Laminate and Coating Composition
Provided is a laminate that may exhibit thermally stable hydrophilicity, and a coating composition that may be used for such a laminate. A laminate according to one embodiment of the present disclosure includes: a substrate; a first layer disposed on at least one surface of the substrate, the first layer including a binder and an inorganic nanoparticle; and a hydrophilic second layer disposed on the first layer, the binder containing a cured product of a binder precursor containing 30 mass % or greater of a tri- or higher functional (meth)acrylate monomer relative to a total amount of the binder, and the inorganic nanoparticle having a (meth)acryloyl group.
1 . A laminate comprising: a substrate;
a first layer disposed on at least one surface of the substrate, the first layer comprising a binder and an inorganic nanoparticle; and
a second layer that is hydrophilic, the second layer being disposed on the first layer,
the binder containing a cured product of a binder precursor, the binder precursor containing 30 mass % or greater of a tri- or higher functional (meth)acrylate monomer relative to a total amount of the binder, and the inorganic nanoparticle having a (meth)acryloyl group.
2 . The laminate according to claim 1 , wherein the first layer contains the inorganic nanoparticle in an amount of more than 50 mass % based on the total weight of the first layer.
3 . The laminate according to claim 1 , wherein the inorganic nanoparticle is at least one kind of particle selected from the group consisting of silica, alumina, zinc oxide, zirconium oxide, tin-doped indium oxide, and antimony-doped tin oxide.
4 . The laminate according to claim 1 , wherein the second layer contains a zwitterionic silane.
5 . The laminate according to claim 1 , wherein the substrate is a transparent substrate.
6 . The laminate according to claim 5 , having a haze value of 10% or less.
7 . The laminate according to claim 1 , further comprising an adhesive layer disposed on a surface of the substrate that is opposite to a side of the second layer.
8 . An article comprising the laminate described in claim 1 .
9 . The article according to claim 8 , which is used as a medical device.
10 . The article according to claim 9 , which is used as a microfluidic chip.
11 . A coating composition comprising a binder precursor and an inorganic nanoparticle, the binder precursor containing 30 mass % or greater of a tri- or higher functional (meth)acrylate monomer relative to a total amount of the binder precursor, and the inorganic nanoparticle having a (meth)acryloyl group,
wherein the coating composition forms a layer on which a hydrophilic layer is applied.
12 . The composition according to claim 11 , wherein the (meth)acrylate monomer has a (meth)acryloyl equivalent from 80 to 700.
13 . The composition according to claim 11 , wherein the (meth)acrylate monomer is at least one selected from the group consisting of tris[2-((meth)acryloyloxy)ethyl] isocyanurate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, pentaerythritol alkoxy tetra(meth)acrylate, dipentaerythritol hexa(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, ethoxylated pentaerythritol tetra(meth)acrylate, a tri- or higher functional urethane (meth)acrylate, and a tri- or higher functional epoxy (meth)acrylate.
14 . The composition according to claim 11 , comprising the inorganic nanoparticle in an amount greater than 50 parts by mass based on 100 parts by mass of a solid content of the composition.