Granted Patent B2

US 12,623,959 · App. 18/209,152 · Granted May 12, 2026

Inventor: Andrew V. Wagner (Pittsburgh, PA)

Assignee: Vitro Flat Glass LLC

C03C17/36C03C17/3618C03C17/3644C03C17/3652C03C17/366C03C17/3681C03C17/3689Y10T428/2495Y10T428/265

Abstract

Claims (112)

1 . A coated transparency, comprising:

a. a first substrate having a No. 1 surface and a No. 2 surface;

b. a second substrate spaced from the first substrate, with a gas-filled gap between the first substrate and the second substrate, the second substrate having a No. 3 surface and a No. 4 surface, with the No. 3 surface facing the No. 2 surface; and

c. a coating formed over at least a portion of the No. 3 surface and defining a side of the gas-filled gap opposite the No. 2 surface, the coating comprising:

i. a first dielectric layer formed over at least a portion of the No. 3 surface;

ii. a continuous metallic layer formed over at least a portion of the first dielectric layer, the metallic layer having a thickness less than 8 nm;

iii. a primer layer formed over at least a portion of the metallic layer;

iv. a second dielectric layer formed over at least a portion of the primer layer; and

v. an overcoat formed over at least a portion of the second dielectric layer,

wherein the coated transparency has a solar heat gain coefficient greater than or equal to 0.6 and a heat transfer coefficient less than or equal to 0.35,

wherein the gas-gap is filled with air or a non-reactive gas, and

wherein the first dielectric layer comprises a first film and a second film, the second film in direct contact over at least a portion of the first film.

2 . The coated transparency of claim 1 , wherein the first film comprises zinc alloy oxide and wherein the second film comprises metal oxide; and wherein the first dielectric layer has a thickness in the range of 40 nm to 50 nm.

3 . The coated transparency of claim 1 , wherein the first film has a thickness in the range of 35 nm to 45 nm.

4 . The coated transparency of claim 1 , wherein the second film has a thickness in the range of 3 nm to 15 nm.

5 . The coated transparency of claim 1 , wherein the first film comprises zinc stannate and the second film comprises zinc oxide.

6 . The coated transparency of claim 1 , wherein the metallic layer comprises silver having a thickness less than or equal to 7.5 nm.

7 . The coated transparency of claim 1 , wherein the overcoat comprises titania and has a thickness in the range of less than or equal to 6 nm.

8 . The coated transparency of claim 1 , wherein the second dielectric layer comprises a first film and a second film, the second film in direct contact over at least a portion of the first film.

9 . The coated transparency of claim 8 , wherein the second dielectric layer has a thickness in the range of 30 nm to 40 nm.

10 . The coated transparency of claim 8 , the first film has a thickness in the range of 5 nm to 9 nm, and the second film has a thickness in the range of 26 nm to 32 nm.

11 . The coated transparency of claim 1 , wherein the second dielectric layer comprises a first film comprising zinc oxide and a second film comprising zinc stannate.

12 . The coated transparency of claim 1 , wherein the overcoat has a thickness in the range of 1-10 nm and the overcoat comprises titania.

13 . The coated transparency of claim 1 , wherein the second substrate is a glass substrate,

wherein the first dielectric layer has a thickness in the range of 40 nm to 50 nm, the second film has a thickness in the range of 3 nm to 15 nm, and the first film has a thickness in the range of 25 nm to 40 nm,

wherein the metallic layer comprises silver having a thickness less than or equal to 7.5 nm,

wherein the primer film comprises titanium,

wherein the second dielectric layer comprises a zinc oxide film and a zinc stannate film deposited over the zinc oxide film, the second dielectric layer has a thickness in the range of 30 nm to 40 nm, and the zinc oxide film has a thickness in the range of 3 nm to 15 nm,

wherein the overcoat has a thickness in the range of 2 nm to 6 nm and the overcoat comprises titania, and

wherein the solar heat gain coefficient is greater than or equal to 0.65 and the heat transfer coefficient is less than or equal to 0.33.

14 . The coated transparency of claim 1 , wherein the second substrate is a glass substrate,

wherein the first film comprises zinc stannate, and the second film comprises zinc oxide, wherein the first dielectric layer has a thickness in the range of 41 nm to 48 nm, the first film has a thickness in the range of 35 nm to 40 nm, and the second film has a thickness in the range of 6 nm to 8 nm,

wherein the metallic layer comprises silver having a thickness less than or equal to 7 nm,

wherein the primer film comprises titanium,

wherein the second dielectric layer comprises a first film comprising zinc oxide, a second film comprising zinc stannate, wherein the second dielectric layer has a thickness in the range of 28 nm to 40 nm, the first film has a thickness in the range of 3 nm to 5 nm, and the second film has a thickness in the range of 25 nm to 35 nm,

wherein the overcoat has a thickness in the range of 4 nm to 10 nm and the overcoat comprises titania, and

wherein the solar heat gain coefficient is greater than or equal to 0.65 and the heat transfer coefficient is less than or equal to 0.35.

15 . A coated transparency, comprising:

a. a first substrate having a No. 1 surface and a No. 2 surface;

b. a second substrate spaced from the first substrate, with a gas-filled gap between the first substrate and the second substrate, the second substrate having a No. 3 surface and a No. 4 surface, with the No. 3 surface facing the No. 2 surface; and

c. a coating formed over at least a portion of the No. 3 surface and defining a side of the gas-filled gap opposite the No. 2 surface, the coating comprising:

i. a first dielectric layer formed over at least a portion of the No. 3 surface;

ii. a continuous metallic layer formed over at least a portion of the first dielectric layer, the metallic layer having a thickness less than 8 nm;

iii. a primer layer formed over at least a portion of the metallic layer;

iv. a second dielectric layer formed over at least a portion of the primer layer; and

v. an overcoat formed over at least a portion of the second dielectric layer,

wherein the coated transparency has a solar heat gain coefficient greater than or equal to 0.6 and a heat transfer coefficient less than or equal to 0.35,

wherein the gas-gap is filled with air or a non-reactive gas,

wherein the first dielectric layer comprises a first film and a second film, and

wherein the first film comprises zinc stannate and the second film comprises zinc oxide.

16 . A coated transparency, comprising:

a. a first substrate having a No. 1 surface and a No. 2 surface;

b. a second substrate spaced from the first substrate, with a gas-filled gap between the first substrate and the second substrate, the second substrate having a No. 3 surface and a No. 4 surface, with the No. 3 surface facing the No. 2 surface; and

c. a coating formed over at least a portion of the No. 3 surface and defining a side of the gas-filled gap opposite the No. 2 surface, the coating comprising:

i. a first dielectric layer formed over at least a portion of the No. 3 surface;

ii. a continuous metallic layer formed over at least a portion of the first dielectric layer, the metallic layer having a thickness less than 8 nm;

iii. a primer layer formed over at least a portion of the metallic layer;

iv. a second dielectric layer formed over at least a portion of the primer layer; and

v. an overcoat formed over at least a portion of the second dielectric layer,

wherein the coated transparency has a solar heat gain coefficient greater than or equal to 0.6 and a heat transfer coefficient less than or equal to 0.35,

wherein the gas-gap is filled with air or a non-reactive gas, and

wherein the second dielectric layer comprises a first film and a second film, the second film in direct contact over at least a portion of the first film.

17 . A coated transparency, comprising:

a. a first substrate having a No. 1 surface and a No. 2 surface;

b. a second substrate spaced from the first substrate, with a gas-filled gap between the first substrate and the second substrate, the second substrate having a No. 3 surface and a No. 4 surface, with the No. 3 surface facing the No. 2 surface; and

c. a coating formed over at least a portion of the No. 3 surface and defining a side of the gas-filled gap opposite the No. 2 surface, the coating comprising:

i. a first dielectric layer formed over at least a portion of the No. 3 surface;

ii. a continuous metallic layer formed over at least a portion of the first dielectric layer, the metallic layer having a thickness less than 8 nm;

iii. a primer layer formed over at least a portion of the metallic layer;

iv. a second dielectric layer formed over at least a portion of the primer layer; and

v. an overcoat formed over at least a portion of the second dielectric layer,

wherein the coated transparency has a solar heat gain coefficient greater than or equal to 0.6 and a heat transfer coefficient less than or equal to 0.35,

wherein the gas-gap is filled with air or a non-reactive gas, and

wherein the second dielectric layer comprises a first film comprising zinc oxide and a second film comprising zinc stannate.

18 . A coated transparency, comprising:

a. a first substrate having a No. 1 surface and a No. 2 surface;

b. a second substrate spaced from the first substrate, with a gas-filled gap between the first substrate and the second substrate, the second substrate having a No. 3 surface and a No. 4 surface, with the No. 3 surface facing the No. 2 surface; and

c. a coating formed over at least a portion of the No. 3 surface and defining a side of the gas-filled gap opposite the No. 2 surface, the coating comprising:

i. a first dielectric layer formed over at least a portion of the No. 3 surface;

ii. a continuous metallic layer formed over at least a portion of the first dielectric layer, the metallic layer having a thickness less than 8 nm;

iii. a primer layer formed over at least a portion of the metallic layer;

iv. a second dielectric layer formed over at least a portion of the primer layer; and

v. an overcoat formed over at least a portion of the second dielectric layer,

wherein the coated transparency has a solar heat gain coefficient greater than or equal to 0.6 and a heat transfer coefficient less than or equal to 0.35,

wherein the gas-gap is filled with air or a non-reactive gas,

wherein the second substrate is a glass substrate,

wherein the first dielectric layer comprises a first film and a second film,

wherein the first dielectric layer has a thickness in the range of 40 nm to 50 nm, the second film has a thickness in the range of 3 nm to 15 nm, and the first film has a thickness in the range of 25 nm to 40 nm,

wherein the metallic layer comprises silver having a thickness less than or equal to 7.5 nm,

wherein the primer film comprises titanium,

wherein the second dielectric layer comprises a zinc oxide film and a zinc stannate film deposited over the zinc oxide film, the second dielectric layer has a thickness in the range of 30 nm to 40 nm, and the zinc oxide film has a thickness in the range of 3 nm to 15 nm,

wherein the overcoat has a thickness in the range of 2 nm to 6 nm and the overcoat comprises titania, and

wherein the solar heat gain coefficient is greater than or equal to 0.65 and the heat transfer coefficient is less than or equal to 0.33.

19 . A coated transparency, comprising:

a. a first substrate having a No. 1 surface and a No. 2 surface;

b. a second substrate spaced from the first substrate, with a gas-filled gap between the first substrate and the second substrate, the second substrate having a No. 3 surface and a No. 4 surface, with the No. 3 surface facing the No. 2 surface; and

c. a coating formed over at least a portion of the No. 3 surface and defining a side of the gas-filled gap opposite the No. 2 surface, the coating comprising:

i. a first dielectric layer formed over at least a portion of the No. 3 surface;

ii. a continuous metallic layer formed over at least a portion of the first dielectric layer, the metallic layer having a thickness less than 8 nm;

iii. a primer layer formed over at least a portion of the metallic layer;

iv. a second dielectric layer formed over at least a portion of the primer layer; and

v. an overcoat formed over at least a portion of the second dielectric layer,

wherein the coated transparency has a solar heat gain coefficient greater than or equal to 0.6 and a heat transfer coefficient less than or equal to 0.35,

wherein the gas-gap is filled with air or a non-reactive gas,

wherein the second substrate is a glass substrate,

wherein the first dielectric layer comprises a first film and a second film,

wherein the first film comprises zinc stannate, and the second film comprises zinc oxide, wherein the first dielectric layer has a thickness in the range of 41 nm to 48 nm, the first film has a thickness in the range of 35 nm to 40 nm, and the second film has a thickness in the range of 6 nm to 8 nm,

wherein the metallic layer comprises silver having a thickness less than or equal to 7 nm,

wherein the primer film comprises titanium,

wherein the second dielectric layer comprises a first film comprising zinc oxide, a second film comprising zinc stannate, wherein the second dielectric layer has a thickness in the range of 28 nm to 40 nm, the first film has a thickness in the range of 3 nm to 5 nm, and the second film has a thickness in the range of 25 nm to 35 nm,

wherein the overcoat has a thickness in the range of 4 nm to 10 nm and the overcoat comprises titania, and

wherein the solar heat gain coefficient is greater than or equal to 0.65 and the heat transfer coefficient is less than or equal to 0.35.

Assignments (1)

Continuity (4)

References Cited (44)