Granted Patent B2

US 12,444,324 · App. 18/183,311 · Granted Oct 14, 2025

Inventors: Douglas Barnhardt (West Chester, OH); Barron G. McKillip (Batavia, OH); Stephen Riccardi (York, PA); Floyd Needham (Loveland, OH); A. Craig Bushman (Loveland, OH)

Assignee: Multi-Color Corporation

G09F3/10B32B7/06B32B7/12B32B27/08B32B27/10B32B27/16B32B27/30B32B27/308B32B27/32B32B27/36B32B27/38B32B27/40B32B2250/242B32B2307/4023B32B2307/748B32B2307/75B32B2405/00B32B2519/00G09F2003/0202G09F2003/0225G09F2003/023G09F2003/0257Y10T428/2839Y10T428/2848

Abstract

Claims (28)

1. A pressure sensitive label comprising:

(a) a support portion, said support portion including at least a carrier layer; and

(b) a transfer portion over said support portion for transfer of the transfer portion to an article while the transfer portion is in contact with the article, said transfer portion including at least: (i) a printable layer in contacting relationship with the carrier layer, and (ii) an ink layer positioned such that said printable layer is between said carrier layer and said ink layer, wherein the printable layer includes about 30 wt % to about 50 wt % of a triacrylate ester monomer, about 10 wt % to about 12.5 wt % of a diacrylate ester monomer, about 10 wt % to about 12.5 wt % of an aromatic urethane acrylate, about 10 wt % to about 12.5 wt % of a difunctional acrylate, about 5 wt % to about 7 wt % of an acrylate oligomer, about 3 wt % to about 5 wt % of triethanolamine, and about 1 wt % to about 2 wt % of 4-phenylbenzophenone.

2. The pressure sensitive label of claim 1 , further comprising an adhesive layer positioned such that said ink layer is between said printable layer and said adhesive layer.

3. The pressure sensitive label of claim 1 , further comprising a release layer positioned such that said carrier layer is between said printable layer and said release layer.

4. The pressure sensitive label of claim 1 , wherein the carrier layer has a surface tension that allows the printable layer to releasably bond thereto.

5. The pressure sensitive label of claim 4 , wherein the surface of the carrier layer that contacts the printable layer has a dyne level below about 32.

6. The pressure sensitive label of claim 4 , wherein the carrier layer comprises polypropylene.

7. The pressure sensitive label of claim 1 , wherein the carrier layer is chosen from plastic film, foil, parchment, and paper.

8. The pressure sensitive label of claim 1 , wherein the ink layer comprises about 25 wt % to about 35 wt % ethanol, about 20 wt % to about 25 wt % propylene glycol methyl ether, about 15 wt % to about 20 wt % propyl acetate, about 15 wt % to about 20 wt % isopropanol, and about 3 wt % to about 5 wt % aluminum flake.

9. The pressure sensitive label of claim 2 , wherein the adhesive layer comprises about 37.5 wt % to about 80 wt % acrylate, and about 2.5 wt % to about 10 wt % of a photoinitiator.

10. The pressure sensitive label of claim 3 , wherein the release layer comprises dimethyl siloxane and silicone.

11. The pressure sensitive label of claim 1 , wherein said label does not include any release layer between said carrier layer and said printable layer.

12. The pressure sensitive label of claim 1 , wherein said ink layer is UV curable.

13. The pressure sensitive label of claim 1 , wherein the printable layer is water-based or UV-curable.

14. A pressure sensitive label comprising:

(a) a support portion, said support portion including at least a carrier layer; and

(b) a transfer portion over said support portion for transfer of the transfer portion to an article while the transfer portion is in contact with the article, said transfer portion including at least:

(i) a printable layer in contacting relationship with the carrier layer,

(ii) one or more ink layers positioned such that said printable layer is between said carrier layer and said one or more ink layers; and

(iii) an adhesive layer;

wherein all ink layers of the pressure sensitive label are positioned between the printable layer and the adhesive layer, wherein the printable layer includes about 30 wt % to about 50 wt % of a triacrylate ester monomer, about 10 wt % to about 12.5 wt % of a diacrylate ester monomer, about 10 wt % to about 12.5 wt % of an aromatic urethane acrylate, about 10 wt % to about 12.5 wt % of a difunctional acrylate, about 5 wt % to about 7 wt % of an acrylate oligomer, about 3 wt % to about 5 wt % of triethanolamine, and about 1 wt % to about 2 wt % of 4-phenylbenzophenone.

15. A pressure sensitive label comprising:

(a) a support portion, said support portion including at least a carrier layer; and

(b) a transfer portion over said support portion for transfer of the transfer portion to an article while the transfer portion is in contact with the article, said transfer portion including at least:

(i) a printable layer in contacting relationship with the carrier layer, and

(ii) one or more ink layers positioned such that said printable layer is between said carrier layer and said one or more ink layers; and

wherein the printable layer includes about 30 wt % to about 50 wt % of a triacrylate ester monomer, about 10 wt % to about 12.5 wt % of a diacrylate ester monomer, about 10 wt % to about 12.5 wt % of an aromatic urethane acrylate, about 10 wt % to about 12.5 wt % of a difunctional acrylate, about 5 wt % to about 7 wt % of an acrylate oligomer, about 3 wt % to about 5 wt % of triethanolamine, and about 1 wt % to about 2 wt % of 4-phenylbenzophenone.

Assignments (5)

Continuity (7)

References Cited (86)