SECONDARY BATTERY
A secondary battery, including a negative electrode plate and an electrolyte are provided. In some embodiments, the negative electrode plate includes a negative electrode current collector and a negative electrode active substance layer, a first metal oxide layer, and a second metal ion adsorption layer that are sequentially arranged on at least one surface of the negative electrode current collector; the first metal oxide is selected from at least one of manganese dioxide, molybdenum oxide, magnesium oxide, aluminum oxide, and phosphorus pentoxide; and the electrolyte contains second metal ions. In the secondary battery provided in this application, the first metal oxide layer is provided on the negative electrode plate, and the second metal ion adsorption layer is formed on a negative electrode to serve as a protective layer, thereby inhibiting decomposition of electrolytes and improving cycling performance and rate performance of battery cells.
1 . A secondary battery, comprising a negative electrode plate and an electrolyte, wherein
the negative electrode plate comprises a negative electrode current collector and a negative electrode active substance layer, a first metal oxide layer, and a second metal ion adsorption layer that are sequentially arranged on at least one surface of the negative electrode current collector;
the first metal oxide is selected from at least one of manganese dioxide, molybdenum oxide, magnesium oxide, aluminum oxide, or phosphorus pentoxide; and
the electrolyte contains second metal ions.
2 . The secondary battery according to claim 1 , wherein
ionic radius of the second metal ion is less than or equal to 0.92 nm.
3 . The secondary battery according to claim 1 , wherein
the second metal ions are selected from at least one of Li + , Cr 3+ , Ca 2+ , K + , Na + , Mo 6+ , and Fe 2+ , and optionally, at least one of Li + , Cr 3+ , Mo 6+ , or Fe 2+ .
4 . The secondary battery according to claim 1 , wherein
a thickness of the first metal oxide layer is 0.1 nm-10 nm.
5 . The secondary battery according to claim 4 , wherein
the thickness of the first metal oxide layer is 0.5 nm-5 nm.
6 . The secondary battery according to claim 1 , wherein
the second metal ions are provided by at least one salt selected from LiCl, CrCl 3 , CaCl 2 ), KCl, NaCl, MoCl 6 , or FeCl 2 .
7 . The secondary battery according to claim 1 , wherein
concentration of the second metal ions in the electrolyte is less than 0.1 mol/L.
8 . The secondary battery according to claim 7 , concentration of the second metal ions in the electrolyte is less than 0.05 mol/L.
9 . The secondary battery according to claim 1 , wherein
a thickness of a solid electrolyte interphase film (SEI film) formed on a surface of a negative electrode is less than 40 nm.
10 . The secondary battery according to claim 9 , the thickness of the SEI film formed on a surface of a negative electrode is 10 nm-35 nm.
11 . The secondary battery according to claim 1 , wherein
the first metal oxide layer is formed by atomic layer deposition (ALD).
12 . A battery pack, comprising the secondary battery according to claim 1 .
13 . An electric apparatus, comprising at least one of the secondary battery according to claim 1 , or the battery pack according to claim 10 .