Granted Patent B2

US 12,203,040 · App. 18/232,439 · Granted Jan 21, 2025

Inventors: Ravi Chandran (Ellicott City, MA); Dave G. Newport (Cumberland, ME); Daniel A. Burciaga (Manchester, MD); Daniel Michael Leo (Baltimore, MD)

Assignee: ThermoChem Recovery International, Inc.

C10J3/721C10K1/005C10K1/026C10J2300/0946C10J2300/0959C10J2300/1261C10J2300/1618C10J2300/1637C10J2300/1815C10J2300/1846C10J2300/1853

Abstract

Claims (38)

1. A system comprising:

a first reactor configured to generate a first product gas including char;

a solids separation device configured to separate the char from the first product gas to produce separated char and char-depleted product gas, wherein the char-depleted product gas has a reduced amount of char relative to the first product gas;

an eductor configured to accept a recycle gas and configured to entrain the separated char in a motive fluid that comprises the recycle gas; and

a second reactor configured to accept a mixture comprising the motive fluid with the separated char and configured to accept the char-depleted product gas, wherein the second reactor is further configured to react the separated char and the char-depleted product gas with an oxygen-containing gas to produce a final product gas.

2. The system of claim 1 , wherein the motive fluid comprises one or more selected from the group consisting of a gas, carbon dioxide, nitrogen, tail-gas, conditioned syngas, syngas, off-gas, steam, superheated steam, a vapor, and a superheated vapor.

3. The system of claim 1 , wherein the eductor is configured to entrain the separated char in the motive fluid, prior to introducing the mixture comprising the motive fluid with the separated char to the second reactor.

4. The system of claim 1 , wherein the solids separation device comprises one or more cyclones.

5. The system of claim 1 , further comprising:

a primary gas clean-up system configured to cool and remove solids and water vapor and some of the contaminants from the final product gas to produce a first cleaned product gas;

a compression system configured to compress the first cleaned product gas to produce a compressed product gas; and

a secondary gas clean-up system configured to remove contaminants and carbon dioxide from the compressed product gas to produce a second cleaned product gas.

6. The system of claim 5 , wherein the carbon dioxide from the secondary gas clean-up system is provided as the recycle gas, prior to introducing the mixture comprising the motive fluid with the separated char to the second reactor.

7. The system of claim 5 , further comprising:

a production system configured to produce an intermediate product from at least a portion of the second cleaned product gas.

8. The system of claim 7 , wherein the intermediate product includes one or more selected from the group consisting of liquid fuel, a chemical, tail-gas, ethanol, mixed alcohols, methanol, dimethyl ether, Fischer-Tropsch products, and synthetic natural gas.

9. The system of claim 7 , wherein one of the intermediate products from the production system is provided as the recycle gas, prior to introducing the mixture comprising the motive fluid with the separated char to the second reactor.

10. The system of claim 7 , wherein the production system comprises a reactor including one or more reactors selected from the group consisting of a multi-tubular reactor, a multi-tubular fixed-bed reactor, an entrained flow reactor, a slurry reactor, a fluid bed reactor, a circulating catalyst reactor, a riser reactor, a can reactor, a microchannel reactor, a fixed bed reactor, a bioreactor, and a moving bed reactor.

11. The system of claim 7 , further comprising:

a purification system configured to purify the intermediate product to produce a purified product.

12. The system of claim 11 , wherein the purified product comprises an off-gas.

13. The system of claim 11 , wherein the purified product from the purification system is provided as the recycle gas, prior to introducing the mixture comprising the motive fluid with the separated char to the second reactor.

14. The system of claim 1 , wherein the first product gas further comprises hydrogen, carbon monoxide, carbon dioxide, and hydrocarbons; and/or wherein the final product gas has a reduced amount of char and a reduced amount of hydrocarbons, relative to the char-depleted product gas.

15. The system of claim 1 , wherein the first reactor is configured to steam reform a carbonaceous material to produce the first product gas.

16. The system of claim 15 , wherein the first reactor further comprises:

an input configured to introduce the carbonaceous material to an interior of the first reactor and

a reactant input configured to provide a reactant to react with the carbonaceous material in the first reactor to produce the first product gas.

17. The system of claim 1 , wherein the first reactor further comprises a particulate heat transfer material contained within an interior of the first reactor and an optional first reactor heat exchanger immersed within the particulate heat transfer material; or wherein the first reactor comprises an up-flow, catalytic, refractory-lined, steel pressure vessel with a fluidized bed or an up-flow, non-catalytic, refractory-lined, steel pressure vessel with a fluidized bed; and/or wherein the second reactor comprises a cylindrical, down-flow, non-catalytic, lined, steel pressure vessel.

18. The system of claim 1 , wherein the first reactor comprises a steam reformer, and/or wherein the second reactor comprises a char/hydrocarbon reformer.

19. The system of claim 1 , wherein the second reactor is further configured to accept the mixture comprising the motive fluid with the separated char and configured to accept the char-depleted product gas at different reaction zones within the second reactor.

20. The system of claim 1 , wherein the second reactor further comprises a burner configured to react the oxygen-containing gas with a fuel, and wherein the burner comprises an annulus type burner or a pulse combustor burner.

21. The system of claim 1 , wherein the second reactor further comprises a second reactor heat exchanger in thermal contact with an interior of the second reactor, and wherein the second reactor heat exchanger is configured to remove heat from within the interior of the second reactor by use of a heat transfer medium.

22. The system of claim 1 , wherein the second reactor is further configured to introduce additional oxygen-containing gas between a first char input for the separated char and a product gas input for the char-depleted product gas.

23. The system of claim 1 , further comprising:

a feedstock delivery system configured to transfer a source of carbonaceous material to the first reactor.

24. The system of claim 1 , further comprising:

a feedstock preparation system configured to accept a source of carbonaceous material comprising municipal solid waste and to produce sorted municipal solid waste in at least one processing step, including one or more processing steps selected from the group consisting of large objects removal, recyclables removal, ferrous metal removal, size reduction, drying or water removal, biowaste removal, non-ferrous metal removal, polyvinyl chloride removal, glass removal, size reduction, and pathogen removal; and

a feedstock delivery system configured to accept the sorted municipal solid waste from the feedstock preparation system as the source of carbonaceous material, wherein the feedstock delivery system is further configured to transfer the source of carbonaceous material to the first reactor.

Assignments (2)

Continuity (3)

References Cited (333)