BIOSURFACTANTS FOR IRON AND ZINC SULFIDE SCALE REMEDIATION AND CONTROL
The subject invention provides scale inhibitors and/or dispersants comprising microbial surfactants, or biosurfactants, as well as methods of their use for removing metal sulfide scale deposits and/or preventing the precipitation and/or deposition thereof on the surfaces of, for example, reservoirs, wellbores, pipelines, tubing and other oilfield equipment.
1 . A method for enhancing oil recovery from an oil production environment having scale deposits and/or scale ions therein, the method comprising applying a composition comprising one or more microbial biosurfactants to the oil production environment such that the composition contacts the scale deposits and/or scale ions, wherein the composition inhibits the formation of scale deposition on surfaces in the oil production environment and/or wherein the composition removes scale deposits that are present on the surfaces.
2 . The method of claim 1 , wherein the scale is zinc sulfide or ion sulfide scale.
3 . The method of claim 1 , wherein the composition comprises one or more glycolipid biosurfactants.
4 . The method of claim 3 , wherein the glycolipid biosurfactants are linear sophorolipids, lactonic sophorolipids, or a mixture thereof.
5 . The method of claim 4 , wherein the sophorolipids have one or more of the following structures:
6 . The method of claim 3 , wherein the rhamnolipids have one or more of the following structures:
7 . The method of claim 1 , wherein the composition is applied to a fluid comprising scale ions, said fluid selected from crude oil fluid, a brine fluid, produced water, a frack fluid, and well treatment fluids, wherein the application of the composition disperses scale ions, reduces agglomeration of scale ions and/or reduces precipitation of scale crystals from the fluid.
8 . The method of claim 1 , wherein the composition is applied directly to a surface of equipment associated with oil production, processing, transportation, storage and/or refining selected from piping, tubing, pipelines, drills, pumps, valves and tanks, and wherein the application of the composition reduces the deposition of scale crystals thereon and/or removes scale deposits from the surface.
9 . The method of claim 1 , wherein the composition is injected into a subterranean formation as a continuous injection treatment, a batch treatment or a squeeze treatment.
10 . The method of claim 1 , used to improve the flow of oil and/or gas from a formation by opening pores, fractures, tubing and/or piping associated with the formation.
11 . The method of claim 1 , used to maintain equipment associated with oil production, processing, transportation, storage and/or refining.