IP Library Granted Patent US 12,544,321
Granted Patent B2
US 12,544,321 · App. 18/554,695 · Granted Feb 10, 2026

Hair treatment method

Inventors: Luisa Zoe Collins (Chester, GB); Rongrong Zhou (Wirral, GB)
Assignee: Conopco, Inc.
A61K8/27A61K8/737A61K8/8141A61Q5/02A61Q5/12
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Quick Facts
Patent No.
US 12,544,321
App. No.
18/554,695
Granted
Feb 10, 2026
Kind
B2
Abstract

A method of providing anti-frizz to hair, comprising the steps of: (i) applying a shampoo composition to the hair, wherein the composition comprises (a) from 0.05 wt % to 1.4 wt % a soluble zinc compound. (b) a cleansing surfactant selected from anionic surfactants and mixtures thereof. (c) from 0.1 wt % to 10 wt % of a suspending agent, and (d) from 0.01 wt % to 5 wt % of a cationic deposition polymer; and; wherein the composition has a pH of from 3 to 5; and (ii) rinsing the composition from the hair.

Claims (24)

1 . A method of providing anti-frizz to hair, the method comprising the steps of

(i) applying a shampoo composition to the hair, wherein the shampoo composition comprises

(a) from 0.05 wt % to 1.4 wt % a soluble zinc compound,

(b) a cleansing surfactant selected from anionic surfactants and mixtures thereof,

(c) from 0.1 wt % to 10 wt % of a suspending agent, and

(d) from 0.01 wt % to 5 wt % of a cationic deposition polymer; and

wherein the composition has a pH of from 3 to 5; and

(ii) rinsing the composition from the hair.

2 . The method of claim 1 , wherein the soluble zinc compound is selected from the group consisting of zinc sulphate, zinc chloride, zinc gluconate, zinc acetate, and mixtures thereof.

3 . The method of claim 2 , wherein the soluble zinc compound is zinc sulphate.

4 . The method of claim 1 , wherein a level of soluble zinc compound in the total composition is from 0.1 wt % to 1.25 wt % by weight of the total composition.

5 . The method of claim 1 , wherein the composition further comprises a preservative.

6 . The method of claim 1 , wherein the composition further comprises from 0.01 wt % to 10 wt % of an emulsified silicone.

7 . The method of claim 1 , wherein the suspending agent is selected from the group consisting of polyacrylic acids, cross-linked polymers of acrylic acid, copolymers of acrylic acid with a hydrophobic monomer, copolymers of carboxylic acid-containing monomers and acrylic esters, cross-linked copolymers of acrylic acid and acrylate esters, heteropolysaccharide gums and crystalline long chain acyl derivatives and mixtures thereof.

8 . The method of claim 7 , wherein the suspending agent is a mixture of a cross-linked polymer of acrylic acid and a crystalline long chain acyl derivative.

9 . The method of claim 1 , wherein the suspending agent is present in an amount of from 0.1 wt % to 5 wt %.

10 . The method of claim 1 , wherein the cationic deposition polymer is selected from the group consisting of cationic diallyl quaternary ammonium-containing polymers, mineral acid salts of amino-alkyl esters of homo- and co-polymers of unsaturated carboxylic acids having from 3 to 5 carbon atoms, cationic polyacrylamides, cationic polysaccharide polymers and mixtures thereof.

11 . The method of claim 10 , wherein the cationic polysaccharide polymer is selected from the group consisting of cationic cellulose derivatives, cationic starch derivatives, cationic guar gum derivatives and mixtures thereof.

12 . The method of claim 1 , wherein the cationic deposition polymer is present in an amount of from 0.02 wt % to 1 wt %.

13 . The method of claim 1 comprising the following sequential steps

i) application of the shampoo composition to the hair for a maximum time period of 20 minutes; and

ii) rinsing the hair.

14 . The method of claim 1 , wherein the shampoo composition provides anti-frizz to hair.

15 . The method of claim 1 , wherein a level of soluble zinc compound in the total composition is from 0.1 wt % to 1 wt % by weight of the total composition.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2024
From: COLLINS, LUISA ZOE; ZHOU, RONGRONG
To: CONOPCO, INC., D/B/A UNILEVER
Reel/Frame 069124/0734 →
Priority Claims (1)
EP 21168736 · Apr 15, 2021 · regional
Continuity (1)
Related Publication 20240180801A1 · Jun 6, 2024
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