Efficient and stable p-i-n structured perovskite solar cells
The present disclosure relates to a composition that includes a perovskite having a surface, where the surface includes a pyridine compound. In some embodiments of the present disclosure, the pyridine compound may include an amine functional group. In some embodiments of the present disclosure, the pyridine compound may be selected from a group that includes N(2-methylpyridine)A, N(3-methylpyridine)A, N(4-(methyl)pyridine)A, N(3-(2-ethyl)pyridine)A, and N(4-(2-ethyl)pyridine)A, where A is a cation, and the pyridine compound has an ionic radius larger than 10 Å.
1. A composition comprising:
a perovskite comprising a stoichiometry of ABX 3 ; and
a pyridine compound, wherein:
A is a first cation comprising formamidinium, B is a second cation, and X is an anion,
the perovskite is in a form of a layer comprising a thickness and a surface,
the pyridine compound is located primarily at the surface of the layer, and
the pyridine compound comprises at least one of
2. The composition of claim 1 , wherein A further comprises at least one of methylammonium, ethylammonium, diethylammonium, guanidinium, cesium or rubidium.
3. The composition of claim 1 , wherein the layer has a thickness between 50 nm and 5000 nm.
4. The composition of claim 3 , wherein the thickness is between 30 nm and 1000 nm.
5. The composition of claim 3 , wherein the pyridine compound is present as a layer positioned on the layer of the perovskite.
6. The composition of claim 5 , wherein the layer of the pyridine compound has a thickness greater than 5 Å.
7. The composition of claim 1 , wherein the surface has a surface roughness of less than or equal to 1 nm, as measured over a length scale between 10 nm and 20 nm.
8. The composition of claim 1 , wherein the surface has a surface potential fluctuation of less than 20 mV, as measured over a length scale between 10 nm and 20 nm.
9. The composition of claim 1 , wherein B comprises at least one of tin or lead.
10. The composition of claim 1 , wherein X comprises a halogen.
11. A device comprising:
a pyridine compound;
a perovskite layer comprising a stoichiometry of ABX 3 ; and
a charge transport layer (CTL), wherein:
the surface of the perovskite layer forms an interface with the CTL,
A is a first cation comprising formamidinium, B is a second cation, and X is an anion,
the perovskite layer has a layer having a thickness and a surface,
the pyridine compound is located primarily at the interface,
the surface has a surface roughness less than or equal to 1 nm, as measured over a length scale between 10 nm and 20 nm, and
the pyridine compound comprises at least one of
12. The device of claim 11 , wherein the surface is characterized by surface potential fluctuations of less than 20 mV.
13. A method comprising:
treating a surface of a perovskite layer with an amine-functionalized pyridine, wherein:
the perovskite layer comprises a stoichiometry of ABX 3 :
A is a first cation comprising formamidinium, B is a se and cation, and X is an anion,
the treating converts the amine-functionalize pyridine to a pyridine compound comprising at least one of
the pyridine compound is located primarily at the surface of the perovskite layer, and
the treating reduces at least one of a surface roughness of the surface or a surface potential fluctuation.
14. The method of claim 13 , wherein the surface roughness is less than or equal to 1 nm, as measured over a length scale between 10 nm and 20 nm.