BINDER AND PREPARATION METHOD THEREOF, AND SEPARATOR, ELECTRODE ASSEMBLY, BATTERY CELL, BATTERY, AND ELECTRIC APPARATUS
This application relates to the field of battery technologies, and in particular, to a binder and a preparation method thereof, and a separator, electrode assembly, battery cell, battery, and electric apparatus containing such binder. The binder includes a core layer structure and a shell layer structure provided on a surface of the core layer structure, where the core layer structure includes a polyacrylate polymer, and the shell layer structure includes a polyvinylidene fluoride polymer.
1 . A binder, wherein the binder comprises a core layer structure and a shell layer structure provided on a surface of the core layer structure, the core layer structure comprising a polyacrylate polymer, and the shell layer structure comprising a polyvinylidene fluoride polymer.
2 . The binder according to claim 1 , wherein the shell layer structure comprises a plurality of shells, the plurality of shells being spaced apart on the surface of the core layer structure.
3 . The binder according to claim 1 , wherein a mass ratio of the polyacrylate polymer to the polyvinylidene fluoride polymer is (2-100):1.
4 . The binder according to claim 1 , wherein a median particle size by volume D v 50 of the binder is 0.5 μm-50 μm.
5 . The binder according to claim 1 , wherein constituent monomers of the polyacrylate polymer comprise a first polymeric flexible monomer, a second polymeric polar monomer, and a third polymeric molecular weight regulating monomer.
6 . The binder according to claim 5 , wherein a molar ratio of the first polymeric flexible monomer, the second polymeric polar monomer, and the third polymeric molecular weight regulating monomer is 1:(0.01-0.8):(0.01-0.15).
7 . The binder according to claim 5 , wherein the first polymeric flexible monomer contains an ester bond in structure, the second polymeric polar monomer contains a cyano group in structure, and the third polymeric molecular weight regulating monomer contains an amide bond.
8 . The binder according to claim 5 , wherein the first polymeric flexible monomer is an acrylate monomer, the second polymeric polar monomer is an acrylonitrile monomer, and the third polymeric molecular weight regulating monomer is an acrylamide monomer.
9 . The binder according to claim 8 , wherein the acrylate monomer comprises at least one of methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, tert-butyl acrylate, n-propyl acrylate, cyclohexyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, 2-ethylhexyl methacrylate, isobornyl methacrylate, lauryl methacrylate, 2-hydroxyethyl methacrylate, and 2-hydroxypropyl methacrylate;
and/or the acrylonitrile monomer comprises at least one of acrylonitrile and methacrylonitrile;
and/or the acrylamide monomer comprises at least one of acrylamide, N-methylolacrylamide, and N-butoxymethylacrylamide.
10 . The binder according to claim 1 , wherein the polyvinylidene fluoride polymer comprises at least one of vinylidene fluoride polymer, vinylidene fluoride-hexafluoropropylene copolymer, vinylidene fluoride-pentafluoropropylene copolymer, vinylidene fluoride-tetrafluoropropylene copolymer, vinylidene fluoride-trifluoropropylene copolymer, vinylidene fluoride-perfluorobutene copolymer, vinylidene fluoride-tetrafluoroethylene copolymer, vinylidene fluoride-trifluoroethylene copolymer, vinylidene fluoride-trifluorochloroethylene copolymer, or vinylidene fluoride-fluoroethylene copolymer.
11 . A preparation method of binder, comprising:
mixing and stirring water, an emulsifier, an initiator, and constituent monomers of a polyacrylate polymer and heating for reaction to obtain a core-layer seed emulsion; and
putting water, an emulsifier, an initiator, and constituent monomers of a polyvinylidene fluoride polymer into the core-layer seed emulsion, stirring, and heating under a reaction pressure for polymerization reaction, to obtain a core-shell-structured binder.
12 . The preparation method of binder according to claim 11 , wherein a mass ratio of the constituent monomers of the polyacrylate polymer to the constituent monomers of the polyvinylidene fluoride polymer is (2-100):1.
13 . The preparation method of binder according to claim 11 , wherein the step of mixing and stirring water, an emulsifier, an initiator, and constituent monomers of a polyacrylate polymer and heating for reaction to obtain a core-layer seed emulsion comprises the following steps:
mixing and stirring water, the emulsifier, and the constituent monomers of the polyacrylate polymer to obtain a core-layer monomer pre-emulsion; and
after temperature rise, adding in batches the initiator and stirring for reaction to obtain the core-layer seed emulsion after the reaction.
14 . The preparation method of binder according to claim 11 , wherein the constituent monomers of the polyvinylidene fluoride polymer comprise vinylidene fluoride;
or the constituent monomers of the polyvinylidene fluoride polymer comprise vinylidene fluoride and at least one of hexafluoropropylene, pentafluoropropylene, tetrafluoropropylene, trifluoropropylene, perfluorobutene, tetrafluoroethylene, trifluoroethylene, trifluorochloroethylene, and fluoroethylene.
15 . A separator, wherein the separator comprises the binder according to claim 1 .
16 . An electrode assembly, wherein the electrode assembly comprises the separator according to claim 15 .
17 . A battery cell, wherein the battery cell comprises the electrode assembly according to claim 16 .
18 . A battery, wherein the battery comprises the battery cell according to claim 17 .
19 . An electric apparatus, wherein the electric apparatus comprises the battery according to claim 18 .