NEGATIVE-ELECTRODE ACTIVE MATERIAL, PREPARATION METHOD THEREOF, SECONDARY BATTERY AND APPARATUS
A negative-electrode active material includes a carbon matrix, boron, and iron distributed in an interior of the carbon matrix.
1 . A negative-electrode active material comprising:
a carbon matrix;
boron; and
iron distributed in an interior of the carbon matrix.
2 . The negative-electrode active material according to claim 1 , wherein the boron is distributed in a surface layer of the carbon matrix.
3 . The negative-electrode active material according to claim 1 , wherein:
the iron is in a zero-valence atomic state; and/or
the boron is in at least one of following states: a boron carbide state, a zero-valence atomic state, and a solid solution of boron in carbon.
4 . The negative-electrode active material according to claim 1 , wherein:
a weight of the iron is 0.1%-5% of a weight of the carbon matrix;
a weight of the boron is 0.01%-3% of the weight of the carbon matrix; and/or
a weight of the iron and the boron together is 0.1%-5% of the weight of the carbon matrix.
5 . The negative-electrode active material according to claim 1 , wherein a weight amount of the iron is greater than or equal to a weight amount of the boron.
6 . The negative-electrode active material according to claim 1 , wherein an X-ray photoelectron spectroscopy (XPS) analysis of the negative-electrode active material shows a characteristic peak only in a binding energy range of 183.0 eV-188.0 eV.
7 . The negative-electrode active material according to claim 1 , wherein, at a discharge rate of 0.33 C, a delithiation platform voltage of the negative-electrode active material is 0.18V-0.22V.
8 . The negative-electrode active material according to claim 1 , wherein the carbon matrix includes artificial graphite.
9 . A preparation method of a negative-electrode active material comprising:
providing a carbon-containing raw material;
adding an iron source to the carbon-containing raw material to obtain a first mixture;
performing heat treatment on the first mixture to obtain a carbon-containing intermediate material;
adding a boron source to the carbon-containing intermediate material to obtain a second mixture; and
performing graphitization treatment on the second mixture to obtain the negative-electrode active material;
wherein the negative-electrode active material includes a carbon matrix, boron, and iron, and the iron is distributed in an interior of the carbon matrix.
10 . The method according to claim 9 , wherein a coking value of the carbon-containing raw material is 40%-65%.
11 . The method according to claim 9 , wherein a volatile proportion of the carbon-containing raw material is 30%-55%.
12 . The method according to claim 9 , wherein a median particle size of the iron source is less than or equal to 3 μm.
13 . The method according to claim 9 , wherein a mass percentage of element iron in the iron source to the carbon-containing raw material is 0.05%-4%.
14 . The method according to claim 9 , wherein performing the heat treatment on the first mixture includes performing a first heating for a first heat treatment time of at least 2 hours at a first heat treatment temperature of 140° C.-260° C., and performing a second heating for a second heat treatment time of at least 2 hours at a second heat treatment temperature of 500° C.-650° C.
15 . The method according to claim 14 , wherein:
the first heat treatment temperature is 150° C.-230° C.;
the second heat treatment temperature is 520° C.-600° C.;
the first heat treatment time is 2-4 hours; and/or
the second heat treatment time is 3-6 hours.
16 . The method according to claim 9 , wherein a mass percentage of element boron in the boron source to the carbon-containing intermediate material is 0.1%-8%.
17 . The method according to claim 9 , wherein a temperature of the graphitization treatment is 2200° C.-2600° C.
18 . The method according to claim 9 , wherein:
the carbon-containing raw material is selected from at least one of coal pitch, petroleum pitch, natural pitch, shale tar pitch, petroleum, heavy oil, or decanted oil;
the iron source is selected from at least one of soluble iron (II) salt, soluble iron (III) salt, ferric oxide, ferroferric oxide, ferrous oxide, or ferrous powder; and/or
the boron source is selected from at least one of elemental boron, boric acid, metaboric acid, pyroboric acid, or boron trioxide.
19 . A secondary battery comprising a negative-electrode plate, wherein the negative-electrode plate includes a negative-electrode active material including a carbon matrix, boron, and iron distributed in an interior of the carbon matrix.
20 . An apparatus comprising the secondary battery according to claim 19 .