IP Library Granted Patent US 12,397,331
Granted Patent B2
US 12,397,331 · App. 18/304,052 · Granted Aug 26, 2025

Solar module recycling and testing

Inventors: Pablo Ribeiro Dias (Oakland, CA); Suvi Sharma (Fremont, CA)
Assignee: SOLARCYCLE, Inc.
B09B3/35B02C13/26B02C18/0084B02C23/14B09B2101/15
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Quick Facts
Patent No.
US 12,397,331
App. No.
18/304,052
Granted
Aug 26, 2025
Kind
B2
Abstract

Embodiments relate to one or more techniques that may be employed alone or in combination, in the refurbishment or recycling of used solar modules. In certain approaches, a (heated) wire may be used to cut through one or more layers (e.g., front encapsulant, back encapsulant, both front and back encapsulant, backsheet) of a solar module that is being recycled or refurbished. Some approaches may employ testing of a used solar module, alone or in combination with information (e.g., as part of a received package) regarding parameters of a used solar module such as panel size, width, length, height, thickness of glass, or others. According to specific embodiments, used solar modules may be subjected to various cleaning processes at one or more points during refurbishment/recycling.

Claims (28)

1. A method comprising:

performing a first phase shredding upon a photovoltaic module including a glass sheet and a polymer encapsulant;

separating broken glass from results of the first phase shredding including the polymer encapsulant;

following the separating, performing a second phase shredding upon the results of the first phase shredding including the polymer encapsulant;

prior to the first phase shredding, applying a fluid jet to the glass sheet; and

prior to the first phase shredding, testing the photovoltaic module.

2. The method as in claim 1 wherein the separating employs a sieve.

3. The method as in claim 2 wherein the sieve has openings of between about 2-50 mm.

4. The method as in claim 1 further comprising:

prior to performing the second phase shredding, delaminating the results of the first phase shredding.

5. The method as in claim 1 further comprising:

prior to performing the first phase shredding, removing a junction box and/or a frame from the photovoltaic module.

6. The method as in claim 1 wherein the first phase shredding involves application of a hammer and/or a knife.

7. The method as in claim 1 wherein the first phase shredding involves rotation.

8. The method as in claim 1 wherein the separating is based upon density.

9. The method as in claim 1 wherein the separating is based upon optical sorting.

10. The method as in claim 1 further comprising:

uniting results of the first phase shredding with results of the second phrase shredding in a same container.

11. The method as in claim 1 wherein conditions of the first phase shredding are different from conditions of the second phase shredding.

12. The method as in claim 1 wherein the fluid jet comprises water.

13. The method as in claim 1 wherein the testing is for wet leakage.

14. The method as in claim 1 wherein the applying comprises soap.

15. The method as in claim 1 further comprising:

prior to the applying, determining that the photovoltaic module is dirty.

16. The method as in claim 1 wherein a pressure of the fluid jet is between about 50-200 MPa.

17. The method as in claim 1 wherein the fluid jet is applied horizontally.

18. The method as in claim 1 wherein the fluid jet is applied at an angle of from between about 1-20° from horizontal.

19. The method as in claim 1 further comprising supporting the photovoltaic module on a belt during the applying.

Continuity (5)
Continuation In Part 18147585 · Dec 28, 2022
Provisional Application 63333475 · Apr 21, 2022
Provisional Application 63333886 · Apr 22, 2022
Provisional Application 63389325 · Jul 14, 2022
Related Publication 20230339003A1 · Oct 26, 2023
References Cited (105)
US 6129779A · Bohland et al. · 2000 [cited by applicant]
US 6781344B1 · Hedegor · 2004 [cited by applicant]
US 6902604B2 · Heckel et al. · 2005 [cited by applicant]
US 7105041B2 · Dunn · 2006 [cited by applicant]
US 7731920B2 · Fthenakis · 2010 [cited by applicant]
US 8448318B2 · Murphy · 2013 [cited by applicant]
US 10092907B2 · Mankosa et al. · 2018 [cited by applicant]
US 10385421B2 · Tao · 2019 [cited by applicant]
US 11491774B1 · Lee · 2022 [cited by examiner]
US 12005485B2 · Ribeiro Dias · 2024 [cited by applicant]
US 20120325676A1 · Taylor · 2012 [cited by applicant]
US 20200247106A1 · Lee · 2020 [cited by applicant]
US 20200282432A1 · Khadilkar · 2020 [cited by applicant]
US 20210263181A1 · Jukkola et al. · 2021 [cited by applicant]
US 20220140175A1 · Matsumoto et al. · 2022 [cited by applicant]
AU 2021904167 · 2021 [cited by applicant]
BR 1020160250978 · 2020 [cited by applicant]
BR 1020200124161 · 2020 [cited by applicant]
CN 202555405 · 2012 [cited by applicant]
CN 102953081A · 2013 [cited by applicant]
CN 106834700A · 2017 [cited by applicant]
CN 209929333U · 2020 [cited by applicant]
CN 115358968A · 2022 [cited by applicant]
EP 0279200A2 · 1988 [cited by applicant]
EP 2997169A1 · 2016 [cited by applicant]
EP 4169619A1 · 2023 [cited by applicant]
GB 23008827A · 1996 [cited by applicant]
JP 2011173099A · 2011 [cited by applicant]
JP 2016036756A · 2016 [cited by applicant]
JP 2018086651A · 2018 [cited by applicant]
KR 20130104794A · 2013 [cited by applicant]
KR 101842224B1 · 2018 [cited by applicant]
KR 1020210082629A · 2021 [cited by applicant]
KR 20220026695A · 2022 [cited by applicant]
WO 2005024854A1 · 2005 [cited by applicant]
WO 2006130715A3 · 2006 [cited by applicant]
WO 2012083398A1 · 2012 [cited by applicant]
WO 2013057035 · 2013 [cited by applicant]
WO 2018218358A1 · 2018 [cited by applicant]
WO 2021149545A1 · 2021 [cited by applicant]
WO PCTAU2022051545 · 2022 [cited by applicant]
EP 4169619 A with English translation; Inv: Stephan; Pub. Date: Apr. 2023 (Year: 2023). [cited by examiner]
“Solar Panel Recycling Service” NPC Incorporated. https://www.npcgroup.net/eng/solarpower/reuse-recycle/recycle-service, 2022. [cited by applicant]
Joel Spaes. “New delamination technique for PV module recycling” PV Magazine International. https://www.pv-magazine.com/2021/03/19/new-delamination-technique-for-pv-module-recycling/, 2021. [cited by applicant]
Manzil. “Hanging Solar Chargers” Trend Hunter Inc. https://www.trendhunter.com/trends/sunbox-solar-panels, 2010. [cited by applicant]
“Mystery of Prince Rupert's Drop at 130,000 fps—Smarter Every Day 86” YouTube. https://www.youtube.com/watch?v=xe-f4gokRBs, 2013. [cited by applicant]
The Action Lab. “This Light Lets You See The Strength Of An Object” YouTube. https://www.youtube.com/watch?=jFwm3TIC750, 2021. [cited by applicant]
Marianna Ottoni et al. “A circular approach to the e-waste valorization through urban mining in Rio de Janeiro, Brazil” Journal of Cleaner Production, 2020, vol. 261. https://doi.org/10.1016/j.jclepro.2020.120990. [cited by applicant]
Rong Deng et al. “A sustainable chemical process to recycle end-of-life silicon solar cells” Green Chemistry, 2021, vol. 23, Issue 24, pp. 10157-10167. https://doi.org/10.1039/d1gc02263f. [cited by applicant]
Pablo Dias et al. “Carbon emissions and embodied energy as tools for evaluating environmental aspects of tap water and bottled water in Brazil”. Desalination and Water Treatment, 2015, vol. 57, Issue 28, pp. 13020-13029… [cited by applicant]
Pablo Dias et al. “Recycling Crystalline Silicon Photovoltaic Modules”. Emerging Photovoltaic Materials, 2019, vol. 57, pp. 61-102. https://doi.org/10.1002/9781119407690.ch3. [cited by applicant]
Pablo Dias et al. “Comprehensive recycling of silicon photovoltaic modules incorporating organic solvent delamination—technical, environmental and economic analyses”. Resources, Conservation and Recycling, 2021, vol. 16… [cited by applicant]
Marcelo Pilotto Cenci et al. “Eco-Friendly Electronics—A Comprehensive Review”. Advanced Materials Technologies. https://doi.org/10.1002/admt.202001263, 2021. [cited by applicant]
Michael Eisenstein. “Upgrading the electronics ecosystem”. The circular economy. Springer Nature Limited., 2022, pp. 8-10, vol. 611. [cited by applicant]
Pablo Dias et al. “Electronic waste in Brazil: Generation, collection, recycling and the covid pandemic”. Cleaner Waste Systems, 3, 100022. https://doi.org/10.1016/j.clwas.2022.100022, 2022. [cited by applicant]
Pablo Dias et al. “Ensuring best E-waste recycling practices in developed countries: An Australian example”. Journal of Cleaner Production, 2019, pp. 846-854. https://doi.org/10.1016/j.jclepro.2018.10.306. [cited by applicant]
Verity Tan et al. “Estimating the Lifetime of Solar Photovoltaic Modules in Australia”. Sustainability. https://doi.org/10.3390/su14095336, 2022. [cited by applicant]
Pablo Dias et al. “High yield, low cost, environmentally friendly process to recycle silicon solar panels: Technical, economic and environmental feasibility assessment”. Renewable and Sustainable Energy Reviews. https:/… [cited by applicant]
Pablo Dias et al. “Lead hazard evaluation for cathode ray tube monitors in Brazil”. Brazilian Journal of Chemical Engineering, 2018, vol. 35, pp. 43-49. https://doi.org/10.1590/0104-6632.20180351s20160367. [cited by applicant]
Pablo Dias et al. “Photovoltaic solar panels of crystalline silicon: Characterization and separation”. Waste Management & Research: The Journal for a Sustainable Circular Economy, 2016, vol. 34(3), pp. 235-245. https://… [cited by applicant]
Priscila Silva Silveira Camaargo et al. “Photovoltaic Module Recycling: Thermal Treatment to Degrade Polymers and Concentrate Valuable Metals”. Detritus, 2021, vol. 16, pp. 48-62. https://doi.org/10.31025/2611-4135/2021… [cited by applicant]
Pablo Dias et al. “Recycling Waste Crystalline Silicon Photovoltaic Modules by Electrostatic Separation”. Journal of Sustainable Metallurgy, 2018, pp. 176-186, https://doi.org/10.1007/s40831-018-0173-5. [cited by applicant]
Pablo Dias et al. “Recycling WEEE: Extraction and concentration of silver from waste crystalline silicon photovoltaic modules”. Waste Management, 2016, vol. 57, pp. 220-225. https://doi.org/10.1016/j.wasman.2016.03.016. [cited by applicant]
Pablo Dias et al. “Recycling WEEE: Polymer characterization and pyrolysis study for waste of crystalline silicon photovoltaic modules”. Waste Management, 2017, vol. 60, pp. 716-722. https://doi.org/10.1016/j.wasman.2016… [cited by applicant]
Rong Deng et al. “Remanufacturing end-of-life silicon photovoltaics: Feasibility and viability analysis”. Progress in Photovoltaics: Research and Applications, 2020, pp. 760-774, https://doi.org/10.1002/pip.3376. [cited by applicant]
Alison Lennon et al. The aluminium demand risk of terawatt photovoltaics for net zero emissions by 2050. Nature Sustainability, 2022, pp. 357-363, https://doi.org/10.1038/s41893-021-00838-9. [cited by applicant]
Brett Hallam et al. “The silver learning curve for photovoltaics and projected silver demand for net-zero emissions by 2050”. Progress in Photovoltaics: Research and Applications, 2022, https://doi.org/10.1002/pip.3661. [cited by applicant]
Pablo Dias et al. “Waste electric and electronic equipment (WEEE) management: A study on the Brazilian recycling routes”. Journal of Cleaner Production, 2018, pp. 7-16. https://doi.org/10.1016/j.jclepro.2017.10.219. [cited by applicant]
Pablo Dias et al. “Waste electrical and electronic equipment (WEEE) management: An analysis on the australian e-waste recycling scheme”. Journal of Cleaner Production, 2018, pp. 750-764. https://doi.org/10.1016/j.clepro… [cited by applicant]
Md Tasbirul Islam et al. “Waste mobile phones: A survey and analysis of the awareness, consumption and disposal behavior of consumers in Australia”. Journal of Environmental Management, 2020, https://doi.org/10.1016/j.i… [cited by applicant]
Pablo Dias et al. “What drives WEEE recycling? A comparative study concerning legislation, collection and recycling”. Waste Management & Research: The Journal for a Sustainable Circular Economy, 2022, https://doi.org/10… [cited by applicant]
Md Tasbirul Islam et al. “Young consumers' e-waste awareness, consumption, disposal, and recycling behavior: A case study of university students in Sydney, Australia”. Journal of Cleaner Production, 2021, https://doi.or… [cited by applicant]
A. Krummenauer et al. “Determining the LOD and LOQ in steel alloys analysis using NITON spectrometer”. Journal of Physics: Conference Series, 2021, https://doi.org/10.1088/1742-6596/1826/1/012008. [cited by applicant]
A. Krummenauer et al. “Estimation of measurement uncertainty in the EDXRF spectrometry of stainless steel”. Journal of Physics: Conference Series, 2021, https://doi.org/10.1088/1742-6596/1826/1/012011. [cited by applicant]
Md Tasbirul Islam et al. “Comparison of E-Waste Management in Switzerland and in Australia: A Qualitative Content Analysis.” World Academy of Science, Engineering and Technology International Journal of Environmental an… [cited by applicant]
P.R. Dias. “Recycling waste solar modules using organic solvents.” http://uest.ntua.gr/heraklion2019/proceedings/pdf/74_HERAKLION%202019_Dias_etal.pdf. 2020, pp. 21-24. [cited by applicant]
Keith Burrows et al., “Glass needs for a Growing Photovoltaics Industry”, Solar Energy Materials and Solar Cells, Jan. 2015, p. 1-13, vol. 132. [cited by applicant]
Archivist, “Saint-Gobain Produces the First Zero-Carbon Flat Glass”, Energy & Environment Jun. 2022, USGlass Magazine & USGNN Headline News, Jun. 27, 2022. [cited by applicant]
Eckersley O'Callaghan, “Climate Friday | Glass—The recyclable material we're not recycling”, EOC Engineers, Jul. 14, 2021. [cited by applicant]
T. M. Bruton et al. “Re-Cycling of High Value, High Energy Content Components of Silicon PV Modules”, 12h European Photovoltaic Solar Energy Conference, 1994, pp. 302-305, Amsterdam, The Netherlands. [cited by applicant]
Valeria Fiandra et al. “Silicon photovoltaic modules at end-of-life: Removal of polymeric layers and separation of materials”, Waste Management, 2019, pp. 97-107, vol. 87, Italy. [cited by applicant]
Cynthia Latunussa et al. “Life Cycle Assessment of an innovative recycling process for crystalline silicon photovoltaic panels”, Solar Energy Materials & Solar Cells, 2016, pp. 101-111, vol. 156, Italy. [cited by applicant]
Dion Thompson “Thermal Treatment of End of Life PV Modules”, School of Photovoltaic and Renewable Energy Engineering Faculty of Engineering, The University of New South Wales, Nov. 25, 2019. [cited by applicant]
Priscila Silva Silveira Camargo, “Recycling of Crystalline Silicon Photovoltaic Modules: Separation and Concentration of Materials”, Universidade Federal do Rio Grande do Sul School of Engineering Dissertation, May 2021… [cited by applicant]
Priscila Silva Silveira Camargo et al., “c-Si PV Module Recycling: Analysis of the use of a Mechanical Pre-treatment to Reduce the Environmental Impact of Thermal Treatment and Enhance Materials Recovery,” Waste Managem… [cited by applicant]
Zisheng Zhang et al. “Electrostatic separation for recycling silver, silicon and polyethylene terephthalate from waste photovoltaic cells”, Modern Physics Letters B, World Scientific 2017, Abstract page, vol. 31, Issue … [cited by applicant]
“Machine learning-powered module end-of-life decisions from luminescence images”, Asia-Pacific Solar Research Conference, Nov.-Dec. 2022, 4 pgs., Newcastle, Australia. [cited by applicant]
Brendan Wright et al. “Machine learning-powered module end-of-life decision making based on luminescence images”, The University of New South Wales, Sydney, Australia. [cited by applicant]
Matthias Demant et al. “Micro-Cracks in Silicon Wafers and Solar Cells Detection and Rating of Mechanical Strength and Electrical Quality”, In Proceedings of the 29th Solar Energy Conference and Exhibition, 2014, p. 390… [cited by applicant]
Matthias Demant et al. “Microcracks in Silicon Wafers I: Inline Detection and Implications of Crack Morphology on Wafer Strength”, IEEE Journal of Photovoltaics, Jan. 2016, pp. 126-135, vol. 6, No. 1. [cited by applicant]
Matthias Demant et al. “Deep Learning Approach to Inline Quality Rating and Mapping of Multi Crystalline Si-Wafers”, In Proceedings of the 35th European Photovoltaic Solar Energy Conference and Exhibition, Sep. 2018, p.… [cited by applicant]
Sachin Mehta et al. “Deepsolareye Power Loss Prediction and Weakly Supervised Soiling Localization via Fully Convolutional Networks for Solar Panels”, arXiv:1710.03811v1, Oct. 2017, pp. 333-342. [cited by applicant]
M. Wagar Akram et al. “CNN based automatic detection of photovoltaic cell defects in electroluminescence images”, ScienceDirect, Dec. 2019, vol. 189. pp. 1-8. [cited by applicant]
S. Prabhakaran et al. “Deep Learning-Based Model for Defect Detection and Localization on Photovoltaic Panels”, Computer Systems Science & Engineering, 2022, pp. 1-18. [cited by applicant]
Xiaolong Zhao et al. “HRNet-based automatic identification of photovoltaic module defects using electroluminescence images”, ScienceDirect, Mar. 2023, vol. 267, pp. 1-7. [cited by applicant]
Sharmarke Hassan et al. “Dual spin max pooling convolutional neural network for solar cell crack detection”, Scientific reports, 2023, pp. 1-16, www.nature.com/scientificreports, https://doi.org/10.1038/s41598-023-38177… [cited by applicant]
Fatma Mazen et al. “Deep Learning for Automatic Defect Detection in PV Modules using Electroluminescence Images”, IEEE Access, 2023, vol. 11, p. 57783-57795. [cited by applicant]
Jinxia Zhang et al. “A lightweight network for photovoltaic cell defect detection in electroluminescence images of heterojunction solar cells”, arXiv:2302.07455v, Feb. 2023, pp. 1-12. [cited by applicant]
Alexey Korovin et al. “Anomaly detection in electroluminescence images of heterojunction solar cells” ScienceDirect, 2023, vol. 259, p. 130-136. [cited by applicant]
Aidong Chen et al. “Anomaly Detection Algorithm for Photovoltaic Cells Based on Lightweight Multi-Channel Spatial Attention Mechanism”, Energies, 2023, pp. 1-15, vol. 16, Issue 4. [cited by applicant]
Samuel G. Muller et al. “TrivialAugment: Tuning-free Yet State-of-the-Art Data Augmentation”, In Proceedings of the IEEE/CVF international conference on computer vision, 2021, pp. 774-782. [cited by applicant]
Alexey Dosovitsky et al. “An image is worth 16x16 words Transformers for image recognition at scale”, Published as a conference paper at ICLR, 2021, pp. 1-22. [cited by applicant]
Ilya Loshchilov et al. “Decoupled Weight Decay Regularization”, Published as a conference paper at ICLR, 2019, pp. 1-8, Freiburg, Germany. [cited by applicant]
Haiyong Chen et al. “Solar cell surface defect inspection based on multispectral convolutional neural network”, Journal of Intelligent Manufacturing, 2020, vol. 31, p. 1-14. [cited by applicant]
International Search Report and Written Opinion for related PCT/US2023/066010, mailed Aug. 9, 2023. [cited by applicant]