ELECTRODE PLATE, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND ELECTRIC APPARATUS
A secondary battery includes an electrode plate including a current collector, a functional layer, and an active material layer. At least a portion of a surface of the current collector includes a plurality of protruding portions and a plurality of recessed portions. The functional layer is disposed in one or more of the plurality of recessed portions. The active material layer covers and contacts the current collector and the functional layer. The functional layer includes at least one of a polymer material or a positive temperature coefficient (PTC) material.
1 . A secondary battery, comprising:
an electrode plate comprising:
a current collector, at least a portion of a surface of the current collector comprising a plurality of protruding portions and a plurality of recessed portions;
a functional layer disposed in one or more of the plurality of recessed portions; and
an active material layer covering and contacting the current collector and the functional layer;
wherein the functional layer comprises at least one of a polymer material or a positive temperature coefficient (PTC) material.
2 . The secondary battery according to claim 1 , wherein the active material layer covers the functional layer and the protruding portions, that are not covered by the functional layer, on the surface of the current collector.
3 . The secondary battery according to claim 1 , wherein:
a surface roughness of the surface of the current collector is greater than or equal to 1 μm.
4 . The secondary battery according to claim 3 , wherein the surface roughness is in a range of 1.5 μm-50 μm.
5 . The secondary battery according to claim 3 , wherein the surface roughness is in a range of 1.5 μm-10 μm.
6 . The secondary battery according to claim 5 , wherein the surface roughness is in a range of 1.5 μm-6 μm.
7 . The secondary battery according to claim 1 , wherein the at least one of the polymer material or the PTC material is in a form of particles, and a median particle size by volume of the particles is in a range of 0.1 μm-10 μm
8 . The secondary battery according to claim 7 , wherein the median particle size by volume of the particles is in a range of 0.1 μm-2 μm.
9 . The secondary battery according to claim 1 , wherein:
the functional layer comprises the polymer material; and
the polymer material comprises at least one of polyethylene, ethylene copolymer, polypropylene, polyvinylidene fluoride, polymethyl methacrylate, polystyrene, ethylene propylene rubber, cis-polybutadiene, polyamide, polyaniline, polyphenylene sulfide, copolymer of olefin monomer and acid anhydride monomer, or a polyblend of one or more of polycaprolactone, polylactide, and polyvalerolactone and one or more of polyethylene oxide, polyethylene oxide, polypropylene oxide, and polytetramethylene oxide.
10 . The secondary battery according to claim 9 , wherein the polymer material comprises polyethylene, polyvinylidene fluoride, or polymethyl methacrylate.
11 . The secondary battery according to claim 1 , wherein:
the functional layer comprises the PTC material; and
the PTC material comprises at least one of a bismuth titanate modified material, barium titanate, a barium titanate modified material, vanadium oxide, or a vanadium oxide modified material
12 . The secondary battery according to claim 11 , wherein the PTC material comprises barium titanate.
13 . The secondary battery according to claim 1 , wherein:
the functional layer comprises a conductive material; and
the conductive material comprises at least one of a conductive metal material, a conductive metal oxide material, a conductive metal carbide material, a conductive polymer material, or a conductive carbon-based material
14 . The secondary battery according to claim 13 , wherein the conductive material comprises one or more of conductive metal powder or metal oxide powder, tungsten carbide powder, carbon black, graphite fiber, carbon nanotube, graphene, and graphite sheet.
15 . The secondary battery according to claim 1 , wherein:
the electrode plate is at least one of a positive electrode plate or a negative electrode plate.
16 . The secondary battery according to claim 1 , wherein:
the active material layer comprises at least one of lithium transition metal oxide, olivine-structured lithium-containing phosphate, a modified compound of the lithium transition metal oxide, or a modified compound of the olivine-structured lithium-containing phosphate;
the lithium transition metal oxide comprises one or more of lithium cobalt oxide, lithium nickel oxide, lithium manganese oxide, lithium nickel cobalt oxide, lithium manganese cobalt oxide, lithium nickel manganese oxide, lithium nickel cobalt manganese oxide, and lithium nickel cobalt aluminum oxide; and
the olivine-structured lithium-containing phosphate comprises one or more of lithium iron phosphate, a composite material of lithium iron phosphate and carbon, lithium manganese phosphate, a composite material of lithium manganese phosphate and carbon, lithium manganese iron phosphate, and a composite material of lithium manganese iron phosphate and carbon.
17 . A battery pack, comprising:
a secondary battery comprising an electrode plate comprising:
a current collector, at least a portion of a surface of the current collector comprising a plurality of protruding portions and a plurality of recessed portions;
a functional layer disposed in one or more of the plurality of recessed portions; and
an active material layer covering and contacting the current collector and the functional layer;
wherein the functional layer comprises at least one of a polymer material or a positive temperature coefficient (PTC) material.
18 . An electric apparatus, comprising:
a secondary battery comprising an electrode plate comprising:
a current collector, at least a portion of a surface of the current collector comprising a plurality of protruding portions and a plurality of recessed portions;
a functional layer disposed in one or more of the plurality of recessed portions; and
an active material layer covering and contacting the current collector and the functional layer;
wherein the functional layer comprises at least one of a polymer material or a positive temperature coefficient (PTC) material.