BINDER, PREPARATION METHOD THEREFOR, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK AND POWER CONSUMING DEVICE
The present application provides a binder, a preparation method therefor, a secondary battery, a battery module, a battery pack, and a power consuming device. The binder comprises a polymer comprising structural units derived from a monomer represented by formula I and structural units derived from a monomer represented by formula II, wherein R 1 and R 2 are each independently selected from hydrogen or substituted or unsubstituted C 1-5 alkyl, R 3 is selected from hydrogen or methyl, and R 4 is selected from substituted or unsubstituted C 1-9 alkyl. The binder can be coated on the surface of the positive electrode active material, which is beneficial to maintain the structural integrity of the positive electrode active material during the cycling of the positive electrode plate, thereby improving the cycling performance of the battery.
1 . A binder, comprising a polymer comprising structural units derived from a monomer represented by formula I and structural units derived from a monomer represented by formula II,
wherein R 1 and R 2 are each independently selected from hydrogen or substituted or unsubstituted C 1-5 alkyl, R 3 is selected from hydrogen or methyl, and R 4 is selected from substituted or unsubstituted C 1-9 alkyl.
2 . The binder according to claim 1 , wherein in the polymer, the molar content of the structural units derived from the monomer represented by formula I is 60%-80%, and the molar content of the structural units derived from the monomer represented by formula II is 20%-40%, based on the total number of moles of all structural units in the polymer.
3 . The binder according to claim 1 , wherein the polymer has a weight average molecular weight of 700,000-1,000,000.
4 . The binder according to claim 1 , wherein the polymer is prepared as a solution with a solid content of 7% in N-methylpyrrolidone (NMP) solvent, and the viscosity of the solution is 4500-7500 mPa·s when measured at 25° C.
5 . The binder according to claim 1 , wherein the monomer represented by formula I is selected from one or more of acrylonitrile and butenenitrile.
6 . The binder according to claim 1 , wherein the monomer represented by formula II is selected from one or more of methyl acrylate, ethyl acrylate, butyl acrylate, isopentyl acrylate, isooctyl acrylate, methyl methacrylate, ethyl methacrylate, hydroxyethyl acrylate, and hydroxypropyl acrylate, or from one or more of methyl acrylate, butyl acrylate, and isooctyl acrylate.
7 . A method for preparing a binder, comprising the steps of:
providing a monomer represented by formula I and a monomer represented by formula II,
wherein R 1 and R 2 are each independently selected from hydrogen or substituted or unsubstituted C 1-5 alkyl, R 3 is selected from hydrogen or methyl, and R 4 is selected from substituted or unsubstituted C 1-9 alkyl;
polymerizing the monomer represented by formula I and the monomer represented by formula II under polymerizable conditions to prepare a polymer.
8 . A positive electrode plate, comprising a positive electrode active material, a conductive agent, and a binder according to claim 1 .
9 . The positive electrode plate according to claim 8 , wherein the positive electrode active material is a lithium-containing transition metal oxide.
10 . The positive electrode plate according to claim 8 , wherein the mass ratio of the binder to the positive electrode active material is 0.01:100-6:100, or 0.2:100-3:100, or 0.8:100-2:100.
11 . The positive electrode plate according to claim 8 , wherein the conductive agent is selected from one or more of conductive carbon black, conductive graphite, carbon nanotubes, graphene, and carbon fibers, or from one or more of conductive carbon black and carbon nanotubes.
12 . The positive electrode plate according to claim 8 , wherein the mass ratio of the binder to the conductive agent is 0.1:2-3:2, or 0.2:2-2.8:2, or 0.5:2-2.5:2.
13 . A secondary battery, comprising an electrode assembly and an electrolyte solution, wherein the electrode assembly comprising the positive electrode plate according to claim 8 , a separator, and a negative electrode plate.
14 . A battery module, comprising the secondary battery according to claim 13 .
15 . A battery pack, comprising the battery module according to claim 14 .
16 . A power consuming device, comprising the secondary battery according to claim 13 .