ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent compound according to the present disclosure is contained in a hole transport layer and/or a hole auxiliary layer, so that an organic electroluminescent device having improved light-emitting efficiency and driving lifespan can be manufactured.
1 . An organic electroluminescent compound represented by the following formula 1:
wherein,
R 1 and R 2 each independently represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to an adjacent substituent to form a substituted or unsubstituted ring;
R 3 and R 4 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, or a substituted or unsubstituted tri(C6-C30)arylsilyl;
L represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
Ar 1 and Ar 2 each independently represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to each other to form a substituted or unsubstituted ring;
a represent an integer from 1 to 4, b represents an integer 1 or 2, when a or b is an integer of 2 or more, each of R 3 or each of R 4 may be the same or different; and
c represents an integer 1 or 2, when c is an integer 2, each of Ar 1 or each of Ar 2 may be the same or different.
2 . The organic electroluminescent compound according to claim 1 , wherein the formula 1 is represented by any one of the following formulae 1-1 to 1-6:
wherein, R 1 to R 4 , Ar 1 , Ar 2 , L, a, and b are as defined in claim 1 .
3 . The organic electroluminescent compound according to claim 1 , wherein Ar 1 and Ar 2 each independently represent any one of the the substituents selected from the following group I:
wherein, A 1 to A3 each independently represent a substituted or unsubstituted (C1-C30)alkyl or a substituted or unsubstituted (C6-C30)aryl;
L′ represents a substituted or unsubstituted (C6-C30)arylene or a substituted or unsubstituted (3- to 30-membered)heteroarylene; and
represents bonding position with N.
4 . The organic electroluminescent compound according to claim 1 , wherein, R 1 and R 2 each independently represent hydrogen, a substituted or unsubstituted (C1-C18)alkyl, or a substituted or unsubstituted (C6-C18)aryl,
R 3 and R 4 each independently represent hydrogen or a substituted or unsubstituted (C6-C18)aryl,
L represent a single bond or a substituted or unsubstituted (C6-C18)arylene, and
Ar 1 and Ar 2 each independently represent one of the substituents listed in group I of claim 3 or are linked each other, so that the amine group forms a substituted or unsubstituted carbazole.
5 . The organic electroluminescent compound according to claim 1 , wherein the formula 1 is represented by any one of the following formulae I-1 to I-4:
wherein, R 1 to R 4 , L, a, and b are as defined in claim 1 ;
R 5 represents hydrogen or —NR x R y ;
R x and R y each independently represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, or a substituted or unsubstituted (C6-C30)aryl; and
d represents an integer of 1 or 2, when d is 2, each of R 5 may be the same or different.
6 . The organic electroluminescent compound according to claim 1 , wherein the substituents of the substituted (C1-C30)alkyl, the substituted (C6-C30)aryl(ene), the substituted (3- to 30-membered)heteroaryl(ene), the substituted (C3-C30)cycloalkyl, the substituted (C1-C30)alkoxy, the substituted tri(C1-C30)alkylsilyl, the substituted di(C1-C30)alkyl(C6-C30)arylsilyl, the substituted (C1-C30)alkyldi(C6-C30)arylsilyl, the substituted tri(C6-C30)arylsilyl, and the substituted ring, in R 1 to R 4 , Ar 1 , Ar 2 , and L, each independently, are at least one selected from the group consisting of deuterium, halogen, cyano, carboxyl, nitro, hydroxyl, (C1-C30)alkyl, halo(C1-C30)alkyl, (C2-C30)alkenyl, (C2-C30)alkynyl, (C1-C30)alkoxy, (C1-C30)alkylthio, (C3-C30)cycloalkyl, (C3-C30)cycloalkenyl, (3- to 7-membered) heterocycloalkyl, (C6-C30)aryloxy, (C6-C30)arylthio, (C6-C30)aryl-substituted or unsubstituted (5- to 30-membered)heteroaryl, (5- to 30-membered)heteroaryl-substituted or unsubstituted (C6-C30)aryl, tri(C1-C30)alkylsilyl, tri(C6-C30)arylsilyl, di(C1-C30)alkyl(C6-C30)arylsilyl, (C1-C30)alkyldi(C6-C30)arylsilyl, amino, mono- or di-(C1-C30)alkylamino, (C1-C30)alkyl-substituted or unsubstituted mono- or di-(C6-C30)arylamino, (C1-C30)alkyl(C6-C30)arylamino, (C1-C30)alkylcarbonyl, (C1-C30)alkoxycarbonyl, (C6-C30)arylcarbonyl, di(C6-C30)arylboronyl, di(C1-C30)alkylboronyl, (C1-C30)alkyl(C6-C30)arylboronyl, (C6-C30)ar(C1-C30)alkyl, and (C1-C30)alkyl(C6-C30)aryl.
7 . The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is selected from the group consisting of:
8 . An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .
9 . An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
10 . The organic electroluminescent device according to claim 9 , wherein the organic electroluminescent compound is contained in a hole transport layer and/or a hole auxiliary layer.