Exhaust gas treatment system including a multifunctional catalyst
The present invention relates to an exhaust gas treatment system for treating an exhaust gas stream exiting a diesel engine, wherein said exhaust gas treatment system comprises a first catalyst having an inlet end and an outlet end and comprising a coating disposed on a substrate, wherein the coating comprises palladium supported on an oxidic material comprising zirconium and further comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron; a second catalyst having an inlet end and an outlet end and comprising a coating disposed on a substrate, wherein the coating comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron, wherein at most 0.0001 weight-% of the coating of the second catalyst consists of platinum group metal.
1. An exhaust gas treatment system for treating an exhaust gas stream exiting a diesel engine, said exhaust gas treatment system having an upstream end for introducing said exhaust gas stream into said exhaust gas treatment system, wherein said exhaust gas treatment system comprises;
(i) a first catalyst having an inlet end and an outlet end and comprising a coating disposed on a first substrate, wherein the coating comprises palladium supported on an oxidic material comprising zirconium and further comprises one or more of a vanadium oxide and a first zeolitic material comprising one or more of copper and iron;
(ii) a second catalyst having an inlet end and an outlet end and comprising a coating disposed on a second substrate, wherein the coating comprises one or more of a vanadium oxide and a second zeolitic material comprising one or more of copper and iron, wherein at most 0.0001 weight-% of the coating of the second catalyst consists of platinum group metal;
wherein the first catalyst according to (i) is located downstream of the upstream end of the exhaust gas treatment system and wherein the inlet end of the first catalyst is arranged upstream of the outlet end of the first catalyst;
wherein in the exhaust gas treatment system, the second catalyst according to (ii) is located downstream of the first catalyst according to (i) and wherein the inlet end of the second catalyst is arranged upstream of the outlet end of the second catalyst.
2. The exhaust gas treatment system of claim 1 , wherein from 70 to 98 weight-%, preferably from 75 to 95 weight-%, more preferably from 80 to 90 weight-% of the oxidic material comprised in the coating of the first catalyst according to (i) consist of zirconium and oxygen, preferably of zirconia.
3. The exhaust gas treatment system of claim 1 , wherein the oxidic material comprised in the coating of the first catalyst according to (i) further comprises one or more of lanthanum, hafnium, aluminum, silicon and titanium, preferably one or more of lanthanum and hafnium, more preferably lanthanum and hafnium.
4. The exhaust gas treatment system of claim 1 , wherein from 5 to 40 weight-%, preferably from 7 to 20 weight-%, more preferably from 8 to 15 weight-%, of the coating of the first catalyst according to (i) consist of the oxidic material.
5. The exhaust gas treatment system of claim 1 , wherein the first zeolitic material comprises one or more of copper and iron, wherein from 60 to 95 weight-%, preferably from 80 to 93 weight-%, more preferably from 82 to 92 weight-%, of the coating of the first catalyst according to (i) consist of the zeolitic material comprising one or more of copper and iron.
6. The exhaust gas treatment system of claim 1 , wherein the first zeolitic material comprised in the coating of the first catalyst has a framework structure of AEI, GME, CHA, MFI, BEA, FAU, MOR or mixtures of two or more thereof, preferably a framework structure of AEI, CHA, BEA or mixtures of two or more thereof, more preferably a framework structure of CHA or AEI, more preferably a framework structure of CHA.
7. The exhaust gas treatment system of claim 1 , wherein the second zeolitic material comprises one or more of copper and iron; wherein from 80 to 100 weight-%, preferably from 90 to 99 weight-%, more preferably from 95 to 98 weight-%, of the coating of the second catalyst according to (ii) consist of the second zeolitic material comprising one or more of copper and iron.
8. The exhaust gas treatment system of claim 1 , wherein the second zeolitic material comprised in the coating of the second catalyst has a framework structure of AEI, GME, CHA, MFI, BEA, FAU, MOR or mixtures of two or more thereof, preferably a framework structure of AEI, CHA, BEA or mixtures of two or more thereof, more preferably a framework structure of CHA or AEI, more preferably a framework structure of CHA.
9. The exhaust gas treatment system of claim 1 , wherein the coating of the first catalyst comprises, preferably consists of, palladium supported on an oxidic material comprising zirconium, and the first zeolitic material having a framework structure of CHA and comprising copper, and preferably a metal oxide, and
wherein the coating of the second catalyst comprises, preferably consists of, the first zeolitic material having a framework structure of CHA and comprising copper, and preferably a metal oxide, wherein at most 0.0001 weight-% of the coating of the second catalyst consists of platinum group metal.
10. The exhaust gas treatment system of claim 1 , further comprising a first injector for injecting a fluid into the exhaust gas stream exiting the diesel engine, said first injector being located upstream of the first catalyst and downstream of the upstream end of the exhaust gas treatment system.
11. The exhaust gas treatment system of claim 1 , further comprising
(iii) a third catalyst having an inlet end and an outlet end and comprising a first coating disposed on a third substrate and a second coating disposed on the first coating,
wherein the first coating comprises a platinum group metal supported on an oxidic material and optionally further comprises one or more of a vanadium oxide and a third zeolitic material comprising one or more of copper and iron,
wherein the second coating comprises one or more of a vanadium oxide and a fourth zeolitic material comprising one or more of copper and iron;
wherein in the exhaust gas treatment system, the third catalyst according to (iii) is located downstream of the second catalyst according to (ii) and wherein the inlet end of the third catalyst is arranged upstream of the outlet end of the third catalyst.
12. The exhaust gas treatment system of claim 11 , wherein the platinum group metal comprised in the first coating of the third catalyst according to (iii) is one or more of platinum, palladium, rhodium, iridium and osmium, preferably one or more of platinum, palladium and rhodium, more preferably one or more of platinum and palladium, more preferably platinum.
13. The exhaust gas treatment system of claim 11 , wherein the oxidic material comprised in the first coating of the third catalyst according to (iii) comprises one or more of titania, zirconia, and alumina, preferably one or more of titania and zirconia, more preferably titania;
wherein more preferably from 85 to 98.5 weight-%, more preferably from 85 to 95 weight-%, of the oxidic material consist of titania, calculated as TiO 2 .
14. The exhaust gas treatment system of claim 1 , wherein from 5 to 40 weight-%, preferably from 7 to 20 weight-%, more preferably from 8 to 15 weight-%, of the first coating of the third catalyst according to (iii) consist of the oxidic material, or wherein from 70 to 100 weight-%, preferably from 80 to 100 weight-%, more preferably from 90 to 100 weight-%, more preferably from 95 to 100 weight-%, more preferably from 99 to 100 weight-%, of the first coating of the third catalyst according to (iii) consist of the oxidic material.
15. A method for the treatment of an exhaust gas stream exiting a diesel engine comprising
providing an exhaust gas stream exiting a diesel engine and
passing said gas through the exhaust gas treatment system according claim 1 .