POLARIZING PLATE AND OPTICAL DISPLAY APPARATUS
A polarizing plate and an optical display apparatus including the same are provided. A polarizing plate includes: a polarizer; and a stack of retardation layers on at least one surface of the polarizer, and the stack of retardation layers includes a second retardation layer, a primer layer, and a first retardation layer stacked in sequence on the polarizer, and the primer layer has a glass transition temperature of 60° C. to 150° C. and is a (meth)acrylate-based primer layer.
1 . A polarizing plate comprising:
a polarizer; and
a stack of retardation layers formed on at least one surface of the polarizer,
wherein the stack of retardation layers comprises a second retardation layer, a primer layer, and a first retardation layer stacked in sequence on the polarizer, and
the primer layer has a glass transition temperature of 60° C. to 150° C. and is a (meth)acrylate-based primer layer.
2 . The polarizing plate as claimed in claim 1 , wherein the primer layer has a glass transition temperature of 60° C. to 90° C.
3 . The polarizing plate as claimed in claim 1 , wherein a peel strength between the first retardation layer and the second retardation layer is 300 gf/25 mm or greater.
4 . The polarizing plate as claimed in claim 1 , wherein the primer layer is formed directly on each of the first retardation layer and the second retardation layer.
5 . The polarizing plate as claimed in claim 1 , wherein the primer layer is a (meth)acrylate-based primer layer not modified with a styrene based compound or a (meth)acrylate-based primer layer modified with a styrene based compound.
6 . The polarizing plate as claimed in claim 1 , wherein the primer layer is formed of a primer layer composition comprising a copolymer of a monomer mixture comprising a (meth)acrylic based monomer having a homopolymer glass transition temperature of 10° C. or greater.
7 . The polarizing plate as claimed in claim 6 , wherein the (meth)acrylic based monomer having a homopolymer glass transition temperature of 10° C. or greater comprises at least one selected from among a (meth)acrylic acid ester containing a C 1 to C 10 alkyl group, a (meth)acrylic acid ester containing a C 1 to C 10 alkyl group having a hydroxyl group, and a (meth)acrylic acid ester containing a C 5 to C 10 alicyclic group.
8 . The polarizing plate as claimed in claim 6 , wherein the monomer mixture further comprises a peel strength-enhancing compound.
9 . The polarizing plate as claimed in claim 8 , wherein the peel strength-enhancing compound comprises at least one selected from among a (meth)acrylate based compound, an ester based compound, and a styrene based compound.
10 . The polarizing plate as claimed in claim 9 , wherein the ester based compound comprises at least one selected from among a formic acid ester compound, an acetic acid ester compound, and a (meth)acrylic acid ester compound.
11 . The polarizing plate as claimed in claim 10 , wherein the ester based compound comprises at least one selected from among butyl acetic ester, butyl formic ester, cyclohexyl 2-methyl-propenoic ester, 2-methylcyclohexyl 2-propenoic ester, and isopropyl acetate.
12 . The polarizing plate as claimed in claim 9 , wherein the styrene based compound is present in an amount of greater than 0 parts by weight to 10 parts by weight relative to 100 parts by weight of the monomer mixture.
13 . The polarizing plate as claimed in claim 8 , wherein the monomer mixture comprises 20 parts by weight to 80 parts by weight of the (meth)acrylic based monomer having a homopolymer glass transition temperature of 10° C. or greater and 20 parts by weight to 80 parts by weight of the peel strength-enhancing compound.
14 . The polarizing plate as claimed in claim 1 , wherein the second retardation layer has a higher glass transition temperature than the first retardation layer.
15 . The polarizing plate as claimed in claim 14 , wherein the second retardation layer has a glass transition temperature of 130° C. or greater, and the first retardation layer has a glass transition temperature of 100° C. or greater.
16 . The polarizing plate as claimed in claim 1 , wherein the second retardation layer comprises a polystyrene based polymer, and the first retardation layer is a COP based film, a COC based film, or an acrylic based film.
17 . The polarizing plate as claimed in claim 16 , wherein the polystyrene based polymer contains a halogen.
18 . The polarizing plate as claimed in claim 1 , wherein the second retardation layer is a positive C layer, and the first retardation layer is a positive A layer.
19 . The polarizing plate as claimed in claim 1 , wherein the stack of retardation layers is formed on a light incidence surface of the polarizer.
20 . An optical display apparatus comprising the polarizing plate as claimed in claim 1 .