Improved Polymer Composition
The invention provides polymer compositions that are resistant to burning and which show reduced smoke production when exposed to heat or flame.
1 . A flame-retardant polymer composition comprising:
(1) at least one polymer selected from polyesters (e.g. copolyetheresters, copolyesteresters), polyamides, polyamide elastomers, thermoplastic polyolefinic elastomers, styrenic elastomers, thermoplastic polyurethanes and thermoplastic vulcanisates;
(2) aluminium diethylphosphinate; and
(3) titanium diethylphosphinate salt.
2 . A flame-retardant polymer composition according to claim 1 , comprising:
(1) at least one polymer selected from copolyetheresters, copolyesteresters, polyamides, polyamide elastomers, thermoplastic polyolefinic elastomers, styrenic elastomers, thermoplastic polyurethanes, thermoplastic vulcanisates, or a combination thereof;
(2) aluminium diethylphosphinate; and
(3) titanium diethylphosphinate salt; wherein if the d 50 of the titanium diethylphosphinate salt (volume %, measured using laser diffraction technology with a Malvern Mastersizer 2000 particle size analyser instrument, in acetone) is greater than 35 microns, the concentration of the aluminium diethylphosphinate is less than or equal to 15 wt %, based on the total weight of the composition.
3 . (canceled)
4 . The composition of claim 1 , wherein the copolyetherester is made by reacting a C 2 -C 6 diol with an aromatic diacid moiety and a poly(alkyleneoxide)diol.
5 . The composition of claim 1 , wherein the copolyetherester is made using a poly(alkyleneoxide)diol selected from poly(ethyleneoxide)diol, poly(propyleneoxide)diol, poly(tetramethyleneoxide)diol (“PTMEG”), and mixtures of these.
6 . The composition of claim 1 , wherein the copolyetherester is made using a C 2 -C 6 diol selected from ethylene glycol, propylene glycol, butylene glycol, and mixtures of these.
7 . The composition of claim 1 , wherein the copolyetherester is made using an aromatic diacid selected from terephthalate, /so-terephthalate, and mixtures of these.
8 . The composition of claim 1 , wherein the copolyetherester is made from butylene diol, terephthalate and PTMEG.
9 . The composition of claim 1 , wherein the concentration of DEPAI (2) plus DEPTi (3) is between 8-30 wt %, based on the total weight of the composition.
10 . The composition of claim 1 , wherein the concentration of DEPAI is 5 to 25 wt %, based on the total weight of the composition and the concentration of DEPTi is 1 to 15 wt. % based on the total weight of the composition.
11 - 12 . (canceled)
13 . The composition of claim 1 , wherein the DEPTi has a D 50 (volume %, measured using laser diffraction technology with a Malvern Mastersizer 2000 particle size analyser instrument, in acetone) of ≤35 microns.
14 . (canceled)
15 . The composition of claim 1 , which further comprises an aluminium salt of phosphorous acid, a zinc salt of phosphorous acid or both.
16 . The composition of claim 1 , further comprising aluminium phosphite having the CAS number [CAS 56287-23-1], zinc phosphite having CAS number [CAS 14332-59-3], or a mixture of these.
17 - 18 . (canceled)
19 . The composition of claim 1 , wherein the total phosphite concentration is from 0.1 to 20 wt %, based on the total weight of the composition.
20 . The composition of claim 1 , wherein the ratio of DEPAI/DEPTi is less than or equal to 1.
21 . (canceled)
22 . The composition of claim 1 , which further comprises a nitrogen- and/or phosphorus-containing synergist.
23 . (canceled)
24 . The composition of claim 22 , wherein the nitrogen-containing synergist is present at from 2 to 10 wt %, based on the total weight of the composition.
25 . (canceled)
26 . The composition of claim 1 , comprising:
(1) at least one copolyetherester;
(2) DEPAI;
(3) DEPTi;
(4) an aluminium or zinc salt of phosphorous acid, a zinc salt of phosphorous acid or both;
(5) a nitrogen-containing synergist.
27 . (canceled)
28 . A composition according to claim 26 , wherein the nitrogen-containing synergist is melamine pyrophosphate.
29 . A composition according to claim 26 , wherein the DEPAI is present at 5 to 15 wt %, based on the total weight of the composition and the DEPTi is present at 5 to 15 wt. % based on the total weight of the composition.
30 - 38 . (canceled)
39 . A wire or cable comprising a light- or electricity-conducting core surrounded by a sheath made from the composition of claim 1 .
40 . A shaped article made from the composition according to claim 1 .
41 . A method for making the composition of claim 1 , comprising melt-mixing the ingredients.