Systems and methods for removing carbon dioxide from a combustion flue gas and/or air
View Patent ↗Systems and methods for removing carbon dioxide from a combustion flue gas and/or air by using a high-pressure aqueous ammonia solvent and a plurality of liquid driven ejectors to absorb and remove the carbon dioxide for carbon capture utilization or storage. The aqueous ammonia solvent is regenerated at a high pressure to save potential compression energy required for the absorption and removal of carbon dioxide.
1. A system for removing carbon dioxide from a combustion flue gas or air, comprising:
a first ejector having a suction port, a motive port and an outlet;
an ammonia solvent liquid stream in fluid communication with the first ejector motive port;
a mixed feed gas stream with carbon dioxide or an air stream with carbon dioxide in fluid communication with the first ejector suction port, the mixed feed gas stream comprising a combustion flue gas stream and a flash gas stream;
a first two-phase fluid stream in fluid communication with the first ejector outlet and a first separator;
a second ejector having a suction port, a motive port and an outlet;
a first water wash stream in fluid communication with the second ejector motive port;
a first gas stream connected to the first separator and the second ejector suction port, the first gas stream comprising less carbon dioxide than the mixed feed gas stream or the air stream and a residual amount of ammonia solvent from the ammonia solvent liquid stream;
a first liquid stream connected to the first separator, the first liquid stream comprising a portion of the ammonia solvent liquid stream and absorbed carbon dioxide;
a second two-phase fluid stream in fluid communication with the second ejector outlet and a second separator;
an absorber connected to the first water wash stream;
a second gas stream connected to the second separator and the absorber, the second gas stream comprising less carbon dioxide and ammonia solvent than the first gas stream;
a second liquid stream connected to the second separator, the second liquid stream comprising another portion of the ammonia solvent liquid stream, absorbed carbon dioxide and a portion of the first water wash stream; and
a treated gas stream connected to the absorber the treated gas stream comprising less carbon dioxide than the second gas stream.
2. The system of claim 1 , further comprising a first heat exchanger positioned between the first ejector and the first separator and enclosing a portion of the first two-phase fluid stream and a first portion of a cooled water stream.
3. The system of claim 2 , further comprising a second heat exchanger enclosing a portion of a mixed liquid feed stream comprising the first liquid stream, the second liquid stream and a recovered ammonia stream and a second portion of the cooled water stream.
4. The system of claim 3 , further comprising a third separator in fluid communication with the mixed liquid feed stream and connected to the flash gas stream and a third liquid stream comprising ammonia solvent in the ammonia solvent liquid stream and carbon dioxide.
5. The system of claim 4 , further comprising a regenerator in fluid communication with the third liquid stream and connected to a third gas stream comprising carbon dioxide and a fourth liquid stream comprising the ammonia solvent in the ammonia solvent liquid stream and water in the first water wash stream and a second water wash stream.
6. The system of claim 5 , wherein the second water wash stream is connected to an upper section of the regenerator.
7. The system of claim 6 , further comprising a third heat exchanger enclosing a portion of the third liquid stream and a portion of the fourth liquid stream.
8. The system of claim 7 , further comprising a fourth heat exchanger enclosing a portion of the fourth liquid stream and a portion of a fifth liquid stream comprising the first water wash stream, the second water wash stream and a third water wash stream.
9. The system of claim 8 , further comprising a distillation column connected to the fourth liquid stream, the fifth liquid stream and a fourth gas stream comprising the recovered ammonia stream and a non-condensable component stream.
10. The system of claim 9 , further comprising a fourth separator in fluid communication with the fourth gas stream and connected to the recovered ammonia stream and the non-condensable component stream.
11. A method for removing carbon dioxide from a combustion flue gas or air, comprising:
routing an ammonia solvent liquid stream through a first ejector motive port;
drawing a mixed feed gas stream with carbon dioxide or an air stream with carbon dioxide through a first ejector suction port, the mixed feed gas stream comprising a combustion flue gas stream and a flash gas stream;
discharging a first two-phase fluid stream through a first ejector outlet, the first two-phase fluid stream comprising a mixture of the ammonia solvent liquid stream and one of the mixed feed gas stream and the air stream;
separating the first two-phase fluid stream into a first gas stream and a first liquid stream, the first gas stream comprising less carbon dioxide than the mixed feed gas stream or the air stream and a residual amount of ammonia solvent from the ammonia solvent liquid stream and the first liquid stream comprising a portion of the ammonia solvent liquid stream and absorbed carbon dioxide;
routing a first water wash stream through a second ejector motive port;
drawing the first gas stream through a second ejector suction port;
discharging a second two-phase fluid stream through a second ejector outlet, the second two-phase fluid stream comprising a mixture of the first water wash stream and the first gas stream;
separating the second two-phase fluid stream into a second gas stream and a second liquid stream, the second gas stream comprising less carbon dioxide and ammonia solvent than the first gas stream and the second liquid stream comprising another portion of the ammonia solvent liquid stream, absorbed carbon dioxide and a portion of the first water wash stream;
routing the first water wash stream and the second gas stream to an absorber; and
processing the first water wash stream and the second gas stream in the absorber to produce a treated gas stream comprising less carbon dioxide than the second gas stream.
12. The method of claim 11 , further comprising cooling the first two-phase fluid stream.
13. The method of claim 12 , further comprising cooling a mixed liquid feed stream comprising the first liquid stream, the second liquid stream and a recovered ammonia stream.
14. The method of claim 13 , further comprising separating the mixed liquid feed stream into the flash gas stream and a third liquid stream comprising ammonia solvent in the ammonia solvent liquid stream and carbon dioxide.
15. The method of claim 14 , further comprising separating the third liquid stream into a third gas stream comprising carbon dioxide and a fourth liquid stream comprising the ammonia solvent in the ammonia solvent liquid stream and water in the first water wash stream and a second water wash stream.
16. The method of claim 15 , further comprising cooling the fourth liquid stream using the third liquid stream.
17. The method of claim 16 , further comprising heating the fourth liquid stream using a fifth liquid stream comprising the first water wash stream, the second water wash stream and a third water wash stream.
18. The method of claim 17 , further comprising separating the fourth liquid stream into the fifth liquid stream and a fourth gas stream comprising the recovered ammonia stream and a non-condensable component stream.
19. The method of claim 18 , further comprising separating the fourth gas stream into the recovered ammonia stream and the non-condensable component stream.
20. The method of claim 11 , wherein a pressure of the mixed feed gas stream or the air stream is increased from about 0 PSIG to about 15 PSIG after it is drawn through the first ejector suction port.