Surface Modification of Silicon Particles for Electrochemical Storage
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight silicon particles, the silicon particles having an average particle size between about 10 nm and about 40 μm, wherein the silicon particles have surface coatings comprising silicon carbide or a mixture of carbon and silicon carbide, and greater than 0% and less than about 90% by weight of one or more types of carbon phases, wherein at least one of the one or more types of carbon phases is a substantially continuous phase.
1 . A composite material film comprising:
greater than 0% and less than about 90% by weight silicon particles, the silicon particles having an average particle size between about 10 nm and about 40 μm;
greater than 0% and less than about 90% by weight of one or more types of carbon phases, wherein at least one of the one or more types of carbon phases comprises hard carbon as a matrix phase that is a substantially continuous phase that extends across the entire film.
2 . The composite material film of claim 1 , wherein the average particle size of the silicon particles is between about 100 nm and about 10 μm.
3 . The composite material film of claim 1 , wherein the average particle size of the silicon particles is between about 1 μm and about 15 μm.
4 . The composite material film of claim 1 , wherein the average particle size of the silicon particles is between about 10 nm and about 1 μm.
5 . The composite material film of claim 1 , wherein the silicon particles further comprise an average surface area per unit mass between about 1 m 2 /g and about 30 m 2 /g.
6 . The composite material film of claim 1 , comprising about 20% to about 90% of the silicon particles by weight.
7 . The composite material film of claim 1 , wherein the silicon particles are homogenously distributed throughout the hard carbon.
8 . The composite material film of claim 1 , wherein the silicon particles are in contact with the substantially continuous phase.
9 . The composite material film of claim 1 , wherein the at least one of the one or more types of carbon phases is electrochemically active and electrically conductive.
10 . The composite material film of claim 1 , wherein the one or more types of carbon phases comprises graphite particles.
11 . The composite material film of claim 1 , further comprising conductive particles.
12 . The composite material film of claim 1 , further comprising metal particles.
13 . The composite material film of claim 1 , wherein the composite material film is substantially electrochemically active.
14 . An electrode configured to be used in an electro-chemical cell comprising the composite material film of claim 1 . The electrode of claim 14 , wherein the electrode is an anode.
16 . A method of forming the composite material film of claim 1 comprising:
providing a mixture comprising a precursor and silicon particles; and
pyrolyzing the precursor to convert the precursor into the one or more types of carbon phases to form a composite material.
17 . The method of claim 16 , wherein after pyrolyzing the precursor, the mixture forms a self-supported composite structure.
18 . The method of claim 16 , wherein the mixture further comprises a solvent.
19 . The method of claim 16 , wherein the precursor comprises a polyimide, a phenolic resin, and/or a hydrocarbon compound.
20 . The method of claim 16 , further comprising:
casting the mixture on a substrate;
drying the mixture to form the film;
removing the film from the substrate; and
curing the film in a hot press.