SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND ELECTRIC APPARATUS
This application relates to a secondary battery, a battery module, a battery pack, and an electric apparatus. The secondary battery includes: a negative electrode plate including a negative electrode current collector and a negative electrode film layer disposed on the negative electrode current collector, the negative electrode film layer containing a carbon material; a positive electrode plate including a positive electrode current collector and a positive electrode active material layer disposed on the positive electrode current collector, the positive electrode active material layer containing a sodium-ion active material; and an electrolyte disposed between the negative electrode plate and the positive electrode plate, the electrolyte containing sodium salt and lithium salt.
1 . A secondary battery, characterized by comprising:
a negative electrode plate, comprising a negative electrode current collector and a negative electrode film layer disposed on the negative electrode current collector, the negative electrode film layer containing a carbon material;
a positive electrode plate, comprising a positive electrode current collector and a positive electrode active material layer disposed on the positive electrode current collector, the positive electrode active material layer containing a sodium-ion active material; and
an electrolyte, disposed between the negative electrode plate and the positive electrode plate, the electrolyte containing sodium salt and lithium salt.
2 . The secondary battery according to claim 1 , characterized in that the negative electrode film layer has a thickness of 0.3 μm to 3 μm, and the negative electrode film layer has a surface density of 5 g/m 2 to 50 g/m 2 .
3 . The secondary battery according to claim 1 , characterized in that the carbon material in the negative electrode film layer comprises at least one of carbon nanotubes, graphite, graphene, and carbon fiber.
4 . The secondary battery according to claim 1 , characterized in that based on a mass of the electrolyte, a mass percentage of the lithium salt is 0.1% to 10%.
5 . The secondary battery according to claim 1 , characterized in that the negative electrode film layer has a surface density of x g/m 2 , wherein x=5 g/m 2 to 50 g/m 2 ; based on a mass of the electrolyte, a mass percentage of the lithium salt is y %; and
x and y satisfy the following condition: 0.84≤y−0.01x≤5.84.
6 . The secondary battery according to claim 1 , characterized in that the lithium salt comprises at least one of lithium hexafluorophosphate, lithium tetrafluoroborate, lithium perchlorate, lithium hexafluoroarsenate, lithium trifluoroacetate, lithium tetraphenylborate, lithium trifluoromethanesulfonate, lithium bisoxalatoborate, lithium difluorooxalate borate, lithium bis(fluorosulfonyl)imide, and lithium bis(trifluoromethanesulfonyl)imide.
7 . The secondary battery according to claim 1 , characterized in that a mass percentage of the sodium salt in the electrolyte is 3% to 25%;
and/or the electrolyte further comprises a solvent, and a mass percentage of the solvent in the electrolyte is 70% to 95%.
8 . The secondary battery according to claim 7 , characterized in that the sodium salt comprises at least one of sodium perchlorate, sodium tetrafluoroborate, sodium hexafluorophosphate, sodium hexafluoroarsenate, sodium trifluoroacetate, sodium tetraphenylborate, sodium trifluoromethanesulfonate, sodium bis(fluorosulfonyl)imide, and sodium bis(trifluoromethanesulfonyl)imide;
and/or the solvent comprises at least one of ether solvent, ester solvent, alkane solvent, and sulfonyl solvent.
9 . The secondary battery according to claim 8 , characterized in that the solvent comprises at least one of ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, 1,3-dioxolane, ethylene carbonate, propylene carbonate, butyl ene carbonate, vinylene carbonate, fluoroethylene carbonate, ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, γ-butyrolactone, 1,3-propane sultone, methyl propionate, methyl butyrate, ethyl acetate, ethyl propionate, propyl propionate, ethyl butyrate, and dimethyl sulfoxide.
10 . A battery module, characterized by comprising the secondary battery according to claim 1 .
11 . A battery pack, characterized by comprising the battery module according to claim 10 .
12 . An electric apparatus, characterized in that the electric apparatus comprises at least one of the secondary battery according to claim 1 , the battery module according to claim 10 , and the battery pack according to claim 11 , the secondary battery being configured to supply power.