POSITIVE ELECTRODE PLATE, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK AND POWER CONSUMING DEVICE
A positive electrode plate, a secondary battery, a battery module, a battery pack and a power consuming device are described. The positive electrode plate comprises a current collector, a primer coating layer provided on at least one surface of the current collector, and a positive electrode film provided on the primer coating layer, wherein the primer coating layer contains a polymer A soluble in an aqueous solvent, and the polymer A comprises a structural unit derived from a monomer containing a cyano group, a structural unit derived from a monomer containing an amide group, and a structure unit derived from a monomer containing an ester group. The polymer A is used in the primer coating layer of the positive electrode plate, which increases the molding quality, adhesive force and flexibility of the positive electrode plate, and optimizes the cycling performance of the battery.
1 . A positive electrode plate comprising a current collector, a primer coating layer provided on at least one surface of the current collector, and a positive electrode film provided on the primer coating layer, wherein the primer coating layer contains a polymer A soluble in an aqueous solvent, and the polymer A comprises a structural unit derived from a monomer containing a cyano group, a structural unit derived from a monomer containing an amide group, and a structure unit derived from a monomer containing an ester group.
2 . The positive electrode plate according to claim 1 , wherein the weight average molecular weight of the polymer A in the primer coating layer is 1.5×10 5 -2×10 5 .
3 . The positive electrode plate according to claim 1 , wherein the mass content of the polymer A in the primer coating layer is 5%-40%, optionally 5%-30%, and optionally 5%-20%, based on the total mass of the primer coating layer.
4 . The positive electrode plate according to claim 1 , wherein the primer coating layer further comprises a conductive agent, and the conductive agent is selected from one or more of carbon black, acetylene black, carbon fiber, graphite, and carbon nanotubes.
5 . The positive electrode plate according to claim 1 , wherein the thickness of the primer coating layer is 1-20 μm.
6 . The positive electrode plate according to claim 1 , wherein the positive electrode film comprises a positive electrode active substance, a binder and a conductive agent, wherein the binder comprises a polymer A soluble in an oily solvent, and the polymer A comprises a structural unit derived from a monomer containing a cyano group, a structural unit derived from a monomer containing an amide group, and a structure unit derived from a monomer containing an ester group.
7 . The positive electrode plate according to claim 6 , wherein the positive electrode film comprises the polymer A with a weight average molecular weight of 7×10 5 -1×10 6 .
8 . The positive electrode plate according to claim 7 , wherein the positive electrode film also comprises the polymer A with a weight average molecular weight of 1×10 5 -2.5×10 5 .
9 . The positive electrode plate according to claim 6 , wherein the positive electrode active substance is a lithium-containing transition metal oxide, and the positive electrode active substance is optionally lithium ferrous phosphate or the doped and modified materials thereof, or at least one of the conductive carbon-coated modified materials, conductive metal-coated modified materials or conductive polymer-coated modified materials thereof.
10 . The positive electrode plate according to claim 6 , wherein the mass content of the positive electrode active substance is 70%-99.5%, and optionally 88%-99.5%, based on the mass of the positive electrode film.
11 . The positive electrode plate according to claim 6 , wherein the mass content of the polymer A with a weight average molecular weight of 7×10 5 -1×10 6 in the positive electrode film is 0.4%-5.5%, and/or the mass content of the polymer A with a weight average molecular weight of 1×10 5 -2.5×10 5 in the positive electrode film is 0.05%-0.5%, based on the mass of the positive electrode film.
12 . The positive electrode plate according to claim 1 , wherein
the monomer containing a cyano group in the polymer A is selected from one or more of acrylonitrile and crotonitrile;
the monomer containing an amide group is selected from one or more of methacrylamide, N-methyl methacrylamide, N-ethyl methacrylamide, N-n-propyl methacrylamide, N-isopropyl methacrylamide, N-n-butyl methacrylamide, N-isobutyl methacrylamide, N,N-dimethyl acrylamide, N,N-dimethyl methacrylamide, N,N-diethyl acrylamide and N,N-diethyl methacrylamide; and
the monomer containing an ester group is selected from one or more of methyl acrylate, ethyl acrylate, butyl acrylate, isoamyl acrylate, isooctyl acrylate, methyl methacrylate, ethyl methacrylate, hydroxyethyl acrylate and hydroxypropyl acrylate.
13 . The positive electrode plate according to claim 1 , wherein
the molar content of the structural unit derived from a monomer containing a cyano group in the polymer A is 50%-70%, the molar content of the structural unit derived from a monomer containing an ester group is 10%-30%, and the molar content of the structural unit derived from a monomer containing an amide group is 10%-30%, based on the total molar content of structural units in the polymer A, respectively.
14 . A secondary battery, comprising an electrode assembly and an electrolyte solution, wherein the electrode assembly comprises a positive electrode plate according to claim 1 , a separator and a negative electrode plate.
15 . A battery module, comprising a secondary battery according to claim 14 .
16 . A battery pack, comprising a battery module according to claim 15 .
17 . A power consuming device, comprising a secondary battery according to claim 14
18 . A power consuming device, comprising a battery module according to claim 15 .
19 . A power consuming device, comprising a battery pack according to claim 16 .