ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
The present disclosure relates to an organic electroluminescent compound represented by formula 1 and an organic electroluminescent device comprising the same. By comprising an organic electroluminescent compound according to the present disclosure, it is possible to produce an organic electroluminescent device having improved current efficiency and/or lifetime properties.
1 . An organic electroluminescent compound represented by the following formula 1:
in formula 1,
R 1 and R 2 , each independently, represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to each other to form a ring(s);
R 11 to R 13 , each independently, represent hydrogen, deuterium, or a substituted or unsubstituted (C6-C30)aryl, or are represented by the following formula 1-1, with the proviso that at least one of R 12 and R 13 is represented by the following formula 1-1;
in formula 1-1,
Ar 1 represents a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl;
R 21 and R 25 , each independently, represent hydrogen, deuterium, an unsubstituted (C1-C30)alkyl, or a combination thereof;
R 22 to R 24 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl, with the proviso that at least one of R 22 to R 24 represents a substituted or unsubstituted (C12-C30)aryl comprising the following linking group a in ortho form;
ring A represents a substituted or unsubstituted (C6-C24)arene ring;
a and c, each independently, represent an integer of 1 to 4, and b represents an integer of 1 to 2, in which if a to c represent an integer of 2 or more, each of R 11 to each of R 13 may be the same or different; and
the heteroaryl and heteroarene each comprise at least one heteroatoms selected from B, N, O, S, Si and P.
2 . The organic electroluminescent compound according to claim 1 , wherein the substituted aryl, the substituted arene, the substituted heteroaryl, the substituted heteroarene, and the substituted alkyl, each independently, are substituted with at least one selected from the group consisting of deuterium, a halogen, a cyano, a carboxyl, a nitro, a hydroxy, a phosphine oxide, a (C1-C30)alkyl unsubstituted or substituted with deuterium, a halo(C1-C30)alkyl, a (C2-C30)alkenyl, a (C2-C30)alkynyl, a (C1-C30)alkoxy, a (C1-C30)alkylthio, a (C3-C30)cycloalkyl, a (C3-C30)cycloalkenyl, a (3- to 7-membered)heterocycloalkyl, a (C6-C30)aryloxy, a (C6-C30)arylthio, a (3- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl(s), a (C6-C30)aryl unsubstituted or substituted with a (3- to 30-membered)heteroaryl(s), a tri(C1-C30)alkylsilyl, a tri(C6-C30)arylsilyl, a di(C1-C30)alkyl(C6-C30)arylsilyl, a (C1-C30)alkyldi(C6-C30)arylsilyl, a fused ring group of a (C3-C30)aliphatic ring(s) and a (C6-C30)aromatic ring(s), an amino, a mono- or di-(C1-C30)alkylamino, a mono- or di-(C2-C30)alkenylamino, a mono- or di-(C6-C30)arylamino, a mono- or di-(3- to 30-membered)heteroarylamino, a (C1-C30)alkyl(C2-C30)alkenylamino, a (C1-C30)alkyl(C6-C30)arylamino, a (C1-C30)alkyl(3- to 30-membered)heteroarylamino, a (C2-C30)alkenyl(C6-C30)arylamino, a (C2-C30)alkenyl(3- to 30-membered)heteroarylamino, a (C6-C30)aryl(3- to 30-membered)heteroarylamino, a (C1-C30)alkylcarbonyl, a (C1-C30)alkoxycarbonyl, a (C6-C30)arylcarbonyl, a di(C6-C30)arylboronyl, a di(C1-C30)alkylboronyl, a (C1-C30)alkyl(C6-C30)arylboronyl, a (C6-C30)aryl(C1-C30)alkyl, and a (C1-C30)alkyl(C6-C30)aryl.
3 . The organic electroluminescent compound according to claim 1 , wherein formula 1 is represented by any one of the following formulas 2 to 4:
in formulas 2 to 4,
c′ represents an integer of 1 to 3, in which if c′ represents an integer of 2 or more, each of R 13 may be the same or different; and
R 1 , R 2 , R 11 to R 13 , R 21 to R 25 , Ar 1 , a, and b are as defined in claim 1 .
4 . The organic electroluminescent compound according to claim 1 , wherein the linking group a is represented by any one of the following structures:
in the structures, hydrogen may be replaced by at least one deuterium.
5 . The organic electroluminescent compound according to claim 1 , wherein the substituted or unsubstituted (C12-C30)aryl comprising the linking group a in ortho form is represented by any one of the following structures:
in the structures, hydrogen may be replaced by at least one of deuterium and a methyl(s) unsubstituted or substituted with at least one deuterium.
6 . The organic electroluminescent compound according to claim 1 , wherein R 1 and R 2 each independently, represent a methyl unsubstituted or substituted with deuterium, or a phenyl unsubstituted or substituted with deuterium.
7 . The organic electroluminescent compound according to claim 1 , wherein R 11 to R 13 each independently, represent hydrogen, a methyl unsubstituted or substituted with deuterium, a phenyl unsubstituted or substituted with deuterium, or formula 1-1.
8 . The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is selected from the following compounds:
in the structures, Ph represents a phenyl group.
9 . An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .
10 . An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
11 . The organic electroluminescent device according to claim 10 , wherein the organic electroluminescent compound is comprised in at least one layer of a light-emitting layer, a first hole transport layer, a second hole transport layer, a hole auxiliary layer, an electron blocking layer, and a light-emitting auxiliary layer.