Silicon carbide coatings and methods of fabricating and repairing the same
A slurry for use to form or repair a silicon carbide coating is provided. In one aspect, the slurry includes solid particles and a carbonaceous resin. The solid particles include silicon carbide particles, silicon particles, and carbon particles. A method of fabricating a silicon carbide coating is also provided. In one aspect, the method includes applying the slurry, heating the slurry, and forming the silicon carbide coating from the solid particles and the carbonaceous resin. A method of repairing a silicon carbide coating is also provided. In one aspect, the method includes applying the slurry to a damaged region of the silicon carbide coating, heating the slurry, and repairing the silicon carbide coating with the solid particles and the carbonaceous resin in the damaged region.
1 . A slurry for use to form or repair a silicon carbide coating, the slurry comprising:
solid particles comprising:
silicon carbide particles,
25 to 60 volume percent silicon particles, and
carbon particles; and
a carbonaceous resin.
2 . The slurry of claim 1 , wherein the solid particles form 25 to 80 volume percent of the slurry.
3 . The slurry of claim 1 , wherein the solid particles comprise 40 to 70 volume percent silicon carbide particles and 25 to 55 volume percent silicon particles.
4 . The slurry of claim 1 , wherein the solid particles comprise less than or equal to 10 volume percent carbon particles.
5 . The slurry of claim 1 , wherein the carbon particles comprise diamond, graphite, and/or carbon black.
6 . The slurry of claim 1 , wherein the carbonaceous resin comprises phenolic ester or cyanate ester.
7 . The slurry of claim 1 , wherein the silicon carbide particles have an average particle size in the range of 0.5 to 20 microns.
8 . The slurry of claim 1 , wherein the silicon carbide particles have a particle size with a bimodal distribution.
9 . The slurry of claim 1 , wherein the silicon particles have an average particle size in the range of 5 to 20 microns.
10 . The slurry of claim 1 , wherein the carbon particles have an average particle size in the range of 0.5 to 5 microns.
11 . A method of fabricating a silicon carbide coating on a carbon material, the method comprising:
applying the slurry of claim 1 on the carbon material;
heating the slurry; and
forming the silicon carbide coating from the solid particles and the carbonaceous resin.
12 . The method of claim 11 , wherein heating the slurry comprises melting the silicon particles and pyrolyzing the carbonaceous resin, and wherein forming the silicon carbide coating comprises the melted silicon particles reacting with the carbon particles and pyrolyzed char from the carbonaceous resin.
13 . The method of claim 12 , wherein forming the silicon carbide coating comprises the melted silicon particles reacting with less than or equal to 5 percent of carbon of the carbon material.
14 . The method of claim 11 , wherein forming the silicon carbide coating comprises the carbon particles expanding and filling pores of the silicon carbide coating.
15 . The method of claim 11 , wherein the silicon carbide coating has no more than 5% of porosity.
16 . The method of claim 11 , further comprising applying a silicon coating on the carbon material.
17 . The method of claim 16 , wherein the silicon coating is applied prior to applying the slurry on the carbon material.
18 . The method of claim 16 , wherein the silicon coating is applied after applying the slurry on the carbon material.
19 . The method of claim 11 , wherein the carbon material is a carbon carbon (C/C) composite material, a carbon silicon carbide (C/SiC) composite material, or a carbon carbon-silicon carbide (C/C-SiC) composite material.
20 . A method of repairing a silicon carbide coating, the method comprising:
applying the slurry of claim 1 to a damaged region of the silicon carbide coating;
heating the slurry; and
repairing the silicon carbide coating with the solid particles and the carbonaceous resin in the damaged region.
21 . The method of claim 20 , wherein heating the slurry comprises melting the silicon particles and pyrolyzing the carbonaceous resin, and wherein repairing the silicon carbide coating comprises the melted silicon particles reacting with the carbon particles and pyrolyzed char from the carbonaceous resin.
22 . The method of claim 20 , wherein the silicon carbide coating is on a carbon material, and wherein repairing the silicon carbide coating comprises the melted silicon particles reacting with less than or equal to 5 percent of carbon of the carbon material.
23 . The method of claim 20 , wherein repairing the silicon carbide coating comprises the carbon particles expanding and filling pores of the repaired silicon carbide coating in the damaged region.
24 . The method of claim 20 , wherein the repaired silicon carbide coating in the damaged region has no more than 5% of porosity.
25 . The method of claim 20 , further comprising applying a silicon coating over the applied slurry.