SCALABLE METHOD FOR ACHIEVING SHAPE CONTROL OF DIAMOND MICRO-NANOPARTICLES
The present invention provides a scalable method for achieving shape control of diamond micro-nanoparticles, comprising air oxidizing diamond micro-nanoparticles grown by chemical vapor deposition and/or diamond micro-nanoparticles grown by high pressure and high temperature. The present invention achieves the controllable morphology transformation of diamond micro-nanoparticles via air oxidation treatment. It has been demonstrated that a series of unique shapes, including “flower” shaped, “hollow” structured, “pyramid” patterned on the surface, and “boomerang” shaped, can be achieved by altering the air oxidation parameters, i.e., temperature and duration. The scalable production of these differently shaped diamond micro-nanoparticles represents a significant scientific breakthrough together with a high commercial value. The ability to produce diamond particles with desired shapes simply and cost-effectively will remove many obstacles to using diamonds for practical applications in nanophotonics, quantum computing, quantum optics, etc.
1 . A scalable method for achieving shape control of diamond micro-nanoparticles, comprising air oxidizing diamond micro-nanoparticles grown by chemical vapor deposition and/or diamond micro-nanoparticles grown by high pressure and high temperature, wherein,
diamond micro-nanoparticles with a mean particle size of 10 nm to 500 nm are subjected to air oxidation under one of the following conditions:
5-25 hours of oxidation in the air at 530-570° C.;
10 min-10 hours of oxidation in the air at 580-620° C.; and
diamond micro-nanoparticles with a mean particle size of greater than 500 nm to 10 μm are subjected to air oxidation under one of the following conditions:
10-35 hours of oxidation in the air at 580-620° C.;
5-25 hours of oxidation in the air at 630-670° C.
2 . The scalable method for achieving shape control of diamond micro-nanoparticles according to claim 1 , wherein the preparation method for the diamond micro-nanoparticles grown by chemical vapor deposition comprises the following steps:
( 1 ) mixing the diamond micro-nanoparticles grown by high pressure and high temperature with sodium chloride, and heating at 400-600° C. for 0.5-2 hours in the air; and dispersing the resultant product in deionized water and sonicating it, purifying it with deionized water one to five times by centrifugation, then re-dispersing it in deionized water and sonicating it for 0.5-3 hours to obtain a suspension of the diamond micro-nanoparticles; and
(2) spin-coating the suspension obtained in step (1) on a hydrogen plasma treated standard single-crystal Si substrate, and then putting the suspension spin-coated Si substrate in a microwave-plasma assisted chemical vapor deposition system, with a gas mixture of H 2 and methane for the growth of the diamond micro-nanoparticles.
3 . The scalable method for achieving shape control of diamond micro-nanoparticles according to claim 2 , wherein the diamond micro-nanoparticles grown by high pressure and high temperature in step (1) have a mean particle size of 50 nm to 200 nm.
4 . The scalable method for achieving shape control of diamond micro-nanoparticles according to claim 2 , wherein the diamond micro-nanoparticles grown in step (2) have a mean particle size of 1 to 2 μm.
5 . A scalable method for preparing diamond microparticles with a flower like shape, comprising air oxidizing diamond micro-nanoparticles having a mean particle size of 1 to 2 μm grown by chemical vapor deposition in the air at 580-620° C. for 25-35 hours.
6 . A scalable method for preparing diamond microparticles with pyramidpatterns on the surface, comprising air oxidizing diamond micro-nanoparticles having a mean particle size of 1 to 2 μm grown by chemical vapor deposition in the air at 580-620° C. for 10-20 hours.
7 . A scalable method for preparing diamond microparticles with hollow structures, comprising air oxidizing diamond micro-nanoparticles having a mean particle size of 1 to 2 μm grown by chemical vapor deposition in the air at 630-670° C. for 15-25 hours.
8 . A scalable method for preparing diamond nanoparticles with “pyramid” patterns on the surface, comprising air oxidizing diamond micro-nanoparticles having a mean particle size of 100 to 500 nm grown by high pressure and high temperature under one of the following conditions:
5-25 hours of oxidation in the air at 530-570° C.;
30 min-5 hours of oxidation in the air at 580-620° C.
9 . A scalable method for preparing diamond microparticles with a boomerang like shape, comprising air oxidizing diamond micro-nanoparticles having a mean particle size of 500 nm to 2 μm grown by high pressure and high temperature in the air at 580-620° C. for 10-30 hours.