IP Library Granted Patent US 12,101,948
Granted Patent B2
US 12,101,948 · App. 18/351,880 · Granted Sep 24, 2024

Systems and methods for organic semiconductor devices with sputtered contact layers

Inventors: Scott R. Hammond (Wheat Ridge, CO); Marinus Franciscus Antonius Maria van Hest (Golden, CO)
Assignees: Alliance for Sustainable Energy, LLC; SolarWindow Technologies, Inc.
H10K30/82H10K50/11H10K50/15H10K50/16H10K50/816H10K50/828H10K71/16H10K71/60H10K2102/101H10K2102/103Y02E10/549
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Quick Facts
Patent No.
US 12,101,948
App. No.
18/351,880
Granted
Sep 24, 2024
Kind
B2
Abstract

Systems and methods for organic semiconductor devices with sputtered contact layers are provided. In one embodiment, an organic semiconductor device comprises: a first contact layer comprising a first sputter-deposited transparent conducting oxide; an electron transport layer interfacing with the first contact layer; a second contact layer comprising a second sputter-deposited transparent conducting oxide; a hole transport layer interfacing with the second contact layer; and an organic semiconductor active layer having a first side facing the electron transport layer and an opposing second side facing the hole transport layer; wherein either the electron transport layer or the hole transport layer comprises a buffering transport layer.

Claims (38)

1. An organic photovoltaic module, the module comprising:

a plurality of electrically interconnected organic photovoltaic cells applied to a common substrate, wherein each of the plurality of electrically interconnected organic photovoltaic cells comprises:

a backside transparent contact layer;

a backside collection layer interfacing with the backside transparent contact layer;

an organic semiconductor absorber layer;

a front side buffering collection layer applied over the organic semiconductor absorber layer; and

a sputter-deposited transparent material contact layer applied over the front side buffering collection layer; and

a plurality of scribes that separate the plurality of electrically interconnected organic photovoltaic cells from each other, wherein the plurality of scribes extend into the front side buffering collection layer, the backside collection layer, and the organic semiconductor absorber layer,

wherein the sputter-deposited transparent material contact layer of a first of the plurality of electrically interconnected organic photovoltaic cells further extends into the plurality of scribes and electrically connects with a backside transparent contact layer of a second of the plurality of electrically interconnected organic photovoltaic cells.

2. The module of claim 1 , wherein the common substrate is semi-transparent in a visible light spectrum.

3. The module of claim 1 , wherein the front side buffering collection layer is a hole collection layer comprising a transparent polymer material, semi-transparent polymer material, a transparent oxide material, or semi-transparent metal oxide material; and

wherein the backside collection layer is an electron collection layer.

4. The module of claim 1 , wherein the sputter-deposited transparent material contact layer comprises a sputtered transparent conducting oxide.

5. The module of claim 4 , wherein the sputter-deposited transparent conducting oxide comprises a sputtered indium zinc oxide (IZO).

6. The module of claim 1 , wherein at least one of the backside transparent contact layer or the sputter-deposited transparent material contact layer comprise at least one of:

sputtered indium zinc oxide (IZO);

sputtered indium tin oxide (ITO);

sputtered aluminum doped zinc oxide (AZO); or

sputtered gallium doped zinc oxide (GZO).

7. The module of claim 1 , wherein the organic semiconductor absorber layer comprises either an organic bulk heterojunction structure or a bilayer structure.

8. The module of claim 1 , further comprising an electrically insulating material deposited into the plurality of scribes.

9. An organic photovoltaic module, the module comprising:

a plurality of electrically interconnected organic photovoltaic cells applied to a common substrate, wherein each of the plurality of electrically interconnected organic photovoltaic cells comprises:

an organic semiconductor active layer deposited on one or more backside device layers;

a buffering transport layer over the organic semiconductor active layer;

a plurality of scribes that extend into the buffering transport layer, the organic semiconductor active layer, and the one or more backside device layers; and

a conductive material layer deposited on the buffering transport layer and into the plurality of scribes, wherein the conductive material layer is configured to electrically connect to a back contact layer within the one or more backside device layers.

10. The module of claim 9 , wherein the common substrate is semi-transparent in a visible light spectrum.

11. The module of claim 9 , further comprising an electrically insulating material deposited into the plurality of scribes.

12. The module of claim 9 , wherein the conductive material layer comprises a transparent conducting oxide.

13. The module of claim 12 , wherein the transparent conducting oxide comprises an indium zinc oxide (IZO).

14. The module of claim 12 , wherein the transparent conducting oxide comprises an indium tin oxide (ITO).

15. The module of claim 12 , wherein the transparent conducting oxide comprises an aluminum doped zinc oxide (AZO).

16. The module of claim 12 , wherein the transparent conducting oxide comprises a gallium doped zinc oxide (GZO).

17. The module of claim 9 , wherein the buffering transport layer comprises at least one of a transparent polymer material, a semi-transparent polymer material, a transparent oxide material or semi-transparent oxide material.

18. The module of claim 9 , wherein the organic semiconductor active layer comprises an organic bulk heterojunction structure.

19. The module of claim 9 , wherein the organic semiconductor active layer comprises a bilayer structure.

20. The module of claim 9 , wherein the organic semiconductor active layer comprises an organic emissive electroluminescent layer.

Assignments (2)
CHANGE OF NAME Recorded Dec 16, 2025
From: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
To: ALLIANCE FOR ENERGY INNOVATION, LLC
Reel/Frame 073993/0276 →
CONFIRMATORY LICENSE Recorded Feb 26, 2024
From: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 066555/0932 →