Dispersant and method of preparation thereof, slurry composition and method of preparation thereof, electrode plate and apparatus containing the electrode plate
The present application provides a dispersant and a preparation method thereof, a slurry composition and a preparation method thereof, an electrode, and an apparatus containing the electrode plate. The dispersant includes a block copolymer having a first block and a second block, the first block includes a first repeating structural unit shown in Formula I) and a second repeating structural unit shown in Formula II), and the second block includes a third repeating structural unit shown in Formula III) and a fourth repeating structural unit shown in Formula IV), in which n is any integer from 1-25, R 1 to R 7 are independently selected from hydrogen, halogen, cyano, carbonyl, carboxy, nitro, sulfonyl, amide, ester, substituted or unsubstituted C 1 -C 15 alkyl or alkoxy, and substituted or unsubstituted C 6 -C 30 aryl and R 8 , R 9 , and R 10 have a dipole moment of greater than 2×10 −30 C·m.
1. A dispersant, comprising a block copolymer having a first block and a second block, wherein
said first block comprises a first repeating structural unit shown in Formula I) and a second repeating structural unit shown in Formula II):
in which R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 are independently selected from hydrogen, halogen, cyano, carbonyl, carboxy, nitro, sulfonyl, amide, ester, substituted or unsubstituted C 1 -C 15 alkyl, substituted or unsubstituted C 1 -C 15 alkoxy, and substituted or unsubstituted C 6 -C 30 aryl; and
said second block comprises a third repeating structural unit shown in Formula III) and a fourth repeating structural unit shown in Formula IV):
in which n represents an average degree of polymerization, that is any integer from 1-25 and R 8 , R 9 and R 10 have a dipole moment of greater than 2×10 −30 C·m.
2. The dispersant as claimed in claim 1 , wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 are independently selected from hydrogen, halogen, cyano, substituted or unsubstituted C 1 -C 12 alkyl, or substituted or unsubstituted C 6 -C 12 aryl.
3. The dispersant as claimed in claim 1 , wherein said first repeating structural unit has the following structural formula:
and
said second repeating structural unit is ethylene; optionally said first block is a random copolymerization block of said first repeating structural unit and said second repeating structural unit; optionally said first block has a weight average molecular weight in the range of 1000-500000; and optionally said second block has a weight average molecular weight in the range of 1000-500000.
4. The dispersant as claimed in claim 1 , wherein said first block and second block have a ratio of an average degree of polymerization in the range of (0.1-10): 1.
5. A method of preparing a dispersant as claimed in claim 1 , comprising:
dissolving an initiator and a chain transfer agent in an organic solvent and stirring them under an inert atmosphere to obtain a mixed solution;
adding monomers of a first block to said mixed solution for a first copolymerization reaction;
after the first copolymerization reaction is complete, adding monomers of the second block for a second copolymerization reaction; and
after the second copolymerization reaction is complete, the resulting product is precipitated, filtered and dried, thereby obtaining said dispersant.
6. The method as claimed in claim 5 , wherein said stirring is carried out at rate in the range of 20 min/rpm-1500 min/rpm;
optionally, the first copolymerization reaction is carried out at a reaction temperature in the range of −20° C. to 120° C.
7. A slurry composition for forming an electrode film layer comprising the dispersant as claimed in claim 1 , a binder, an active material, and optionally a conductive agent.
8. The slurry composition as claimed in claim 7 , wherein said slurry composition comprises, relative to a total mass of the slurry composition, being 100%:
0.01%-10% of the dispersant;
0.5%-10% of a binder;
82%-91.99% of an active material; and
0%-15% of a conductive agent.
9. The slurry composition as claimed in claim 7 , wherein said active material is a positive electrode active material.
10. A method of preparing the slurry composition as claimed in claim 7 , comprising:
mixing a conductive agent, the dispersant, and a portion of a solvent with stirring to obtain a first mixture;
adding a binder to said first mixture with stirring for mixing to obtain a second mixture;
adding an active material and the remaining solvent to said second mixture with stirring for mixture to obtain said slurry composition.
11. An electrode plate, comprising,
a current collector;
an active material layer, disposed on at least one surface of said current collector, said active material layer being formed from the slurry composition as claimed in claim 7 .
12. A secondary battery, comprising,
a positive electrode plate;
a negative electrode plate; and
a separator, provided between said positive electrode plate and said negative electrode plate;
wherein said positive electrode plate and/or said negative electrode plate are the electrode plate as claimed in claim 11 .
13. A battery module comprising the secondary battery as claimed in claim 12 .
14. A battery pack comprising the battery module as claimed in claim 13 .
15. An electric device comprising the battery pack as claimed in claim 14 .