PALLADIUM FIXING USING GALLIC ACID OR ITS DERIVATIVE
A method of manufacturing a catalyst article, the method comprising: providing a complex of a compound of formula (I): and a PGM, R1 is H or C 1 -C 6 alkyl, R2 is H, OH, or O—C 1 -C 4 alkyl, the PGM comprising palladium; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.
1 . A method of manufacturing a catalyst article, the method comprising:
providing a complex of a compound of formula (I):
and a PGM, R1 is H or C 1 -C 6 alkyl, R2 is H, OH, or O—C 1 -C 4 alkyl, the PGM comprising palladium;
providing a support material;
applying the complex to the support material to form a loaded support material;
disposing the loaded support material on a substrate; and
heating the loaded support material to form nanoparticles of the PGM on the support material.
2 . The method of claim 1 , wherein R2 is OH.
3 . The method of claim 1 , wherein R1 is H.
4 . The method of claim 1 , wherein the PGM consists of palladium.
5 . The method of claim 1 , wherein the support material comprises alumina and/or ceria-zirconia.
6 . The method of claim 5 , wherein the alumina and/or ceria-zirconia is doped.
7 . The method of claim 1 , wherein the loaded support material is disposed on the substrate in the form of a slurry.
8 . The method of claim 7 , wherein the slurry is prepared by a method comprising:
contacting a PGM salt and a compound of formula (I) in water to form the complex of a compound of formula (I) and a PGM in an aqueous solution, the PGM salt comprising palladium;
applying the complex to the support material to form a loaded support material by contacting the support material with the aqueous solution;
optionally adding one or more of an oxygen storage material, preferably ceria-zirconia; a promoter salt; a binder; an acid or a base; a thickening agent; and a reducing agent to the aqueous solution.
9 . The method of claim 7 , wherein the slurry is prepared by a method comprising:
contacting a support material and an aqueous solution of a PGM salt to form a slurry comprising a PGM-salt-loaded support material, the PGM salt comprising palladium;
applying the complex of a compound of formula (I):
and a PGM to the support material to form a loaded support material by contacting the slurry comprising the PGM-salt-loaded support material and the compound of formula (I) in water;
optionally adding one or more of an oxygen storage material, preferably ceria-zirconia;
a promoter salt; a binder; an acid or a base; a thickening agent; and a reducing agent to the aqueous solution or the slurry comprising the PGM-salt-loaded support material.
10 . The method of claim 7 , further comprising disposing a further slurry on the substrate, the further slurry comprising one or more of a further support material; an oxygen storage material; a promoter salt, preferably barium acetate, barium sulfate, barium citrate or a combination thereof; a binder; an acid or a base; a thickening agent; and a reducing agent, wherein disposing the further slurry on the substrate takes place before disposing the support material on the substrate and/or after heating the loaded support material to form nanoparticles of the PGM on the support material.
11 . A catalyst article obtainable by the method of claim 1 , the catalyst article for use in an emission treatment system.
12 . The catalyst article of claim 11 for three-way catalysis.
13 . The catalyst article of claim 11 , wherein the substrate comprises a wall flow filter substrate.
14 . The catalyst article of claim 11 , wherein the substrate comprises a flow-through substrate.
15 . The catalyst article of claim 11 comprising a bottom layer of support material having rhodium thereon and a top layer of support material having palladium thereon.
16 . The catalyst article of claim 11 comprising a bottom layer of support material having palladium thereon and a top layer of support material having rhodium thereon.
17 . The catalyst article of claim 15 , wherein the top and/or bottom layer of support material also has platinum thereon.
18 . The catalyst article of claim 15 , wherein the top and/or bottom layer of support material has multiple PGMs thereon.
19 . The catalyst article of claim 15 comprising two or more catalyst zones, wherein the two or more catalyst zones differ from each other by containing different PGMs or different amounts of PGMs.
20 . An emission treatment system comprising the catalyst article of claim 11 .
21 . The emission treatment system of claim 20 for a gasoline engine.