iodide host material;
a first dopant comprising a thallium, a molar concentration of said first dopant being less than 10%; and
a second dopant comprising an antimony, wherein a concentration of the second dopant in the scintillator crystal is greater than 0.02 ppm and no greater than 1.3 ppm; and
a third dopant comprising bismuth, wherein a concentration of the third dopant in the scintillator crystal is greater than 0.027 ppm and no greater than 5.2 ppm, wherein the scintillator crystal has a reduced afterglow below 0.1% at 100 ms, and wherein h absolute light output is greater than 55000 ph/MeV.
15. The radiation detection apparatus of claim 14 , wherein the radiation detection apparatus is capable of inspecting more than 300 bags per hour during an X-ray irradiation.
16. The radiation detection apparatus of claim 14 , wherein the radiation detection apparatus is capable of inspecting more than I 000 bags per hour during a Computed tomography irradiation.
17. The radiation detection apparatus of claim 14 , wherein the afterglow in the scintillator crystal is reduced by at least 83% as compared to an un-doped scintillator crystal.
18. The radiation detection apparatus of claim 14 , wherein the afterglow in the scintillator crystal is reduced by at least 90% as compared to an un-doped scintillator crystal.
19. The radiation detection apparatus of claim 14 , wherein the afterglow in the scintillator crystal is reduced by at least 92% as compared to an un-doped scintillator crystal.
20. The radiation detection apparatus of claim 14 , wherein the radiation detection apparatus is one of a Single Photon Emission Computer Tomography (SPECT) apparatus, a Positron Emission Tomography (PET) apparatus, an x-ray imaging apparatus, and an oil well-logging detector.