Spherical particles comprising nanoclay-filled-polymer and methods of production and uses thereof
Methods for producing highly spherical particles that comprise: mixing a mixture comprising: (a) nanoclay-filled-polymer composite comprising a nanoclay dispersed in a thermoplastic polymer, (b) a carrier fluid that is immiscible with the thermoplastic polymer of the nanoclay-filled-polymer composite, optionally (c) a thermoplastic polymer not filled with a nanoclay, and optionally (d) an emulsion stabilizer at a temperature at or greater than a melting point or softening temperature of the thermoplastic polymer of the nanoclay-filled-polymer and the thermoplastic polymer, when included, to disperse the nanoclay-filled-polymer composite in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form nanoclay-filled-polymer particles; and separating the nanoclay-filled-polymer particles from the carrier fluid.
1. A method of selective laser sintering, comprising:
depositing nanoclay-filled-polymer particles, optionally in combination with other thermoplastic polymer particles, onto a surface;
wherein the nanoclay-filled-polymer particles comprise a nanoclay dispersed in a thermoplastic polymer and the other thermoplastic polymer particles, if present, lack a nanoclay; and
wherein the nanoclay-filled-polymer particles further comprise an emulsion stabilizer; and
once deposited, fusing the nanoclay-filled-polymer particles together to form a consolidated body.
2. The method of claim 1 , wherein fusing the nanoclay-filled-polymer particles together takes place by selective laser sintering.
3. The method of claim 1 , wherein the nanoclay comprises exfoliated clay platelets.
4. The method of claim 1 , wherein the nanoclay comprises 1 layer to 10 layer particles.
5. The method of claim 1 , wherein the nanoclay comprises a quaternary ammonium compound.
6. The method of claim 1 , wherein the emulsion stabilizer coats at least a portion of an outer surface of the nanoclay-filled-polymer particles.
7. The method of claim 6 , wherein the emulsion stabilizer comprises a plurality of nanoparticles.
8. The method of claim 7 , wherein the plurality of nanoparticles comprises a plurality of oxide nanoparticles.
9. The method of claim 8 , wherein the plurality of oxide nanoparticles comprises a plurality of silica nanoparticles.
10. The method of claim 7 , wherein the emulsion stabilizer comprises about 0.01 wt % to about 10 wt % of the nanoclay-filled-polymer particles, based on a total weight of the nanoclay-filled-polymer particles.
11. The method of claim 1 , wherein the nanoclay-filled-polymer particles have a D50 ranging from about 20 μm to about 80 μm and a diameter span of about 2 or less.
12. The method of claim 1 , wherein the thermoplastic polymer of the nanoclay-filled-polymer particles comprises a polyamide, a polyolefin, a polyurethane, or any combination thereof.
13. The method of claim 1 , wherein the other thermoplastic polymer particles are present.
14. The method of claim 13 , wherein the other thermoplastic polymer particles comprise a thermoplastic polymer selected from the group consisting of a polyamide, a polyolefin, a polyurethane, and any combination thereof.
15. The method of claim 1 , wherein the nanoclay-filled-polymer particles have a circularity of about 0.9 or greater.
16. The method of claim 1 , wherein the nanoclay-filled-polymer particles comprise about 0.05 wt % to about 20 wt % of the nanoclay.