Organic electroluminescent compound and organic electroluminescent device comprising the same
The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent device with improved driving voltage and/or power efficiency can be provided by using the organic electroluminescent compound according to the present disclosure.
1 . An organic electroluminescent compound represented by the following formula 1-1:
wherein
L 1 and L 2 each independently represents a single bond, a substituted or unsubstituted (C6-C30)arylene or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
Ar 1 to Ar 4 each independently represent a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, or a substituted or unsubstituted fused ring of a (C3-C30)aliphatic ring(s) and a (C6-C30)aromatic ring(s);
R 1 and R 2 each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl or -L 3 -N—(Ar 5 )(Ar 6 );
R 7 represents hydrogen or deuterium;
L 3 each independently represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
Ar 5 and Ar 6 each independently represent a substituted or unsubstituted fused ring of a (C3-C30)aliphatic ring(s) and a (C6-C30)aromatic ring(s), a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl;
a is an integer of 1 to 4, b and c are 1 or 2, and when a, b and c are each an integer of 2 or more, each of R 1 , R 2 and R 7 may be the same or different from each other; and
when there are a plurality of substituents represented by the same symbol, each of the substituents represented by the same symbol may be the same or different from each other.
2 . The organic electroluminescent compound according to claim 1 , wherein the substituents of the substituted (C1-C30)alkyl, the substituted (C6-C30)aryl, the substituted (C6-C30)arylene, the substituted (3- to 30-membered)heteroaryl, the substituted (3- to 30-membered)heteroarylene and the substituted (C3-C30)cycloalkyl, substituted fused ring of a (C3-C30)aliphatic ring(s) and a (C6-C30)aromatic ring(s)
each independently, are at least one selected from the group consisting of
(1)deuterium; a halogen; a cyano; a carboxyl; a nitro; a hydroxyl; a phosphine oxide; a (C1-C30)alkyl; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl; a (C1-C30)alkoxy; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C3-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; and a (5- to 50-membered)heteroaryl, each of which is unsubstituted or substituted with at least one of a (C1-C30)alkyl(s), a (C6-C30)aryl(s), or a di(C6-C30)arylamino(s); and
(2) a (C6-C30)aryl which is unsubstituted or substituted with at least one of a (C1-C30)alkyl(s), and
(3) a (3- to 50-membered)heteroaryl(s), and a mono- or di-(C6-C30)arylamino(s); and
(4) a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl; a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; an amino; a mono- or di-(C1-C30)alkylamino; a mono- or di-(C2-C30)alkenylamino; and a mono- or di-(C6-C30)arylamino, each of which is unsubstituted or substituted with at least one of a (C1-C30)alkyl(s), a (5- to 30-membered)heteroaryl(s), or a di(C6-C30)arylamino(s); and
(5) a mono- or di-(3- to 30-membered)heteroarylamino; a (C1-C30)alkyl(C2-C30)alkenylamino; a (C1-C30)alkyl(C6-C30)arylamino; a (C1-C30)alkyl(3- to 30-membered)heteroarylamino; a (C2-C30)alkenyl(C6-C30)arylamino; a (C2-C30)alkenyl(3- to 30-membered)heteroarylamino; a (C6-C30)aryl(3- to 30-membered)heteroarylamino; a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl; a (C6-C30)arylphosphine; a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl.
3 . The organic electroluminescent compound according to claim 1 , wherein
L 1 and L 2 each independently represents a single bond, or a substituted or unsubstituted (C6-C12)arylene;
Ar 1 to Ar 4 each independently represent a substituted or unsubstituted (C6-C25)aryl, a substituted or unsubstituted (5- to 20-membered)heteroaryl, or a substituted or unsubstituted fused ring of a (C3-C10)aliphatic ring(s) and a (C6-C15)aromatic ring(s);
R 1 and R 2 each independently represent hydrogen, deuterium, a substituted or unsubstituted (C6-C15)aryl, a substituted or unsubstituted (5- to 15-membered)heteroaryl, or -L 3 -N—(Ar 5 )(Ar 6 );
R 7 represents hydrogen or deuterium;
L 3 each independently represents a single bond; and
Ar 5 and Ar 6 each independently represent a substituted or unsubstituted (C6-C12)aryl.
4 . The organic electroluminescent compound according to claim 1 , wherein
L 1 and L 2 each independently represents a single bond, or a substituted or unsubstituted (C6-C12)arylene;
Ar 1 to Ar 4 each independently represent a (C6-C25)aryl unsubstituted or substituted with at least one of a (C1-C6)alkyl(s) and a (C6-C12)aryl(s); a (5- to 20-membered)heteroaryl unsubstituted or substituted with at least one (C6-C12)aryl(s); or a fused ring of a (C3-C10)aliphatic ring(s) and a (C6-C15)aromatic ring(s) unsubstituted or substituted with at least one (C1-C6)alkyl(s);
R 1 and R 2 each independently represent hydrogen; a (C6-C15)aryl unsubstituted or substituted with at least one (C1-C6)alkyl(s); a (5- to 15-membered)heteroaryl unsubstituted or substituted with at least one (C6-C12)aryl(s); or -L 3 -N—(Ar 5 )(Ar 6 );
R 7 represents hydrogen;
L 3 each independently represents a single bond; and
Ar 5 and Ar 6 each independently represent an unsubstituted (C6-C12)aryl.
5 . The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1-1 is selected from the following compounds:
6 . An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .
7 . An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
8 . The organic electroluminescent device according to claim 7 , wherein the organic electroluminescent compound is comprised in a hole transport zone.