POSITIVE ELECTRODE PLATE FOR NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY, NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY, AND METHOD FOR MANUFACTURING POSITIVE ELECTRODE PLATE FOR NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY
A positive electrode plate for a non-aqueous electrolyte rechargeable battery includes a positive electrode mixture layer that is formed by a positive electrode mixture including a positive electrode active material and a conductive material. When R S =(R C ×B C )/(R A ×B A ) is satisfied, where R C (mass %) represents a percentage of the conductive material, B C (m 2 /g) represents a specific surface area of the conductive material, R A (mass %) represents a percentage of the positive electrode active material, B A (m 2 /g) represents a specific surface area of the positive electrode active material, and R S represents a total surface area ratio, an aspect ratio AR of the conductive material is thirty or greater, the total surface area ratio R S is in a range of 0.20 to 1.93, and a porosity P (%) of the positive electrode mixture layer is in a range of 40% to 55%.
1 . A positive electrode plate for a non-aqueous electrolyte rechargeable battery, the battery including a positive electrode plate, a negative electrode plate, a separator insulating the positive electrode plate and the negative electrode plate, and a non-aqueous electrolyte, the positive electrode plate comprising:
a positive electrode current collector; and
a positive electrode mixture layer formed on a part of at least one surface of the positive electrode current collector and formed by a positive electrode mixture, the positive electrode mixture including a positive electrode active material and a conductive material,
wherein when R S =(R C ×B C )/(R A ×B A ) is satisfied, where R C (mass %) represents a percentage of the conductive material in the positive electrode mixture, B C (m 2 /g) represents a specific surface area of the conductive material, R A (mass %) represents a percentage of the positive electrode active material in the positive electrode mixture, B A (m 2 /g) represents a specific surface area of the positive electrode active material, and R S represents a total surface area ratio,
an aspect ratio AR of the conductive material is thirty or greater;
the total surface area ratio R S is in a range of 0.20 to 1.93; and
a porosity P (%) of the positive electrode mixture layer is in a range of 40% to 55%.
2 . The positive electrode plate according to claim 1 , wherein
the specific surface area B A (m 2 /g) of the positive electrode active material is in a range of 1.6 to 3.3 m 2 /g,
the specific surface area B C (m 2 /g) of the conductive material is in a range of 180 to 500 m 2 /g, and
the percentage R C (mass %) of the conductive material in the positive electrode mixture is in a range of 0.2 to 1.5 mass %.
3 . The positive electrode plate according to claim 1 , wherein:
the positive electrode mixture layer is divided in a thickness-wise direction of the positive electrode mixture layer into two regions, a separator region located closer to the separator, and a positive electrode current collector region located closer to the positive electrode current collector; and
a mass M UP (g) of the conductive material present in the separator region of the positive electrode mixture layer is greater than a mass M LOW (g) of the conductive material present in the positive electrode current collector region of the positive electrode mixture layer.
4 . The positive electrode plate according to claim 3 , wherein a conductive material upper-lower ratio R M is in a range of 1.5 to 20, where the conductive material upper-lower ratio R M is a mass ratio of the mass M UP (g) of the conductive material present in the separator region of the positive electrode mixture layer to the mass M LOW (g) of the conductive material present in the positive electrode current collector region of the positive electrode mixture layer.
5 . The positive electrode plate according to claim 3 , wherein a porosity P LOW (%) of the positive electrode current collector region of the positive electrode mixture layer is greater than a porosity P UP (%) of the separator region of the positive electrode mixture layer.
6 . The positive electrode plate according to claim 5 , wherein a porosity upper-lower ratio R P is in a range of 1.1 to 12, where the porosity upper-lower ratio R P is a ratio of the P LOW (%) of the positive electrode current collector region of the positive electrode mixture layer to the P UP (%) of the separator region of the positive electrode mixture layer.
7 . A non-aqueous electrolyte rechargeable battery, the battery comprising:
the positive electrode plate for a non-aqueous electrolyte rechargeable battery according to claim 1 .
8 . A method for manufacturing a positive electrode plate for a non-aqueous electrolyte rechargeable battery, the battery including a positive electrode plate, a negative electrode plate, a separator insulating the positive electrode plate and the negative electrode plate, and a non-aqueous electrolyte, wherein the positive electrode plate includes a positive electrode current collector and a positive electrode mixture layer, the positive electrode mixture layer being formed on a part of at least one surface of the positive electrode current collector and formed by a positive electrode mixture, and the positive electrode mixture including a positive electrode active material and a conductive material, the method comprising:
preparing a positive electrode mixture paste;
applying the positive electrode mixture paste to a part of at least one surface of the positive electrode current collector; and
drying the positive electrode mixture paste to form the positive electrode mixture layer, wherein:
the preparing a positive electrode mixture paste is performed so that when R S =(R C ×B C )/(R A ×B A ) is satisfied, where R C (mass %) represents a percentage of the conductive material in the positive electrode mixture, B C (m 2 /g) represents a specific surface area of the conductive material, R A (mass %) represents a percentage of the positive electrode active material in the positive electrode mixture, B A (m 2 /g) represents a specific surface area of the positive electrode active material, and R S represents a total surface area ratio,
an aspect ratio AR of the conductive material is thirty or greater;
the total surface area ratio R S is in a range of 0.20 to 1.93; and
a porosity P (%) of the positive electrode mixture layer is in a range of 40% to 55%.
9 . The method according to claim 8 , the positive electrode mixture layer being divided in a thickness-wise direction of the positive electrode mixture layer into two regions, a separator region located closer to the separator, and a positive electrode current collector region located closer to the positive electrode current collector, wherein:
the preparing a positive electrode mixture paste includes adjusting a solid content ratio NV of the positive electrode mixture paste, and the drying the positive electrode mixture paste includes controlling a drying temperature and a drying time period so that:
a conductive material upper-lower ratio R M after the drying is in a range of 1.5 to 20, where the conductive material upper-lower ratio R M is a mass ratio of a mass M UP (g) of the conductive material present in the separator region of the positive electrode mixture layer to a mass M LOW (g) of the conductive material present in the positive electrode current collector region of the positive electrode mixture layer; and
a porosity upper-lower ratio R P is in a range of 1.1 to 12, where the porosity upper-lower ratio R P is a ratio of a porosity P LOW (%) of the positive electrode current collector region of the positive electrode mixture layer to a porosity P UP (%) of the separator region of the positive electrode mixture layer.