IP Library Granted Patent US 12,084,580
Granted Patent B2
US 12,084,580 · App. 18/331,261 · Granted Sep 10, 2024

Nickel oxide sol-gel ink

Inventors: Michael Irwin (Heath, TX); Erin Sanehira (Dallas, TX)
Assignee: CubicPV Inc.
C09D1/00B05D3/0254C03C17/25C03C2217/217C03C2218/113C03C2218/32
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Quick Facts
Patent No.
US 12,084,580
App. No.
18/331,261
Granted
Sep 10, 2024
Kind
B2
Abstract

A method for forming a nickel oxide layer is disclosed herein. In some embodiments, a method includes depositing a nickel oxide precursor ink on a substrate, wherein the nickel oxide precursor ink comprises a solvent comprising diols, alcohol amines, and water, Ni(NO 3 ) 2 ·6H 2 O, and at least one metal acetate selected from the group consisting of Ni(CH 3 CO 2 ) 2 ·4H 2 O and Cu(CH 3 CO 2 ) 2 ·1H 2 O, annealing the nickel oxide precursor ink at a temperature between 250° to 400° Celsius for between 10 minutes and 6 hours to form a nickel oxide layer, and cooling the nickel oxide layer.

Claims (12)

1. A method for forming a nickel oxide layer on a substrate, comprising:

depositing a nickel oxide precursor ink on a substrate, wherein the nickel oxide precursor ink comprises:

a solvent comprising diols, alcohol amines, and water;

Ni(NO 3 ) 2 ·6H 2 O; and

at least one metal acetate selected from the group consisting of Ni(CH 3 CO 2 ) 2 ·4H 2 O and Cu(CH 3 CO 2 ) 2 ·1H 2 O;

annealing the nickel oxide precursor ink at a temperature between 250° to 400° Celsius for between 10 minutes and 6 hours to form a nickel oxide layer; and

cooling the nickel oxide layer.

2. The method of claim 1 , wherein: the solvent comprises ethylene glycol, ethanolamine and water.

3. The method of claim 1 , wherein the substrate is selected from the group consisting of glass, p-doped silicon, n-doped silicon, sapphire, magnesium oxide, mica, polymers, ceramics, fabrics, wood, drywall, metal, ITO-coated glass, FTO-coated glass, or combinations thereof.

4. The method of claim 1 , wherein the substrate is coated with a conductive material selected from the group consisting of group consisting of indium-doped tin oxide (ITO), fluorine-doped tin oxide (FTO), cadmium oxide (CdO), zinc indium tin oxide (ZITO), aluminum zinc oxide (AZO), aluminum (Al), gold (Au), calcium (Ca), magnesium (Mg), titanium (Ti), steel, chromium (Cr), copper (Cu), silver (Ag), nickel (Ni), tungsten (W), molybdenum (Mo), carbon, and combinations thereof.

5. The method of claim 1 , wherein the nickel oxide precursor ink is deposited on the substrate under an environment having a humidity between 10% and 50% and a temperature between 20° and 60° Celsius.

6. The method of claim 1 , wherein the annealing takes place at a temperature of 310° Celsius for a time period of two hours.

Assignments (5)
CORRECTIVE ASSIGNMENT TO CORRECT THE SECOND ASSIGNOR'S LAST NAME ON THE COVER SHEET PREVIOUSLY RECORDED AT REEL: 063891 FRAME: 0674. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 16, 2023
From: IRWIN, MICHAEL D.; SANEHIRA, ERIN
To: HEE SOLAR, L.L.C.
Reel/Frame 064007/0503 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2023
From: IRWIN, MICHAEL D.; SENEHIRA, ERIN
To: HEE SOLAR, L.L.C.
Reel/Frame 063891/0674 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2023
From: CUBIC PEROVSKITE LLC
To: CUBICPV INC.
Reel/Frame 063916/0746 →
CHANGE OF NAME Recorded Jun 8, 2023
From: HEE SOLAR, L.L.C.
To: HUNT PEROVSKITE TECHNOLOGIES, L.L.C.
Reel/Frame 063917/0453 →
CHANGE OF NAME Recorded Jun 8, 2023
From: HUNT PEROVSKITE TECHNOLOGIES, L.L.C.
To: CUBIC PEROVSKITE LLC
Reel/Frame 063917/0497 →
Continuity (4)
Division 17136503 · Dec 29, 2020
Division 16577781 · Sep 20, 2019
Provisional Application 62770389 · Nov 21, 2018
Related Publication 20230312936A1 · Oct 5, 2023
Cited By (1)
US 12,437,933