Composition for semiconductor processing and processing method
A composition for semiconductor processing according to the disclosure contains (A) a compound represented by the following general formula (1), (B) a compound represented by the following general formula (2), (C) a compound having at least one functional group selected from the group consisting of an amino group and a salt thereof and a hydroxyl group (excluding the compound represented by the following general formula (1), a compound having a carboxyl group and a nitrogen-containing heterocyclic compound) and (D) a liquid medium, and, when the content of the (A) component is indicated by M A [mass %] and the content of the (B) component is indicated by M B [mass %], M A /M B is 1.0×10 2 to 1.0×10 4 . R 2 N(OH) (1) R 2 NH (2) (In the formula (1) and the formula (2), R's each independently represent an alkyl group having 1 to 4 carbon atoms).
1 . A composition for semiconductor processing comprising:
(A) a compound represented by the following general formula (1);
(B) a compound represented by the following general formula (2);
(C) a compound having at least one functional group selected from the group consisting of an amino group and a salt thereof and a hydroxyl group, excluding the compound represented by the following general formula (1), a compound having a carboxyl group and a nitrogen-containing heterocyclic compound; and
(D) a liquid medium,
wherein, a content of the (A) component is indicated by M A [mass %] and a content of the (B) component is indicated by M B [mass %], and M A /M B is 1.0×10 2 to 1.0×10 4 ,
R 2 N(OH) (1)
R 2 NH (2)
and in the formula (1) and the formula (2), each R independently represents an alkyl group having 1 to 4 carbon atoms.
2 . The composition for semiconductor processing according to claim 1 ,
wherein the (C) component is at least one selected from the group consisting of methanolamine, ethanolamine, isopropanolamine and diethylethanolamine.
3 . The composition for semiconductor processing according to claim 1 ,
wherein the (D) component is an aqueous medium.
4 . The composition for semiconductor processing according to claim 1 , further comprising:
a nitrogen-containing heterocyclic compound.
5 . A processing method comprising:
a step of processing a semiconductor substrate comprising contacting the composition for semiconductor processing according to claim 1 with the substrate.
6 . A processing method comprising:
a step of processing a semiconductor substrate comprising contacting the composition for semiconductor processing according to claim 2 with the substrate.
7 . A processing method comprising:
a step of processing a semiconductor substrate comprising contacting the composition for semiconductor processing according to claim 3 with the substrate.
8 . A processing method comprising:
a step of processing a semiconductor substrate comprising contacting the composition for semiconductor processing according to claim 4 with the substrate.
9 . A processing method comprising:
a step of supplying the composition for semiconductor processing according to claim 1 having a temperature of 25° C. or higher and 65° C. or lower
while a semiconductor substrate is rotated at 300 rpm or faster and 1000 rpm or slower
at a supply rate of the composition for semiconductor processing of 500 mL/minute or faster and 1500 mL/minute or slower
for a supply time of the composition for semiconductor processing of 30 seconds or longer and 300 seconds or shorter
to be brought into contact with the semiconductor substrate.
10 . A processing method comprising:
a step of supplying the composition for semiconductor processing according to claim 2 having a temperature of 25° C. or higher and 65° C. or lower
while a semiconductor substrate is rotated at 300 rpm or faster and 1000 rpm or slower
at a supply rate of the composition for semiconductor processing of 500 mL/minute or faster and 1500 mL/minute or slower
for a supply time of the composition for semiconductor processing of 30 seconds or longer and 300 seconds or shorter
to be brought into contact with the semiconductor substrate.
11 . A processing method comprising:
a step of supplying the composition for semiconductor processing according to claim 3 having a temperature of 25° C. or higher and 65° C. or lower
while a semiconductor substrate is rotated at 300 rpm or faster and 1000 rpm or slower
at a supply rate of the composition for semiconductor processing of 500 mL/minute or faster and 1500 mL/minute or slower
for a supply time of the composition for semiconductor processing of 30 seconds or longer and 300 seconds or shorter
to be brought into contact with the semiconductor substrate.
12 . A processing method comprising:
a step of supplying the composition for semiconductor processing according to claim 4 having a temperature of 25° C. or higher and 65° C. or lower
while a semiconductor substrate is rotated at 300 rpm or faster and 1000 rpm or slower
at a supply rate of the composition for semiconductor processing of 500 mL/minute or faster and 1500 mL/minute or slower
for a supply time of the composition for semiconductor processing of 30 seconds or longer and 300 seconds or shorter
to be brought into contact with the semiconductor substrate.