IP Library Granted Patent US 12,528,972
Granted Patent B2
US 12,528,972 · App. 18/488,556 · Granted Jan 20, 2026

Water-robustness of inkjet prints using paper precoat and methods thereof

Inventors: Varun Sambhy (Pittsford, NY); Eliud Robles Flores (Rochester, NY); Guo-Yau Lin (The Woodlands, TX); Santokh S. Badesha (Pittsford, NY)
Assignee: XEROX CORPORATION
C09D183/04B41M5/0017B41M7/0018B41M7/009C08L83/04C09D11/102C09D11/38C09D11/40C09D11/54B41J11/0015C09D11/52
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Quick Facts
Patent No.
US 12,528,972
App. No.
18/488,556
Filed
Oct 17, 2023
Granted
Jan 20, 2026
Kind
B2
Art Unit
2853
USPC
347/21
Abstract

A system for improving water fastness of printed documents is described, including a paper transport configured to move paper along a path throughout the system for improving water fastness, a precoat application subsystem located along the path of the paper transport may include a precoat composition applicator adjacent to or in contact with the paper transport, a printhead configured to eject ink onto a surface of the paper in an imagewise fashion, and a dryer. A method for improving water fastness of printed documents and a water fastness precoat composition for printed documents is also described, including a non-functional silicone fluid, a functional silicone fluid, or a combination thereof.

Claims (31)

1 . A system for improving water fastness of printed documents, comprising:

a paper transport configured to move paper along a path throughout the system for improving water fastness;

a precoat application subsystem located along the path of the paper transport comprising a precoat composition applicator adjacent to or in contact with the paper transport;

a printhead configured to eject ink onto a surface of the paper in an imagewise fashion; and

a dryer; and wherein:

the precoat composition comprises a functional silicone fluid, comprising a propyl mercapto functionality.

2 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat application subsystem further comprises one or more rollers positionable to contact a surface of the paper.

3 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat application subsystem comprises a liquid ejector positionable to eject droplets onto a surface of the paper in an imagewise fashion.

4 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat composition further comprises a non-functional silicone fluid.

5 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat composition further comprises a terminal propyl amine, or a combination thereof.

6 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat composition further comprises a aminopropyl- or fluoro-functional silicone.

7 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat composition comprises a fluoro-functional silicone.

8 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat composition further comprises a viscosity of from about 10 cP to about 5000 cP, when measured at 25° C.

9 . The system for improving water fastness of printed documents of claim 1 , wherein the precoat application subsystem is external to the printhead and the dryer.

10 . The system for improving water fastness of printed documents of claim 1 , wherein the paper is in the form of a continuous web.

11 . The system for improving water fastness of printed documents of claim 1 , wherein the paper is in the form of one or more discrete sheets.

12 . A method for improving water fastness of printed documents, comprising:

applying a precoat composition to a surface of a paper;

printing an image comprising a water-based ink onto the surface of the paper; and

heating the surface of the paper, the precoat composition, and the water-based ink; and wherein:

the precoat composition comprises a functional silicone fluid, comprising a propyl mercapto functionality.

13 . The method for improving water fastness of printed documents of claim 12 , wherein the precoat composition is applied to the surface of the paper using a precoat application subsystem further comprising one or more rollers positionable to contact a surface of the paper.

14 . The method for improving water fastness of printed documents of claim 12 , wherein the precoat composition is applied to the surface of the paper using a precoat application subsystem comprising a liquid ejector positionable to eject droplets onto a surface of the paper in an imagewise fashion.

15 . The method for improving water fastness of printed documents of claim 12 , further comprising pausing for up to 24 hours between the precoat composition to the surface of the paper and printing the image comprising the water-based ink onto the surface of the paper.

16 . The method for improving water fastness of printed documents of claim 12 , wherein the precoat composition further comprises an amine functional silicone fluid.

17 . The method for improving water fastness of printed documents of claim 12 , wherein the precoat composition further comprises a non-functional silicone fluid.

18 . A water fastness precoat composition for printed documents, comprising:

a non-functional silicone fluid; and

a functional silicone fluid, comprising a propyl mercapto functionality; and wherein

the functional silicone fluid is present in the water fastness precoat composition in an amount of from about 1 wt % to about 30 wt % based on a total weight of the water fastness precoat composition; and

the non-functional silicone fluid is present in the water fastness precoat composition in an amount of from about 50 wt % to about 99 wt % based on a total weight of the water fastness precoat composition.

Assignments (5)
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2023
From: SAMBHY, VARUN; FLORES, ELIUD ROBLES; LIN, GUO-YAU; BADESHA, SANTOKH S.
To: XEROX CORPORATION
Reel/Frame 065256/0553 →