IP Library Granted Patent US 12,347,852
Granted Patent B2
US 12,347,852 · App. 18/183,417 · Granted Jul 1, 2025

Zinc alloy electrodes for lithium batteries

Inventors: Jonathan T. Goodman (Evanston, IL); Yong Shi (Oakville, CA)
Assignee: Li-Metal Corp.
H01M4/382H01M4/0404H01M4/0421H01M4/0471H01M4/134H01M4/1395H01M4/661H01M4/662H01M4/667H01M4/668H01M2004/027
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Quick Facts
Patent No.
US 12,347,852
App. No.
18/183,417
Granted
Jul 1, 2025
Kind
B2
Abstract

Zinc containing electrodes and anodes, processes for their production, and cells including said electrodes and anodes are disclosed. The electrodes and anodes can include zinc adjacent to a copper current collector and carrying lithium metal. Processes include the deposition of zinc and then lithium onto the current collector and the electrochemical products include the electrodes and anodes in a lithium-metal cell.

Claims (10)

1. A lithium metal anode comprising:

a copper current collector carrying and metallurgically affixed to a brass interlayer that includes zinc and copper; and

a ternary interlayer disposed between the brass interlayer and a lithium metal layer, wherein the brass interlayer is free of lithium and the ternary interlayer includes lithium, copper, and zinc,

wherein the brass interlayer includes a zinc to copper ratio of about 1:4 to about 4:1;

wherein the brass interlayer includes a diffusion composition of zinc and copper that has a zinc concentration that increases from adjacent to the copper current collector toward the lithium metal layer and a copper concentration that decreases from adjacent to the copper current collector toward the lithium metal layer; and

wherein the ternary interlayer has a thickness of about 10 nm to about 2 μm.

2. The lithium metal anode of claim 1 , wherein the brass interlayer has a thickness of about 10 nm to about 2 μm.

3. The lithium metal anode of claim 1 , wherein the zinc to copper ratio is about 2:3 to about 3:2.

4. The lithium metal anode of claim 3 , wherein the zinc to copper ratio is about 1:1.

5. The lithium metal anode of claim 1 , wherein the lithium metal layer has a thickness of about 2.5 μm to about 100 μm.

Assignments (1)
CHANGE OF NAME Recorded Dec 22, 2025
From: LI-METAL CORP.
To: SKYCAP INVESTMENT HOLDINGS INC.
Reel/Frame 074041/0627 →
Continuity (2)
Provisional Application 63429435 · Dec 1, 2022
Related Publication 20240186496A1 · Jun 6, 2024
References Cited (174)
US 5053297A · Yamahira · 1991 [cited by applicant]
US 5067990A · Ribitch · 1991 [cited by applicant]
US 5080932A · Koksbang · 1992 [cited by applicant]
US 5518839A · Olsen · 1996 [cited by applicant]
US 5522955A · Brodd · 1996 [cited by applicant]
US 5846675A · Sazhin · 1998 [cited by applicant]
US 6025094A · Visco · 2000 [cited by applicant]
US 6214061B1 · Visco · 2001 [cited by applicant]
US 6402795B1 · Chu · 2002 [cited by applicant]
US 6430031B1 · Dispennette · 2002 [cited by applicant]
US 6713216B2 · Kugai · 2004 [cited by applicant]
US 6844113B2 · Yagi · 2005 [cited by examiner]
US 6991662B2 · Visco · 2006 [cited by applicant]
US 7390591B2 · Visco · 2008 [cited by applicant]
US 7811705B2 · Scott · 2010 [cited by applicant]
US 8133374B2 · Takezawa · 2012 [cited by applicant]
US 8221915B2 · Tikhonov · 2012 [cited by applicant]
US 8282806B2 · Fuhrmann · 2012 [cited by applicant]
US 8821969B2 · He · 2014 [cited by applicant]
US 9315680B2 · Uemura · 2016 [cited by applicant]
US 9418796B2 · Yoshimura · 2016 [cited by applicant]
US 10177366B2 · Swonger · 2019 [cited by applicant]
US 10541406B1 · Teeters · 2020 [cited by applicant]
US 10593988B2 · Xiao · 2020 [cited by applicant]
US 10862129B2 · Pan · 2020 [cited by applicant]
US 10862171B2 · Visco · 2020 [cited by applicant]
US 11214882B2 · Kaczmarek et al. · 2022 [cited by applicant]
US 20020177044A1 · Yagi · 2002 [cited by applicant]
US 20040219432A1 · Kojima · 2004 [cited by applicant]
US 20060019168A1 · Li · 2006 [cited by applicant]
US 20060137168A1 · Futscher · 2006 [cited by applicant]
US 20100266898A1 · Yamamoto · 2010 [cited by applicant]
US 20110177398A1 · Affinito · 2011 [cited by applicant]
US 20110300290A1 · Kim · 2011 [cited by applicant]
US 20130095380A1 · Affinito · 2013 [cited by applicant]
US 20140011072A1 · Leuthner · 2014 [cited by applicant]
US 20140015453A1 · Leuthner · 2014 [cited by applicant]
US 20160181594A1 · Balogh · 2016 [cited by applicant]
US 20160233549A1 · Tiruvannamalai · 2016 [cited by applicant]
US 20170263935A1 · Kozen · 2017 [cited by applicant]
US 20170365854A1 · Gopalakrishnannair · 2017 [cited by applicant]
US 20170373321A1 · Skotheim · 2017 [cited by applicant]
US 20180005767A1 · Divigalpitiya · 2018 [cited by applicant]
US 20180371632A1 · Bodoin · 2018 [cited by applicant]
US 20190013516A1 · Herle · 2019 [cited by applicant]
US 20190048483A1 · Swonger · 2019 [cited by applicant]
US 20190058198A1 · Fan · 2019 [cited by applicant]
US 20190088987A1 · Herle · 2019 [cited by applicant]
US 20190140267A1 · Gopalakrishnan Nair · 2019 [cited by applicant]
US 20190173090A1 · Liang · 2019 [cited by applicant]
US 20190190000A1 · Herle · 2019 [cited by applicant]
US 20190379056A1 · Chen · 2019 [cited by applicant]
US 20200127293A1 · Son · 2020 [cited by applicant]
US 20200194786A1 · Wang · 2020 [cited by applicant]
US 20200280104A1 · Son · 2020 [cited by applicant]
US 20210194058A1 · Sekiya · 2021 [cited by applicant]
US 20220216482A1 · Jastrzebski · 2022 [cited by applicant]
US 20220328803A1 · Herle · 2022 [cited by applicant]
US 20240243264A1 · Jastrzebski · 2024 [cited by applicant]
CN 109742323 · 2018 [cited by applicant]
CN 109390548 · 2019 [cited by applicant]
CN 109727779 · 2019 [cited by applicant]
CN 20200280104 · 2019 [cited by applicant]
EP 0690517 · 1996 [cited by applicant]
JP 1987053569 · 1987 [cited by applicant]
JP H04206275 · 1992 [cited by applicant]
JP H09298066 · 1997 [cited by applicant]
JP 2797390 · 1998 [cited by applicant]
JP 2002203593 · 2002 [cited by applicant]
JP 2005063978 · 2005 [cited by applicant]
JP 2011089160 · 2011 [cited by applicant]
JP 2011258913 · 2011 [cited by applicant]
JP 2012059484 · 2012 [cited by applicant]
JP 2020530183 · 2020 [cited by applicant]
KR 20100127983 · 2010 [cited by applicant]
WO 2005001157 · 2005 [cited by applicant]
WO 2012076328 · 2012 [cited by applicant]
WO 2017138361 · 2017 [cited by applicant]
WO 2017196892 · 2017 [cited by applicant]
WO 2018193993 · 2018 [cited by applicant]
WO 2019246095A1 · 2019 [cited by applicant]
WO 2020210913 · 2020 [cited by applicant]
WO 2021080052 · 2021 [cited by applicant]
WO 2022077120 · 2022 [cited by applicant]
WO 2022241538 · 2022 [cited by applicant]
Itoh, Satoshi et al. (1977). Electrocrystallization of various metals onto copper single crystal substrates. Surface Technology, 5(1), 27-42. [cited by applicant]
Popov, K. I., Keca, D. N., &; Andjelic, M. D. (1978). Electrodeposition of zinc on copper from alkaline zincate solutions. Journal of Applied Electrochemistry, 8(1), 19-23. [cited by applicant]
Chu, M. G., McBreen, J., &; Adzic, G. (1981). Substrate effects on zinc deposition from zincate solutions: I. deposition on Cu, Au, CD and Zn. Journal of The Electrochemical Society, 128(11), 2281-2286. [cited by applicant]
Grier, D., Ben-Jacob, E., Clarke, R., &; Sander, L. M. (1986). Morphology and microstructure in electrochemical deposition of zinc. Physical Review Letters, 56(12), 1264-1267. [cited by applicant]
Kadlec, S., &; Musil, J. (1996). Low pressure magnetron sputtering and selfsputtering discharges. Vacuum, 47(3), 307-311. [cited by applicant]
Nakamura, I., Fujitani, T., Uchijima, T., &; Nakamura, J. (1996). A model catalyst for Methanol Synthesis: Zn-deposited and Zn-free Cu Surfaces. Journal of Vacuum Science Technology A: Vacuum, Surfaces, and Films, 14(3)… [cited by applicant]
Chaliampalias, D., Papazoglou, M., Tsipas, S., Pavlidou, E., Skolianos, S., Stergioudis, G., &; Vourlias, G. (2011). Fabrication and examination of oxidation resistance of zinc coated copper and brass components by chem… [cited by applicant]
Okamoto, H. (2012). Li—Zn (lithium-zinc). Journal of Phase Equilibria and Diffusion, 33(4), 345-345. [cited by applicant]
Fahlteich, John, Amberg-Schwab, Sabine., Weber, Ulrike., Noller, Klaus., Miesbauer, Oliver., Boeffel, Christine., &; Schiller, Nicolas. (2013). 29.1: Ultra-high barriers for encapsulation of flexible displays and lighti… [cited by applicant]
Cazzaniga, Andrea., Ettlinger, Rebecca Bolt., Canulescu, Stela., Schou, Jørge. N., &; Pryds, Nini. (2014). Nanosecond laser ablation and deposition of silver, copper, zinc and tin. Applied Physics A, 117(1), 89-92. [cited by applicant]
Yan, Z., Wang, E., Jiang, L., &; Sun, G. (2015). Superior cycling stability and high rate capability of three-dimensional Zn/CU foam electrodes for zinc-based alkaline batteries. RSC Advances, 5(102), 83781-83787. [cited by applicant]
Bhaskar, Srilakshmi. P., &; Jagirdar, Balajir. (2017). A journey from bulk brass to nanobrass: A comprehensive study showing structural evolution of various Cu/Zn bimetallic nanophases from the vaporization of brass. Jo… [cited by applicant]
Mueller, Franziska., Geiger, Dorin., Kaiser, Ute., Passerini, Stefano., &; Bresser, Dominic. (2016). Elucidating the impact of cobalt doping on the lithium storage mechanism in conversion/alloying-type zinc oxide anodes… [cited by applicant]
Muench, Simon., Wild, Andreas., Friebe, Christian., Haupler, Bernhard., Janoschka, Tobias., &; Schubert, Ulrich S. (2016). Polymer-based organic batteries. Chemical Reviews, 116(16), 9438-9484. [cited by applicant]
Fahlteich, John., Steiner, Cindy., Schiller, Nicolas., Miesbauer, Oliver., Noller, Klaus., Deichmann, Karl.-Joachim., Mirza, Mark., &; Amberg-Schwab, Sabine. (2017). Roll-to-roll thin film coating on fluoropolymer webs—… [cited by applicant]
Yan, Kai., Lu, Zhenda., Lee, H. Yun.-Wook., Xiong, Feng., Hsu, Po.-Chun., Li, Yuzhang., Zhao, Jie., Chu, Steven., &; Cui, Yi. (2016). Selective deposition and stable encapsulation of lithium through heterogeneous seeded… [cited by applicant]
Liu, S., Zhang, X., Li, R., Gao, L., &; Luo, J. (2018). Dendrite-free li metal anode by lowering deposition interface energy with CU99ZN alloy coating. Energy Storage Materials, 14, 143-148. [cited by applicant]
Genovese, Matthew., Louli, A. J., Weber, Rochelle., Sanderson, R. J., Johnson, M. B., &; Dahn, J. R. (2018). Combinatorial methods for improving lithium metal cycling efficiency. Journal of The Electrochemical Society, … [cited by applicant]
Xu, Kangli., Zhu, Maogen., Wu, Xun., Liang, Jianwen., Liu, Yun., Zhang, Tianwen., Zhu, Yongchun., &; Qian, Y. (2019). Dendrite-tamed deposition kinetics using single-atom zn sites for Li Metal anode. Energy Storage Mate… [cited by applicant]
Wang, Gang., Xiong, X., Zou, P., Fu, X., Lin, Z., Li, Y., Liu, Y., Yang, C., &; Liu, M. (2019). Lithiated zinc oxide hanorod arrays on copper current collectors for robust Li metal anodes. Chemical Engineering Journal, … [cited by applicant]
Zhang, N., Yu, S.-H., &; Abruna, H. D. (2019). Regulating lithium nucleation and growth by zinc modified current collectors. Nano Research, 13(1), 45-51. [cited by applicant]
Qian, Y., Meng, C., He, J., &; Dong, X. (2020). A lightweight 3D zn@cu nanosheets@activated carbon cloth as long-life anode with large capacity for flexible zinc ion batteries. Journal of Power Sources, 480, 228871. [cited by applicant]
Lu, S., Wang, Z., Yan, H., Wang, R., Lu, K., Cheng, Y., Qin, W., &; Wu, X. (2020). High rate and cycling stable Li metal anodes enabled with aluminum-zinc oxides modified copper foam. Journal of Energy Chemistry, 41, 87… [cited by applicant]
Li, Z., Shi, Z.-Z., Hao, Y., Li, H.-F., Zhang, H.-J., Liu, X.-F., &; Wang, L.-N. (2020). Insight into role and mechanism of Li on the key aspects of biodegradable Zn Li alloys: Microstructure Evolution, mechanical prope… [cited by applicant]
Zhang, D., Dai, A., Wu, M., Shen, K., Xiao, T., Hou, G., Lu, J., &; Tang, Y. (2019). Lithiophilic 3D porous CuZn current collector for stable lithium metal batteries. ACS Energy Letters, 5(1), 180-186. [cited by applicant]
Chi, S.-S., Wang, Q., Han, B., Luo, C., Jiang, Y., Wang, J., Wang, C., Yu, Y., &; Deng, Y. (2020). Lithiophilic zn sites in porous CuZn alloy induced uniform li nucleation and dendrite-free li metal deposition. Nano Let… [cited by applicant]
Zhou, B., Bonakdarpour, A., Stosevski, I., Fang, B., &; Wilkinson, D. P. (2022). Modification of cu current collectors for Lithium Metal Batteries—A Review. Progress in Materials Science, 130, 100996. [cited by applicant]
Zheng Z. J., Ye, H., &; Guo, Z. P. (2020). Recent progress in designing stable composite lithium anodes with mproved wettability. Advanced Science, 7(22), 2002212. [cited by applicant]
Yamada, M., Watanabe, T., Gunji, T., Wu, J., &; Matsumoto, F. (2020). Review of the design of current collectors for improving the battery performance in lithium-ion and Post-Lithium-Ion Batteries. Electrochem, 1(2), 12… [cited by applicant]
Fayette, M., Chang, H. J., Rodriguez-Perez Ismael A., Li, X., &; Reed, D. (2020). Electrodeposited zinc-based films as anodes for aqueous zinc batteries. ACS Applied Materials &; Interfaces, 12(38), 42763-42772. [cited by applicant]
Zhu, P., Gastol, D., Marshall, J., Sommerville, R., Goodship, V., &; Kendrick, E. (2021). A review of current collectors for lithium-ion batteries. Journal of Power Sources, 485, 229321. [cited by applicant]
Chen, Q., Li, H., Meyerson, M. L., Rodriguez, R., Kawashima, K., Weeks, J. A., Sun, H., Xie, Q., Lin, J., Henkelman, G., Heller, A., Peng, D.-L., &; Mullins, C. B. (2021). Li-zn overlayer to facilitate uniform lithium d… [cited by applicant]
Liu, Y., Gao, D., Xiang, H., Feng, X., &; Yu, Y. (2021). Research progress on copper-based current collector for lithium metal batteries. Energy Fuels, 35(16), 12921-12937. [cited by applicant]
Li, D., Hu, H., Chen, B., &; Lai, W. Y. (2022). Advanced current collector materials for high-performance lithium metal anodes. Small, 18(24), 2200010. [cited by applicant]
Yuan, H., Ding, X., Liu, T., Nai, J., Wang, Y., Liu, Y., Liu, C., &; Tao, X. (2022). A review of concepts and contributions in lithium metal anode development. Materials Today, 53, 173-196. [cited by applicant]
Jeong, H., Jang, J., &; Jo, C. (2022). A review on current collector coating methods for next-generation batteries. Chemical Engineering Journal, 446, 136860. [cited by applicant]
Joshi, B., Samuel, E., Kim, Y.-Il, Yarin, A. L., Swihart, M. T., &; Yoon, S. S. (2022). Progress and potential of electrospinning-derived substrate-free and binder-free lithium-ion battery electrodes. Chemical Engineeri… [cited by applicant]
Office Action issued for U.S. Appl. No. 18/055,706 on Mar. 23, 2023. [cited by applicant]
Fan, Z. et al. (2022) “Long-cycling all-solid-state batteries achieved by 2D interface between prelithiated aluminum foil anode and sulfide electrolyte,” Small, 18(44), p. 2204037. [cited by applicant]
Crowley, P. J., et al. (2022) “Diffusional lithium trapping as a failure mechanism of aluminum foil anodes in lithium-ion batteries,” Journal of Power Sources, 546, p. 231973. [cited by applicant]
Zheng T. et al. (2022) “Aluminum foil anodes for Li-ion rechargeable batteries: The role of Li solubility within β-lial,” ACS Sustainable Chemistry Engineering, 10(10), pp. 3203-3210. [cited by applicant]
Li D. et al. (2022) “Single-material aluminum foil as anodes enabling high-performance lithium-ion batteries: The roles of prelithiation and working mechanism,” Materials Today, 58, pp. 80-90. [cited by applicant]
Final Office Action issued for U.S. Appl. No. 18/055,706 on Jul. 14, 2023. [cited by applicant]
Pham, M. T. M., et al. (2021) “Prevention of lithium-ion battery thermal runaway using polymer-substrate current collectors” Cell Reports Physical Science, 2(3), 100360. https://doi.org/10.1016/j.xcrp.2021.100360. [cited by applicant]
Allen, J. (2020). Review of polymers in the prevention of thermal runaway in lithium-ion batteries. Energy Reports, 6, 217-224. https://doi.org/10.1016/j.egyr.2020.03.027. [cited by applicant]
Choi, B. N., et al. (2020) “Electro-deposition of the lithium metal anode on dendritic copper current collectors for lithium battery application” Applied Surface Science, 506, 144884. https://doi.org/10.1016/j.apsusc.20… [cited by applicant]
Fritsch, M., et al. (2020) “Lightweight polymer-carbon composite current collector for lithium-ion batteries”, Batteries, 6 (4), 60. https://doi.org/10.3390/batteries6040060. [cited by applicant]
Cho, E.-C., et al. (2021) “Modification of aluminum current collectors with laser-scribed graphene for enhancing the performance of Lithium Ion Batteries” Journal of Power Sources, 506, 230060. https://doi.org/10.1016/j… [cited by applicant]
Zhou, Y., Wang, et al. (2019) “Recent advances in fiber-shaped supercapacitors and lithium—Ion Batteries” Advanced Materials, 32(5), 1902779 https://doi.org/10.1002/adma.201902779. [cited by applicant]
Whitehead, A. H., et al. (2005) “Current collectors for positive electrodes of lithium-based batteries” Journal of The Electrochemical Society, 152(11). https://doi.org/10.1149/1.2039587. [cited by applicant]
Yun, J. H., et al. (2011) “Low resistance flexible current collector for Lithium Secondary Battery. Electrochemical and Solid-State Letters” 14(8). https://doi.org/10.1149/1.3596721. [cited by applicant]
Choudhury, R., et al. (2021) “Engineering current collectors for batteries with high specific energy,” Joule, 5(6), pp. 1301-1305. [cited by applicant]
Ye, Y. et al. (2020) “Ultralight and fire-extinguishing current collectors for high-energy and high-safety lithium-ion batteries,” Nature Energy, 5(10), pp. 786-793. [cited by applicant]
Zhang, Y. et al. (2020) “Polyaniline/copper composite anode current collectors prepared through electrochemical polymerization for lithium—Ion Batteries,” ChemElectroChem, 7(13), pp. 2896-2904. Available at: https://doi… [cited by applicant]
Chen, L.L. et al. (2020) “Nonmetal current collectors: The key component for high-energy-density aluminum batteries,” Advanced Materials, 32(42), p. 2001212. Available at: https://doi.org/10.1002/adma.202001212. [cited by applicant]
Garcia, A. et al. (2011) “Localized ligand induced electroless plating (LIEP) process for the fabrication of copper patterns onto flexible polymer substrates,” Advanced Functional Materials, 21(11), pp. 2096-2102. Avail… [cited by applicant]
Non-final rejection issued for U.S. Appl. No. 18/055,715, mailed Mar. 15, 2023. [cited by applicant]
Final rejection issued for U.S. Appl. No. 18/055,715, mailed Jun. 28, 2023. [cited by applicant]
Hongli VVan, Jiaxun Zhang, et al. Salt-in-Salt Reinforced Carbonate Electrolyte for Li Metal Batteries; Sufu Liu+ , Jiale Xia+ , Weiran Zhang+ , ngew. Chem. nt. Ed. 2022, 61, e202210522. [cited by applicant]
Chen J. et al. (2021) “An Inorganic-Rich Solid Electrolyte Interphase for Advanced Lithium-Metal Batteries in Carbonate Electrolytes”; Sufu Liu+ , Xiao Ji+ , Nan Piao+ , . Chem. Int. Ed. 2021, 60, 3661-3671. [cited by applicant]
Ming Liu et al. (2019) “Efficient Li-metal plating/stripping in carbonate electrolytes using a LiNO3-gel polymer electrolyte, monitored by operando neutron depth profiling” Chem. Mater., Just Accepted Manuscript . Publi… [cited by applicant]
Weidong Zhang, et al.; (2020) Colossal Granular Lithium Deposits Enabled by the Grain-Coarsening Effect for High-Efficiency Lithium Metal Full Batteries; Adv. Mater., 2001740, DOI: 10.1002/adma.202001740. [cited by applicant]
Dongdong Liu et al.; An inorganic-rich SEI induced by LiNO3 additive for a stable lithium metal anode in carbonate electrolyte; Chem. Commun., 2021, 57, 9232. [cited by applicant]
Xinyang Nang et al.; Inhibiting Dendrite Growth via Regulating the Electrified Interface for Fast-Charging Lithium Metal Anode; ACS Cent. Sci. 2021, 7, 20292038. [cited by applicant]
Chong Yan et al.; Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries; Angew. Chem. Int. Ed. 2018, 57, 1-6, 1https://doi.org/10.1002/anie.201807034. [cited by applicant]
Aurbach, Doron, et al. “The electrochemical behaviour of 1, 3-dioxolane-LiCIO4 solutions-I. Uncontaminated solutions.” Electrochimica acta 35.3 (1990): 625-638. [cited by applicant]
Li, Weiyang, et al. “The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth.” Nature communications 6.1 (2015): 1-8. [cited by applicant]
Xu, Kang. “Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.” Chemical reviews 104.10 (2004): 4303-4418. [cited by applicant]
Liu, Yayuan, et al. “Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode.” Nature Communications 1 (2018) 9:3656 | DOI: 10.1038/s41467-018-06077-5. [cited by applicant]
Shi, Qiuwei, et al. “High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes.” Proceedings of the National Academy of Sciences 115.22 (2018): 5676-5680. [cited by applicant]
Zhang, Weidong, et al. “Colossal granular lithium deposits enabled by the grain-coarsening effect for high-efficiency lithium metal full batteries.” Advanced Materials 32.24 (2020): 2001740. [cited by applicant]
Li, Siyuan, et al. “Synergistic dual-additive electrolyte enables practical lithium-metal batteries.” Angewandte Chemie International Edition 59.35 (2020): 14935-14941. [cited by applicant]
Omenya, Fredrick, et al. “Intrinsic challenges to the electrochemical reversibility of the high energy density copper (II) fluoride cathode material.” ACS Applied Energy Materials 2.7 (2019): 5243-5253. [cited by applicant]
Alexander, G. V., Sreejith, O. V., Indu, M. S., &; Murugan, R. (2020). Interface-compatible and high-cyclability lithiophilic lithium-zinc alloy anodes for garnet-structured solid electrolytes. ACS Applied Energy Materi… [cited by applicant]
Office Action (Non-Final Rejection) dated Nov. 27, 2024 for U.S. Appl. No. 17/604,009 (pp. 1-10). [cited by applicant]
Office Action dated Sep. 10, 2024 for U.S. Appl. No. 18/183,417. [cited by applicant]
Written Opinion of the International Searching Authority for PCT/CA2022/050589, mailed Jul. 11, 2022. [cited by applicant]
Touja et al., “An Overview on Protecting Metal Anodes with Alloy-Type Coating”. Batteries and Supercops, Mar. 10, 2021 (Oct. 3, 2021), vol. vol. 8, Issue 8, pp. 1252-1266. *Sect. 1 Introduction; Sect. 2.2. Other Coating… [cited by applicant]
International Search Report and Written Opinion for corresponding PCT Application No. PCT/CA2021/051454, issued from the Canadian Intellectual Property Office on Jan. 25, 2022. [cited by applicant]
European Search Report Issued Oct. 11, 2023 in relation to EP20790420.2. [cited by applicant]
Supplemental European Search Report Issued Jan. 1, 2024 in relation to EP20790420.2. [cited by applicant]
European Search Opinion Issued Jan. 1, 2024 in relation to EP20790420.2. [cited by applicant]
International Search Report and Written Opinion for International application No. PCT/CA2020/050513 issued on Jun. 15, 2020, from the Canadian Intellectual Property Office. [cited by applicant]
Swisher, R., et al. “Progress in Vacuum Deposited Lithium Metal Anode Structures”, Mar. 5, 2001, 18th International Seminar & Exhibit on Primary and Secondary Batteries. [cited by applicant]
Examination Report issued on May 20, 2024 in Indian application 202127052644. [cited by applicant]
Office Action dated Jun. 4, 2024 for Japanese Application 2021-560734. [cited by applicant]
Written opinion of the international searching authority for PCT/CA2021/051454 issued Jan. 25, 2022. [cited by applicant]
Office action issued re: Chinese Application No. 20208003789739, mailed on Aug. 7, 2024. [cited by applicant]
Office Action dated Aug. 9, 2024 for Brazilian Application 11 2021 020579-9. [cited by applicant]