Vapor compression systems containing lubricant-refrigerant compositions
The present disclosure relates to refrigeration, air conditioning and heat pump apparatus containing a lubricating composition comprising polyol ester lubricant, tetrafluoropropene and difluoromethane.
1 . A refrigeration, air-conditioning or heat pump apparatus comprising an evaporator, a compressor, a condenser, a vapor phase refrigerant blend, and an expansion device; wherein said compressor comprises a lubricant reservoir containing a liquid phase lubricating composition comprising polyol ester lubricant, difluoromethane, and 2,3,3,3-tetrafluoropropene, and said vapor phase refrigerant blend is selected from the group consisting of:
35 wt % difluoromethane and 65 wt % 2,3,3,3-tetrafluoropropene;
68.9 wt % difluoromethane and 31.1 wt % 2,3,3,3-tetrafluoropropene; and
21.5 wt % difluoromethane and 78.5 wt % 2,3,3,3-tetrafluoropropene.
2 . The apparatus of claim 1 , wherein the polyol ester lubricant is obtained by reacting a carboxylic acid with a polyol comprising a neopentyl backbone selected from the group consisting of neopentyl glycol, trimethylol propane, pentaerythritol, dipentaerythritol, and mixtures thereof.
3 . The apparatus of claim 1 , wherein the polyol ester lubricant is obtained by reacting an alcohol with a carboxylic acid having 2 to 15 carbons.
4 . The apparatus of claim 3 , wherein the carboxylic acid is linear or branched.
5 . The apparatus of claim 2 , wherein said polyol ester lubricant has a viscosity of from about 10 to about 200 centistokes at about 40° C.
6 . The apparatus of claim 1 , wherein said compressor is a rotary compressor, reciprocating compressor, or scroll compressor.
7 . The apparatus of claim 1 , which is an air conditioning apparatus.
8 . The apparatus of claim 1 , which is a refrigeration apparatus.
9 . The apparatus of claim 1 , which is a heat pump apparatus.
10 . The apparatus of claim 1 , wherein said liquid phase lubricating composition comprises:
a. from about 2 to 7 weight percent difluoromethane, about 6 to 18 weight percent 2,3,3,3-tetrafluoropropene, and about 75 to 91 weight percent polyol ester lubricant;
b. from about 5 to 14 weight percent difluoromethane, about 3 to 9 weight percent 2,3,3,3-tetrafluoropropene, and about 76 to 92 weight percent polyol ester lubricant; or
c. from about 1 to 4 weight percent difluoromethane, about 7 to 20 weight percent 2,3,3,3-tetrafluoropropene, and about 77 to 92 weight percent polyol ester lubricant.
11 . The apparatus of claim 10 , wherein said liquid phase lubricating composition comprises:
a. from about 2 to 6.5 weight percent difluoromethane, about 6 to 17 weight percent 2,3,3,3-tetrafluoropropene, and about 77 to 91 weight percent polyol ester lubricant;
b. from about 5 to 13 weight percent difluoromethane, about 3 to 8 weight percent 2,3,3,3-tetrafluoropropene, and about 80 to 92 weight percent polyol ester lubricant; or
c. from about 2 to 4 weight percent difluoromethane, about 7 to 19 weight percent 2,3,3,3-tetrafluoropropene, and about 78 to 92 weight percent polyol ester lubricant.
12 . The apparatus of claim 10 , wherein said liquid phase lubricating composition comprises:
a. from about 3 to 6.5 weight percent difluoromethane, about 8 to 17 weight percent 2,3,3,3-tetrafluoropropene, and about 77 to 88 weight percent polyol ester lubricant;
b. from about 7 to 13 weight percent difluoromethane, about 3 to 8 weight percent 2,3,3,3-tetrafluoropropene, and about 80 to 89 weight percent polyol ester lubricant; or
c. from about 3 to 4 weight percent difluoromethane, about 9 to 19 weight percent 2,3,3,3-tetrafluoropropene, and about 78 to 89 weight percent polyol ester lubricant.
13 . The apparatus of claim 10 , wherein said liquid phase lubricating composition comprises:
a. from about 6 to 7 weight percent difluoromethane, about 6 to 18 weight percent 2,3,3,3-tetrafluoropropene, and about 75 to 78 weight percent polyol ester lubricant;
b. from about 7 to 9 weight percent difluoromethane, about 7 to 9 weight percent 2,3,3,3-tetrafluoropropene, and about 76 to 81 weight percent polyol ester lubricant; or
c. from about 1 to 4 weight percent difluoromethane, about 18 to 20 weight percent 2,3,3,3-tetrafluoropropene, and about 77 to 79 weight percent polyol ester lubricant.
14 . A method of lubricating a compressor in a refrigeration, air conditioning or heat pump system, said method comprising adding a POE lubricant to the compressor, charging the system with refrigerant blend and operating the system, wherein:
said compressor comprises a lubricant reservoir containing a liquid phase lubricating composition comprising POE lubricant, difluoromethane, and 2,3,3,3-tetrafluoropropene; and
said refrigerant blend is selected from the group consisting of: 35 wt % difluoromethane and 65 wt % 2,3,3,3-tetrafluoropropene, 68.9 wt % difluoromethane and 31.1 wt % 2,3,3,3-tetrafluoropropene, and 21.5 wt % difluoromethane and 78.5 wt % 2,3,3.3-tetrafluoropropene.