PLURALITY OF ORGANIC ELECTROLUMINESCENT MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME

1 . A plurality of organic electroluminescent materials comprising at least one first compound and at least one second compound, wherein the first compound is represented by the following formula 1:

wherein,

R 1 to R 10 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, or

with a proviso that at least one of R 1 to R 10 is

L 1 represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;

Ar 1 and Ar 2 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl, or Ar 1 and Ar 2 may be linked to each other to form a fused ring; and

* represents the position linked to phenanthrene; and

the second compound is represented by the following formula 2:

wherein,

ring A, ring B, and ring C, each independently, represent a substituted or unsubstituted mono- or polycyclic (3- to 50-membered) alicyclic or aromatic ring, or the combination thereof, which may contain at least one heteroatom selected from B, N, O, S, Si, and P; and ring B and ring C may be linked to each other to form a fused ring;

Y 1 represents B;

X 1 and X 2 , each independently, represent NR or O; and

R, each independently, represents hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted mono- or di-(C1-C30)alkylamino, a substituted or unsubstituted mono- or di-(C2-C30)alkenylamino, a substituted or unsubstituted mono- or di-(C6-C30)arylamino, a substituted or unsubstituted mono- or di-(3- to 30-membered)heteroarylamino, a substituted or unsubstituted (C1-C30)alkyl(C2-C30)alkenylamino, a substituted or unsubstituted (C1-C30)alkyl(C6-C30)arylamino, a substituted or unsubstituted (C1-C30)alkyl(3- to 30-membered)heteroarylamino, a substituted or unsubstituted (C2-C30)alkenyl(C6-C30)arylamino, a substituted or unsubstituted (C2-C30)alkenyl(3- to 30-membered)heteroarylamino, or a substituted or unsubstituted (3- to 30-membered)heteroaryl(C6-C30)arylamino; or may be linked to at least one of ring A, ring B, and ring C to form a fused ring.

2 . The plurality of organic electroluminescent materials according to claim 1 , wherein the substituents of the substituted alkyl, the substituted aryl(ene), the substituted heteroaryl(ene), the substituted cycloalkyl, the substituted heterocycloalkyl, the substituted alkoxy, the substituted trialkylsilyl, the substituted dialkylarylsilyl, the substituted alkyldiarylsilyl, the substituted triarylsilyl, the substituted mono- or di-alkylamino, the substituted mono- or di-alkenylamino, the substituted mono- or di-arylamino, the substituted mono- or di-heteroarylamino, the substituted alkylalkenylamino, the substituted alkylarylamino, the substituted alkylheteroarylamino, the substituted alkenylarylamino, the substituted alkenylheteroarylamino, the substituted heteroarylarylamino, and the substituted ring, each independently, are at least one selected from the group consisting of deuterium; a halogen; a cyano; a carboxyl; a nitro; a hydroxyl; a (C1-C30)alkyl unsubstituted or substituted with at least one deuterium; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl; a (C1-C30)alkoxy; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C3-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; a (3- to 30-membered)heteroaryl unsubstituted or substituted with at least one of deuterium(s), a (C1-C30)alkyl(s), a (C6-C30)aryl(s), and a di(C6-C30)arylamino(s); a (C6-C30)aryl unsubstituted or substituted with at least one of deuterium(s), a (C1-C30)alkyl(s), a (3- to 30-membered)heteroaryl(s), and a di(C6-C30)arylamino(s); a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl; a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; an amino; a mono- or di-(C1-C30)alkylamino; a mono- or di-(C2-C30)alkenylamino; a mono- or di-(C6-C30)arylamino unsubstituted or substituted with at least one of deuterium(s), a (C1-C30)alkyl(s), a (3- to 30-membered)heteroaryl(s), and a di(C6-C30)arylamino(s); a mono- or di-(3- to 30-membered)heteroarylamino; a (C1-C30)alkyl(C2-C30)alkenylamino; a (C1-C30)alkyl(C6-C30)arylamino; a (C1-C30)alkyl(3- to 30-membered)heteroarylamino; a (C2-C30)alkenyl(C6-C30)arylamino;

a (C2-C30)alkenyl(3- to 30-membered)heteroarylamino; a (3- to 30-membered)heteroaryl(C6-C30)arylamino unsubstituted or substituted with at least one of a (C1-C30)alkyl(s) and a (C6-C30)aryl(s); a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl; a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl.

3 . The plurality of organic electroluminescent materials according to claim 1 , wherein formula 1 is represented by the following formula 1-1:

wherein, L 1 , Ar 1 , Ar 2 , R 1 to R 4 , and R 6 to R 10 are as defined in claim 1 .

4 . The plurality of organic electroluminescent materials according to claim 1 , wherein R 1 to R 10 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C10)alkyl, a substituted or unsubstituted (C6-C25)aryl, a substituted or unsubstituted (5- to 25-membered)heteroaryl, or

with a proviso that at least one of R 1 to R 10 is

and * represents the position linked to phenanthrene.

5 . The plurality of organic electroluminescent materials according to claim 1 , wherein R 1 to R 10 , each independently, represent hydrogen, deuterium, or

with a proviso that at least one of R 1 to R 10 is

and * represents the position linked to phenanthrene.

6 . The plurality of organic electroluminescent materials according to claim 1 , wherein formula 2 is represented by the following formula 2-1:

wherein,

Y 1 , X 1 , and X 2 , each independently, are as defined in claims 1 ; and

R 21 to R 31 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted mono- or di-(C1-C30)alkylamino, a substituted or unsubstituted mono- or di-(C2-C30)alkenylamino, a substituted or unsubstituted mono- or di-(C6-C30)arylamino, a substituted or unsubstituted mono- or di-(3- to 30-membered)heteroarylamino, a substituted or unsubstituted (C1-C30)alkyl(C2-C30)alkenylamino, a substituted or unsubstituted (C1-C30)alkyl(C6-C30)arylamino, a substituted or unsubstituted (C1-C30)alkyl(3- to 30-membered)heteroarylamino, a substituted or unsubstituted (C2-C30)alkenyl(C6-C30)arylamino, a substituted or unsubstituted (C2-C30)alkenyl(3- to 30-membered)heteroarylamino, or a substituted or unsubstituted (3- to 30-membered)heteroaryl(C6-C30)arylamino; or adjacent ones of R 21 to R 31 may be linked to each other to form a ring(s).

7 . The plurality of organic electroluminescent materials according to claim 1 , wherein the compound represented by formula 1 is at least one selected from the following compounds:

wherein, D n represents that n hydrogens are replaced with deuterium; and n represents an integer of 1 or more.

8 . The plurality of organic electroluminescent materials according to claim 1 , wherein the compound represented by formula 2 is at least one selected from the following compounds:

wherein, D2 to D5 respectively represent that 2 to 5 hydrogens are replaced with deuterium.

9 . The plurality of organic electroluminescent materials according to claim 1 , wherein the compound represented by formula 1 is comprised as a hole transport zone material, and the compound represented by formula 2 is comprised as a dopant material.

10 . An organic electroluminescent device comprising a first electrode, a second electrode facing the first electrode, and an organic layer between the first and second electrodes, wherein the organic layer comprises the plurality of organic electroluminescent materials according to claim 1 .

11 . The organic electroluminescent device according to claim 10 , wherein the organic layer comprises at least one layer of hole transport zone and at least one light-emitting layer, and at least one layer of the hole transport zone comprises the compound represented by formula 1, and at least one layer of the light-emitting layer comprises the compound represented by formula 2.