IP Library Granted Patent US 12,485,690
Granted Patent B2
US 12,485,690 · App. 18/369,548 · Granted Dec 2, 2025

Ribbon for use in producing printer activatable indicators

Inventors: Eric W. Liberato (Pequannock, NJ); John Olson (Dayton, NJ); James J. O'Hagan (McHenry, IL); Mohannad Abdo (Clifton, NJ); Gene A. Hofer (Lake Zurich, IL)
Assignee: ZEBRA TECHNOLOGIES CORPORATION
B41J31/06B41J2/3355B41J3/4075B41J33/006B41J33/26
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Quick Facts
Patent No.
US 12,485,690
App. No.
18/369,548
Granted
Dec 2, 2025
Kind
B2
Abstract

Disclosed is a thermal transfer ribbon for use with a media processing device. The thermal transfer ribbon includes a carrier layer and a transfer layer operatively coupled to the carrier layer. The transfer layer includes an environmental indicator material encapsulated in a plurality of microcapsules. The plurality of microcapsules prevent the environmental indicator material from producing an observable effect in response to exposure to a predetermined environmental condition. The environmental indicator material is released from the plurality of microcapsules in response to the plurality of microcapsules being ruptured. After the environmental indicator material is released and exposed to the predetermined environmental condition, the environmental indicator material produces the observable effect. The observable effect results from a change in the environmental indicator material from an original state to a second state in response to the predetermined environmental condition.

Claims (46)

1 . A thermal transfer ribbon for use with a media processing device, the thermal transfer ribbon comprising:

a carrier layer; and

a transfer layer operatively coupled to the carrier layer, the transfer layer comprising an environmental indicator material encapsulated in a plurality of microcapsules, the plurality of microcapsules preventing the environmental indicator material from producing an observable effect in response to exposure to a predetermined environmental condition,

wherein the environmental indicator material is released from the plurality of microcapsules in response to the plurality of microcapsules being ruptured, and after the environmental indicator material is released and exposed to the predetermined environmental condition, the environmental indicator material produces the observable effect, the observable effect resulting from a change in the environmental indicator material from an original state to a second state in response to the predetermined environmental condition.

2 . The thermal transfer ribbon of claim 1 , wherein the transfer layer further comprises:

a microcapsule panel comprising the plurality of microcapsules; and

an ink panel positioned adjacent the microcapsule panel.

3 . The thermal transfer ribbon of claim 2 , wherein the ink panel spans a length of the thermal transfer ribbon and the microcapsule panel spans the same length of the thermal transfer ribbon.

4 . The thermal transfer ribbon of claim 2 , wherein the microcapsule panel spans a first length of the thermal transfer ribbon, wherein the ink panel spans a second length of the thermal transfer ribbon, and wherein the second length begins sequentially after the first length.

5 . The thermal transfer ribbon of claim 1 , wherein the media processing device is a thermal transfer printer, wherein the plurality of microcapsules are configured to be printed on a media element by the media processing device when the media processing device is used to print the media element using a thermal transfer process, and wherein the plurality of microcapsules remain intact during the thermal transfer process.

6 . The thermal transfer ribbon of claim 1 , wherein the media processing device is a thermal transfer printer, and wherein the plurality of microcapsules are configured to rupture in response to a force applied by the media processing device to a media element when the media processing device is used to transfer at least a portion of the transfer layer to the media element using a thermal transfer process.

7 . The thermal transfer ribbon of claim 6 , wherein the thermal transfer ribbon further comprises a bursting additive proximate the plurality of microcapsules.

8 . The thermal transfer ribbon of claim 7 , wherein the transfer layer further comprises the bursting additive.

9 . The thermal transfer ribbon of claim 7 , wherein the carrier layer further comprises the bursting additive, and wherein the bursting additive is aligned with regions of the transfer layer containing the plurality of microcapsules.

10 . The thermal transfer ribbon of claim 7 , wherein the bursting additive is positioned in an intermediate layer attached to the carrier layer, and wherein the bursting additive is aligned with regions of the transfer layer containing the plurality of microcapsules.

11 . The thermal transfer ribbon of claim 1 , wherein the media processing device is a thermal transfer printer, wherein the plurality of microcapsules are configured to rupture in response to a heat applied by the media processing device to a media element when the device is used to transfer at least a portion of the transfer layer to the media element using a thermal transfer process, and wherein the heat causes a temperature of the at least the portion of the plurality of microcapsules to be equal to or greater than a predetermined temperature threshold.

12 . A method of applying an environmental sensor to a media element with a media processing device, the method comprising:

feeding a media element into an upstream end of a print head assembly of the media processing device, wherein the print head assembly comprises a thermal transfer ribbon comprising:

a carrier layer; and

a transfer layer operatively coupled to the carrier layer, the transfer layer comprising an environmental indicator material encapsulated in a plurality of microcapsules, the plurality of microcapsules preventing the environmental indicator material from producing an observable effect in response to exposure to a predetermined environmental condition,

wherein the environmental indicator material is released from the plurality of microcapsules in response to the plurality of microcapsules being ruptured, and after the environmental indicator material is released and exposed to the predetermined environmental condition, the environmental indicator material produces the observable effect, the observable effect resulting from a change in the environmental indicator material from an original state to a second state in response to the predetermined environmental condition;

printing a portion of the transfer layer onto the media element by thermal transfer printing with the print head assembly, wherein the portion of the transfer layer comprises a portion of the plurality of microcapsules, wherein the portion of the plurality of microcapsules form a second plurality of microcapsules on the media element, and wherein the second plurality of microcapsules form the environmental sensor on the media element; and

feeding the media element out of a downstream end of the print head assembly.

13 . The method of claim 12 , further comprising rupturing at least a portion of the second plurality of microcapsules during the thermal transfer printing.

14 . The method of claim 12 , further comprising:

feeding the media element into an upstream end of an activation mechanism of the media processing device; and

rupturing at least a portion of the second plurality of microcapsules by passing the media element through the activation mechanism.

15 . The method of claim 12 , further comprising:

retracting the media element through the print head assembly from the downstream end toward the upstream end; and

printing a portion of the ink panel onto the media element by thermal transfer printing with the print head assembly.

16 . The method of claim 12 , further comprising:

feeding the media element into an upstream end of a second print head assembly of the media processing device, wherein the second print head assembly comprises an ink thermal transfer ribbon comprising an ink transfer layer;

printing a portion of the ink transfer layer onto the media element by thermal transfer printing with the second print head assembly; and

feeding the media element out of a downstream end of the second print head assembly.

17 . A method of forming a thermal transfer ribbon, the method comprising:

applying a release layer to a substrate;

coating the release layer with a transfer layer, the transfer layer comprising an environmental indicator material encapsulated in a plurality of microcapsules, the plurality of microcapsules preventing the environmental indicator material from producing an observable effect in response to exposure to a predetermined environmental condition,

wherein the environmental indicator material is released from the plurality of microcapsules in response to the plurality of microcapsules being ruptured, and after the environmental indicator material is released and exposed to the predetermined environmental condition, the environmental indicator material produces the observable effect, the observable effect resulting from a change in the environmental indicator material from an original state to a second state in response to the predetermined environmental condition; and

attaching a first end of the substrate to a supply spool;

attaching a second end of the substrate to a take-up spool; and

winding the substrate around the supply spool.

18 . The method of claim 17 , further comprising attaching an intermediate layer to the substrate opposite the release layer, wherein the intermediate layer comprises a bursting additive.

19 . The method of claim 17 , further comprising:

attaching an intermediate layer to the substrate, wherein the intermediate layer comprises a bursting additive; and

attaching the release layer to the intermediate layer.

20 . The method of claim 17 , further comprising coating a bursting additive onto the substrate prior to applying the release layer to the substrate.

Assignments (2)
MERGER Recorded May 29, 2025
From: TEMPTIME CORPORATION
To: ZEBRA TECHNOLOGIES CORPORATION
Reel/Frame 071548/0054 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2023
From: LIBERATO, ERIC W.; OLSON, JOHN; O'HAGAN, JAMES J.; ABDO, MOHANNAD; HOFER, GENE A.
To: TEMPTIME CORPORATION
Reel/Frame 065551/0759 →