POLYMER BLENDS HAVING INCREASED TEMPERATURE RESISTANCE
Embodiments of polymer blends may include a first polymer composition and a second polymer composition. The first polymer composition may include a polyolefin having a thermal transition temperature of at least 100° C. and a graftable monomer having at least one acid or anhydride functional group grafted onto the polyolefin. The second polymer composition may include an E/X/Y ethylene interpolymer, wherein E is an ethylene monomer and comprises greater than 50 wt. % of the interpolymer, X is an α,β-unsaturated C 3 -C 8 carboxylic acid and comprises greater than 0 to 25 wt. % of the interpolymer, and Y is an optional comonomer comprising C 1 -C 8 alkyl acrylate.
1 . A polymer blend comprising:
a first polymer composition comprising:
a polyolefin having a thermal transition temperature of at least 100° C. (defined as temperature below which the storage modulus is >10 MPa @ 10 rad/s measured using Dynamic Mechanical Thermal Analysis (DMTA)); and
graftable monomer comprising at least one acid or anhydride functional group grafted onto the polyolefin,
a second polymer composition comprising an E/X/Y ethylene interpolymer, wherein E is an ethylene monomer and comprises greater than 50 wt. % of the interpolymer, X is an α,β-unsaturated C 3 -C 8 carboxylic acid and comprises greater than 0 to 25 wt. % of the ethylene interpolymer, and Y is an optional comonomer comprising C 1 -C 8 alkyl acrylate.
2 . The polymer blend of claim 1 , wherein the polyolefin comprises ethylene based polymer or propylene based polymer.
3 . The polymer blend of claim 2 , wherein the ethylene based polymer comprises high-density polyethylene with a density greater than 0.940 g/cc.
4 . The polymer blend of claim 1 , wherein the graftable monomer comprises at least one of acrylic acid, methacrylic acid, or both grafted onto the polyolefin.
5 . The polymer blend of claim 1 , wherein the α,β-unsaturated C 3 -C 8 carboxylic acid comprises acrylic acid, or methacrylic acid.
6 . The polymer blend of claim 1 , wherein the polyolefin comprises a melt index (I 2 ) of 0.5 to 60 g/10 mins, when measured according to ASTM D1238 (190° C./2.16 kg).
7 . The polymer blend of claim 1 , wherein the weight ratio of the first polymer composition to the second polymer composition is from 20/80 wt. % to 80/20 wt. %.
8 . The polymer blend of claim 1 , wherein the first polymer composition, the second polymer composition, or both comprise acrylic acid.
9 . The polymer blend of claim 1 , wherein the thermal transition temperature of the polyolefin is at least 125° C.
10 . An ionomer composition comprising the polymer blend of claim 1 , wherein the first polymer composition, the second polymer composition, or both are at least partially neutralized by metal salts.
11 . The ionomer composition of claim 10 , wherein from 15% to 90% of acid sites of the first polymer composition, the second polymer composition, or both are neutralized by the metal salts.
12 . The ionomer composition of claim 10 , wherein the metal salt comprises one or more salts of zinc, magnesium, lithium, aluminum, or sodium.
13 . The ionomer composition of claim 10 , wherein the ionomer composition has a rheology ratio greater than 10.0 (at a test temperature of 190° C.).
14 . The ionomer composition of claim 10 , wherein the ionomer composition has a phase angle less than 57° (at a test temperature of 190° C. and complex modulus of 20 kPa).
15 . A method of making the ionomer composition of claim 10 comprising:
blending the first polymer composition and the second polymer composition; and
neutralizing the first polymer composition and the second polymer composition, wherein the first polymer composition, the second polymer composition, or both are neutralized by the metal salts before or after blending.