CATALYST ARTICLE HAVING HIGH LOCAL RHODIUM CONCENTRATION
The present invention provides a catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising support material particles; at least some of the support material particles are rhodium-supporting support material particles having rhodium supported thereon at a concentration of from 0.001 to 3.5 wt. %, based on the weight of the rhodium-supporting support material particle; and the rhodium is present at a loading of up to 20 g/ft 3 relative to the first catalytic region.
1 . A catalyst article for treating exhaust gas comprising:
a substrate comprising an inlet end and an outlet end with an axial length L;
a first catalytic region comprising support material particles;
at least some of the support material particles are rhodium-supporting support material particles having rhodium supported thereon at a concentration of from 0.001 to 3.5 wt. %, based on the weight of the rhodium-supporting support material particle;
the rhodium is present at a loading of up to 20 g/ft 3 relative to the first catalytic region;
the support material particles comprise a ceria-zirconia mixed oxide; and wherein the ceria-zirconia mixed oxide has a ceria content of at least 20 wt. %.
2 . The catalyst article of claim 1 , wherein the rhodium-supporting support material particles have rhodium supported thereon at a concentration of from 0.3 to 3.5 wt. %, based on the weight of the rhodium-supporting support material particle.
3 . The catalyst article of claim 1 , wherein at least some of the support material particles are non-supporting support material particles having essentially no rhodium supported thereon, preferably having no rhodium supported thereon.
4 . The catalyst article of claim 1 , wherein the ceria zirconia mixed oxide has a ceria content of 20-45 wt. %.
5 . The catalyst article of claim 1 , wherein the rhodium is present at a loading of from 1 to 20 g/ft 3 relative to the first catalytic region.
6 . The catalyst article of claim 1 , wherein the support material particles are present at a loading of from 0.5 to 3 g/in 3 .
7 . The catalytic article of claim 1 , further comprising a second catalytic region.
8 . The catalytic article of claim 7 , wherein the second catalytic region comprises a second PGM component.
9 . The catalytic article of claim 8 , wherein the second PGM component is selected from the group consisting of platinum, palladium, rhodium, and a mixture thereof.
10 . The catalytic article of claim 8 , wherein the second catalytic region further comprises a second OSC material and/or a second inorganic oxide.
11 . The catalytic article of claim 1 , wherein the first catalytic region is supported/deposited directly on the substrate.
12 . The catalytic article of claim 7 , wherein the second catalytic region is supported/deposited directly on the substrate.
13 . The catalytic article of claim 1 , wherein the first catalytic region extends for less than the axial length L.
14 . The catalytic article of claim 7 , wherein the second catalytic region extends for less than the axial length L.
15 . The catalytic article of claim 7 , further comprising a third catalytic region.
16 . The catalytic article of claim 15 , wherein the third catalytic region comprises a third PGM component.
17 . The catalytic article of claim 16 , wherein the third PGM component is selected from the group consisting of platinum, palladium, rhodium, and a mixture thereof.
18 . The catalytic article of claim 16 , wherein the third catalytic region further comprises a third OSC material and/or a third inorganic oxide.
19 . The catalyst article of claim 1 , wherein the first catalyst region further comprises platinum and/or palladium.
20 . The catalyst article of claim 1 , wherein the substrate comprises a wall flow filter substrate or a flow-through substrate.