PIGMENTABLE NON-ASPHALTIC SEALANT COMPOSITIONS AND METHODS FOR IMPROVED LOW TEMPERATURE PROPERTIES
A pigmentable non-asphaltic composition for use as a sealant for cracks and joints in pavement surfaces, and for other purposes, and a method of forming the composition wherein (a) the composition comprises a non-asphaltic base blend which uses one or more tree rosin esters and (b) the low temperature properties of the composition, such as ductility and flexural creep stiffness, are enhanced by incorporating distilled tall oil and/or other low temperature property enhancing additives.
1 . A non-asphaltic composition for use as a hot-applied sealant, or for pavement markings, or for use as a binder for aggregates for filling potholes and road repairs, the non-asphaltic composition comprising:
a non-asphaltic base blend which includes
one or more processing oils in a total amount in a range of from 5% to 35% by weight based on a total weight of the non-asphaltic composition,
one or more plasticizers in a total amount in a range of from 0.5% to 6% by weight based on the total weight of the non-asphaltic composition, and
one or more tree rosin esters in a total amount in a range of from 25% to 80% by weight based on the total weight of the non-asphaltic composition and
a low temperature property enhancing additive which (i) is incorporated when and/or after the non-asphaltic base blend is formed, (ii) is selected from a distilled tall oil, a distilled tall oil blend, one or more vegetable oils, or a combination thereof, and (iii) is included in the non-asphaltic composition in a total amount, in a range of from 1% to 25% by weight based on the total weight of the non-asphaltic composition, which increases a 4° C. ductility and decreases a flexural creep stiffness of the non-asphaltic composition.
2 . The non-asphaltic composition of claim 1 further comprising the total amount of the low temperature property enhancing additive also increasing a resilience and reducing a viscosity of the non-asphaltic composition.
3 . The non-asphaltic composition of claim 2 further comprising the total amount of the low temperature property enhancing additive (i) not reducing a softening point of the non-asphaltic composition below 79° C., (ii) maintaining the softening point of the non-asphaltic composition at a value of 80° C. or greater, or (iii) increasing the softening point of the non-asphaltic composition.
4 . The non-asphaltic composition of claim 1 further comprising:
a total of from 1% to 25% by weight, based on the total weight of the non-asphaltic composition, of one or more color neutralizing materials which at least partially neutralize a non-white shade or color of the non-asphaltic base blend and
a total of from 0.1% to 6% by weight, based on the total weight of the non-asphaltic composition, of one or more pigment materials which impart a non-white color or shade to the non-asphaltic composition.
5 . The non-asphaltic composition of claim 4 further comprising:
the one or more color neutralizing materials comprising titanium dioxide and
the one or more pigment materials comprising Gilsonite which imparts a gray color to the non-asphaltic composition.
6 . The non-asphaltic composition of claim 1 further comprising a total of from 2% to 20% by weight, based on the total weight of the non-asphaltic composition, of one or more elastomeric polymer materials.
7 . The non-asphaltic composition of claim 1 further comprising the low temperature property enhancing additive being the distilled tall oil or the distilled tall oil blend.
8 . The non-asphaltic composition of claim 7 further comprising the low temperature property enhancing additive, which is the distilled tall oil or the distilled tall oil blend, comprising (i) one or more rosin acids in a total amount of from 10% to 50% by weight based on a total weight of the distilled tall oil or the distilled tall oil blend and (ii) one or more fatty acids in a total amount of from 60% to 90% by weight based on the total weight of the distilled tall oil or the distilled tall oil blend.
9 . The non-asphaltic composition of claim 8 further comprising:
the one or more rosin acids comprising abietic acid and/or pimaric acid and
the one or more fatty acids comprising palmitic acid, stearic acid, oleic acid, linoleic acid, and/or linolenic acid.
10 . The non-asphaltic composition of claim 8 further comprising:
the one or more rosin acids including each of abietic acid and pimaric acid and
the one or more fatty acids including each of palmitic acid, stearic acid, oleic acid, linoleic acid, and linolenic acid.
11 . The non-asphaltic composition of claim 7 further comprising the one or more tree rosin esters being one or more pine-based pentaerythritol ester resins and/or one or more pine-based glycerol ester resins.
12 . The non-asphaltic composition of claim 11 further comprising:
the total amount of the one or more tree rosin esters being from 40% to 55% by weight based on the total weight of the non-asphaltic composition and
the total amount of the low temperature property enhancing additive being from 2% to 7% by weight based on the total weight of the non-asphaltic composition.
13 . The non-asphaltic composition of claim 1 further comprising the one or more tree rosin esters being one or more pine-based pentaerythritol ester resins.
14 . The non-asphaltic composition of claim 1 further comprising the one or more plasticizers comprising one or more epoxidized esters of vegetable oils.
15 . The non-asphaltic composition of claim 1 further comprising the one or more plasticizers being one or more epoxidized esters of soybean oil.
16 . A method for forming, and enhancing low temperature properties of, a non-asphaltic composition for use as a hot-applied sealant, or for pavement markings, or for use as a binder for aggregates for filling potholes and road repairs, the method comprising steps of:
a) forming a non-asphaltic base blend by heating and blending
one or more processing oils in a total amount in a range of from 5% to 35% by weight based on a total weight of the non-asphaltic composition,
one or more plasticizers in a total amount in a range of from 0.5% to 6% by weight based on the total weight of the non-asphaltic composition, and
one or more tree rosin esters in a total amount in a range of from 25% to 80% by weight based on the total weight of the non-asphaltic composition and
b) incorporating, during and/or after step (a), a low temperature property enhancing additive in a total amount, in a range of from 1% to 25% by weight based on the total weight of the non-asphaltic composition, which increases a 4° C. ductility and decreases a flexural creep stiffness of the non-asphaltic composition, the low temperature property enhancing additive being a distilled tall oil, a distilled tall oil blend, one or more vegetable oils, or a combination thereof.
17 . The method of claim 16 further comprising:
the one or more tree rosin esters being one or more pine-based pentaerythritol ester resins and/or one or more pine-based glycerol ester resins and
the low temperature property enhancing additive being the distilled tall oil or the distilled tall oil blend.
18 . The method of claim 17 further comprising:
the total amount of the low temperature property enhancing additive incorporated in step (b) also increasing a resilience and reducing a viscosity of the non-asphaltic composition and
the total amount of the low temperature property enhancing additive incorporated in step (b) also (i) not reducing a softening point of the non-asphaltic composition below 79° C., (ii) maintaining the softening point of the non-asphaltic composition at a value of 80° C. or greater, or (iii) increasing the softening point of the non-asphaltic composition.
19 . The method of claim 17 further comprising:
the one or more tree rosin esters being one or more pine-based pentaerythritol ester resins and
the low temperature property enhancing additive, which is the distilled tall oil or the distilled tall oil blend, comprising (i) one or more of abietic acid and/or pimaric acid in a total amount of from 10% to 50% by weight based on a total weight of the distilled tall oil or the distilled tall oil blend and (ii) one or more of palmitic acid, stearic acid, oleic acid, linoleic acid, and/or linolenic acid in a total amount of from 60% to 90% by weight based on the total weight of the distilled tall oil or the distilled tall oil blend.
20 . The method of claim 16 further comprising, after step (a), one or more of:
adding a total of from 2% to 20% by weight, based on the total weight of the non-asphaltic composition, of one or more elastomeric polymer materials;
adding crumb rubber;
adding a total of from 1% to 25% by weight, based on the total weight of the non-asphaltic composition, of one or more color neutralizing materials which at least partially neutralize a non-white shade or color of the non-asphaltic base blend, the one or more color neutralizing materials comprising at least titanium dioxide; and/or
adding a total of from 0.1% to 6% by weight, based on the total weight of the non-asphaltic composition, of one or more pigment materials which impart a non-white color or shade to the non-asphaltic composition.