Tungsten oxide powder and electrochromic device using the same
According to one embodiment, provided is a tungsten oxide powder including primary particles having an average particle size of 100 nm or less. Each of the primary particles include a crystal phase and an amorphous phase coexisting in each primary particle.
1. A tungsten oxide powder comprising secondary particles, the secondary particles comprising primary particles having an average particle size of 100 nm or less, each of the primary particles comprising a crystal phase and an amorphous phase coexisting in each primary particle,
wherein in each of the primary particles, the amorphous phase is present at a range of 80% to 100% of a peripheral length of the crystal phase, and the primary particles in the secondary particles are bonded via the amorphous phases thereof.
2. The tungsten oxide powder according to claim 1 , wherein in each of the primary particles, the amorphous phase is present at 100% of a peripheral length of the crystal phase.
3. The tungsten oxide powder according to claim 1 , wherein a ratio B 1 /A 1 of an area B 1 of the amorphous phase to an area A 1 of the crystal phase in each of the primary particles is within a range of 0.2 to 0.8.
4. The tungsten oxide powder according to claim 1 , wherein the average particle size is within a range of 5 nm to 20 nm.
5. The tungsten oxide powder according to claim 1 , comprising a tungsten oxide powder containing 0.01 mol % to 50 mol % of any one or more selected from the group consisting of potassium, sodium, lithium, and magnesium.
6. The tungsten oxide powder according to claim 1 , wherein a maximum width of the amorphous phase in each of the primary particles is 0.1 nm to 5 nm.
7. The tungsten oxide powder according to claim 6 , wherein a ratio B 1 /A 1 of an area B 1 of the amorphous phase to an area A 1 of the crystal phase in each of the primary particles is within a range of 0.2 to 0.8.
8. The tungsten oxide powder according to claim 7 , wherein the average particle size is within a range of 5 nm to 20 nm.
9. The tungsten oxide powder according to claim 8 , wherein a ratio B 2 /A 2 of an area B 2 of the amorphous phase to an area A 2 of the crystal phase in the secondary particles is within a range of 0.2 to 0.8.
10. The tungsten oxide powder according to claim 8 , for use in an electrochromic device.
11. The tungsten oxide powder according to claim 1 , for use in an electrochromic device.
12. An electrochromic device comprising an electrochromic layer, the electrochromic layer comprising the tungsten oxide powder according to claim 1 .
13. The electrochromic device according to claim 12 , wherein the electrochromic layer has a volume resistance value of 1×10 5 Ω·cm or less.