Secondary battery, battery module, battery pack and electric device
View Patent ↗Provided are a secondary battery, a battery module, a battery pack and an electric device. The secondary battery includes an electrode assembly and an electrolytic solution configured to infiltrate the electrode assembly, wherein the electrode assembly includes a negative electrode plate, a separation film and a positive electrode plate, and the negative electrode plate includes a negative electrode current collector and a negative electrode material layer located on at least one surface of the negative electrode current collector; and by setting a tortuosity of the negative electrode plate as τ, the τ satisfies Formula I below: τ=0.5(ε) −α Formula I where, ε is a porosity of the negative electrode material layer, and α is a Bruggeman index of the negative electrode material layer, and the τ and a conductivity σ of the electrolytic solution satisfy Formula II below: (2τ) 0.5 +6≤σ≤(2τ) 0.5 +10 Formula II. Therefore, the secondary battery has an excellent fast-charging performance.
1. A secondary battery, comprising
an electrode assembly and an electrolytic solution configured to infiltrate the electrode assembly, wherein
the electrode assembly comprises a negative electrode plate, a separation film and a positive electrode plate, and the negative electrode plate includes a negative electrode current collector and a negative electrode material layer located on at least one surface of the negative electrode current collector;
by setting a tortuosity of the negative electrode plate as τ, the τ satisfies Formula I below:
τ=0.5(ε) −α Formula I
where, ε is a porosity of the negative electrode material layer, and α is a Bruggeman index of the negative electrode material layer,
the τ and a conductivity σ of the electrolytic solution satisfy Formula II below:
6≤σ−(2τ) 0.5 ≤10 Formula II,
the τ satisfies: 4.9≤τ≤7, and
the σ ranges from 8 mS/cm to 14 mS/cm.
2. The secondary battery according to claim 1 , wherein
the porosity ε of the negative electrode material layer is 25% to 45%.
3. The secondary battery according to claim 1 , wherein
a negative electrode material is graphite, and the α is 1.5 to 2.2.
4. The secondary battery according to claim 1 , wherein
the electrolytic solution includes at least one of cyclic esters including ethylene carbonate and propylene carbonate, as well as at least one of dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, ethyl acetate, methyl acetate, methyl formate, ethyl formate, methyl propionate, propyl formate, ethyl propionate and propyl acetate.
5. The secondary battery according to claim 1 , wherein
a lithium salt of the electrolytic solution includes at least one of lithium hexafluorophosphate and lithium fluorosulfonyl imide, and has a concentration of 0.5-1.5 mol/L.
6. The secondary battery according to claim 5 , wherein
the lithium fluorosulfonyl imide includes at least one of lithium bis(fluorosulfonyl)imide, lithium fluoro (trifluoromethyl) sulfonylimide, lithium bis(trifluoromethyl) sulfonylimide, lithium bis(pentafluoroethyl) sulfonylimide and lithium fluoro (perfluorobutyl) sulfonylimide, preferably the lithium bis(fluorosulfonyl)imide.
7. The secondary battery according to claim 1 , wherein
a thickness of the negative electrode material layer is 30 μm-400 μm in the negative electrode plate.
8. A battery module, comprising
the secondary battery according to claim 1 .
9. A battery pack, comprising
the battery module according to claim 8 .
10. An electric device, comprising
the battery pack according to claim 9 .