Secondary battery and electrical device
The present application relates to a secondary battery, which includes: a cathode sheet, an anode sheet, and an electrolyte; the cathode sheet includes a cathode film layer containing a cathode active material, and the anode sheet includes an anode film layer containing an anode active material; and the secondary battery meets a following function relationship: 0.22≤3×(A1/A2)×(B2−B1)/(B1+B2)≤1.55, the parameters are referred to the description; and an electrical device including the secondary battery. The secondary battery in the present application has both good cycle life and excellent fast charging capacity.
1. A secondary battery, comprising:
a cathode sheet, comprising a cathode film layer containing a cathode active material;
an anode sheet, comprising an anode film layer containing an anode active material; and
an electrolyte;
wherein the secondary battery meets a following function relationship:
0.22≤3×( A 1/ A 2)×( B 2− B 1)/( B 1+ B 2)≤1.55;
wherein A1 is a particle size D n10 of the cathode active material corresponding to that a cumulative percentage of a particle number sequentially counted from a small particle in the cathode active material reaches 10% of a total particle number, in m;
A2 is a particle size D n10 of the anode active material corresponding to that a cumulative percentage of a particle number sequentially counted from a small particle in the anode active material reaches 10% of the total particle number, in m;
B1 is a porosity of the cathode film layer; and
B2 is a porosity of the anode film layer.
2. The secondary battery according to claim 1 , wherein 0.25 μm≤A1≤1.2 μm, and 0.4 μm≤A2≤3.0 μm.
3. The secondary battery according to claim 1 , wherein 10%≤B2−B1≤40%.
4. The secondary battery according to claim 1 , wherein an average volume particle size D v50 of the cathode active material is ranged from 4.2 μm to 9.7 μm.
5. The secondary battery according to claim 1 , wherein an average volume particle size D v50 of the anode active material is ranged from 3.4 μm to 9.6 μm.
6. The secondary battery according to claim 1 , wherein the cathode active material meets at least one of following characteristics:
D v10 is ranged from 2.2 μm to 4.9 μm; and
D v90 is ranged from 8.2 μm to 21.9 μm.
7. The secondary battery according to claim 1 , wherein the anode active material meets at least one of following characteristics:
D v10 is ranged from 1.9 μm to 3.4 μm; and
D v90 is ranged from 7.9 μm to 17.5 μm.
8. The secondary battery according to claim 1 , wherein a compaction density of the cathode film layer is arranged from 2.3 g/cm 3 to 3.2 g/cm 3 , and a thickness of the cathode film is arranged from 60 μm to 110 μm.
9. The secondary battery according to claim 1 , wherein a compaction density of the anode film layer is arranged from 0.9 g/cm 3 to 1.2 g/cm 3 , and a thickness of the anode film layer is arranged from 50 μm to 140 μm.
10. The secondary battery according to claim 1 , wherein the cathode film layer comprises the cathode active material of 90-97%, a conductive agent of 0.8-2.0%, and a binder of 1.5-2.7%, based on a weight of the cathode film layer.
11. The secondary battery according to claim 1 , wherein the anode film layer comprises the anode active material of 91.6-97.5%, a conductive agent of 0-1.74%, and a binder of 0-6.56%, based on a weight of the anode film layer.
12. The secondary battery according to claim 1 , wherein the secondary battery is a sodium-ion secondary battery.
13. An electrical device, comprising a secondary battery comprising:
a cathode sheet, comprising a cathode film layer containing a cathode active material;
an anode sheet, comprising an anode film layer containing an anode active material; and
an electrolyte;
wherein the secondary battery meets a following function relationship:
0.22≤3×( A 1/ A 2)×( B 2− B 1)/( B 1+ B 2)≤1.55;
wherein A1 is a particle size D n10 of the cathode active material corresponding to that a cumulative percentage of a particle number sequentially counted from a small particle in the cathode active material reaches 10% of a total particle number, in m;
A2 is a particle size D n10 of the anode active material corresponding to that a cumulative percentage of a particle number sequentially counted from a small particle in the anode active material reaches 10% of the total particle number, in m;
B1 is a porosity of the cathode film layer; and
B2 is a porosity of the anode film layer.