NEGATIVE ELECTRODE PLATE, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK AND ELECTRICAL DEVICE
Embodiments of the present application provide a negative electrode plate, a secondary battery, a battery module, a battery pack and an electrical device. The negative electrode plate may comprise a negative electrode current collector; and a negative electrode active material layer, wherein the negative electrode active material layer may be disposed on at least one surface of the negative electrode current collector, and comprise, based on total weight of the negative electrode active material layer, 90.0% to 98.6% by weight of a negative electrode active material; 1.0%-5.0% by weight of a polymer binder; and 0.2%-4.0% by weight of a toughening fiber.
1 . A negative electrode plate, comprising:
a negative electrode current collector; and
a negative electrode active material layer, disposed on at least one surface of the negative electrode current collector;
wherein the negative electrode active material layer comprises, based on total weight of the negative electrode active material layer;
90.0% to 98.6% by weight of a negative electrode active material;
1.0%-5.0% by weight of a polymer binder; and
0.2%-4.0% by weight of a toughening fiber.
2 . The negative electrode plate according to claim 1 , wherein the polymer binder has a three-dimensional cross-linked network structure.
3 . The negative electrode plate according to claim 1 , wherein the polymer binder is a copolymer containing a plurality of polar functional groups.
4 . The negative electrode plate according to claim 3 , wherein the polar functional group comprises at least one of a carboxyl group, a cyano group, an amide group, an amino group or a hydroxyl group.
5 . The negative electrode plate according to claim 3 , wherein the copolymer has a weight average molecular weight of greater than or equal to 300000.
6 . The negative electrode plate according to claim 3 , wherein the copolymer is at least one selected from polyacrylic acid-acrylonitrile copolymer and derivatives thereof, acrylic acid-acrylamide and derivatives thereof, and acrylic acid-acrylates copolymer and derivatives thereof.
7 . The negative electrode plate according to claim 1 , wherein the toughening fiber has a diameter in the range of 0.1 μm-50 μm and an aspect ratio of greater than or equal to 20.
8 . The negative electrode plate according to claim 1 , wherein the toughening fiber is at least one selected from aramid fibers, plastic fibers and carbon fibers.
9 . The negative electrode plate according to claim 8 , wherein the plastic fibers are one or more selected from polyimide fibers, polyphenylene sulfide fibers, poly(p-phenylene benzobisoxazole) fibers and ultra-high molecular weight polyethylene fibers; and
the carbon fibers are one or more selected from polyacrylonitrile-based carbon fibers, asphalt-based carbon fibers and viscose based carbon fibers.
10 . A secondary battery, comprising:
a positive electrode plate;
a negative electrode plate, the negative electrode plate being the negative electrode plate of claim 1 ;
a separator, disposed between the positive electrode plate and the negative electrode plate; and
an electrolyte.
11 . A battery module, the battery module comprising the secondary battery as claimed in claim 10 .
12 . A battery pack, the battery pack comprising the battery module as claimed in claim 11 .
13 . An electrical device, comprising the secondary battery as claimed in claim 10 .