ELECTRODES, ELECTROCHEMICAL CELLS, AND METHODS OF FORMING ELECTRODES AND ELECTROCHEMICAL CELLS
Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
1 . A method of forming an electrochemical cell, the method comprising:
providing a mixture comprising a precursor and silicon particles;
casting the mixture on a current collector; and
pyrolysing the mixture to convert the precursor into one or more types of carbon phases to form a composite material.
2 . The method of claim 1 , further comprising applying pressure to the precursor at least 2 bars of pressure during the pyrolysing.
3 . The method of claim 1 , further comprising cycling the composite material.
4 . The method of claim 3 , wherein the composite material remains substantially flat and substantially free of wrinkles during cycling.
5 . The method of claim 1 , wherein pyrolysing comprises heating the precursor to about 900° C. to about 1350° C.
6 . The method of claim 1 , further comprising removing the precursor from the current collector prior to pyrolysing the precursor.
7 . The method of claim 1 , wherein at least one of the one or more types of carbon phases is a substantially continuous phase that holds the composite material together such that the silicon particles are distributed throughout the composite material.
8 . The method of claim 7 , wherein the at least one of the one or more types of carbon phases that is a substantially continuous phase comprises hard carbon.
9 . The method of claim 1 , wherein providing the mixture comprises providing the silicon particles at greater than 0% to about 90% by weight.
10 . The method of claim 9 , wherein the composite material comprises the silicon particles at more than about 50% by weight.
11 . The method of claim 10 , wherein the composite material comprises the silicon particles at about 60% to about 80% by weight.
12 . A method of forming an electrode for an electrochemical cell, the method comprising:
providing a mixture comprising a precursor;
casting the mixture on a current collector;
pyrolysing a precursor to convert the precursor into one or more types of carbon phases to form a composite material; and
applying an attachment substance to the composite material, wherein the one or more types of carbon phases hold the active material together on the electrode.
13 . The method of claim 12 , wherein the precursor comprises polyamic acid or polyimide.
14 . The method of claim 12 , wherein providing the mixture comprises providing conductive particles in the mixture.
15 . The method of claim 14 , wherein providing the mixture comprises providing metal particles in the mixture.
16 . The method of claim 12 , wherein providing the mixture comprises providing graphite particles in the mixture.
17 . The method of claim 12 , wherein providing the mixture comprises providing silicon particles.
18 . The method of claim 12 , wherein the composite material is substantially electrochemically active and electrically conductive.
19 . The method of claim 18 , wherein the composite material is an anode.
20 . The method of claim 18 , wherein the composite material is a cathode.