Positive Electrode Active Material, Positive Electrode Plate, Electrode Assembly, Battery Cell, Battery and Electrical Apparatus
A positive electrode active material includes a low-to-medium nickel ternary material and a high-lattice-volume-change positive electrode material. The low-to-medium nickel ternary material has a mass ratio W1≥45% in the positive electrode active material. The high-lattice-volume-change positive electrode material satisfies: the thickness change rate of the positive electrode active substance layer is ≥2.6%, and the thickness change rate is (H 1 −H 2 )/H 1 , where H 1 is the fully discharged thickness of the positive electrode active substance layer, and H 2 is the fully charged thickness of the positive electrode active substance layer.
1 . A positive electrode active material, comprising:
a low-to-medium nickel ternary material; and
a high-lattice-volume-change positive electrode material;
wherein:
the low-to-medium nickel ternary material has a mass ratio W1≥45% in the positive electrode active material, and the low-to-medium nickel ternary material is LiNi x Co y M1 1−x−y O 2 , wherein 0.5≤x≤0.69, y>0, 1−x−y>0, and M1 is selected from one or more of Al, Mn, Mg, Nb, Ti, and Ba; and
the high-lattice-volume-change positive electrode material satisfies a thickness change rate of a positive electrode active substance layer being ≥2.6%, wherein the thickness change rate is (H 1 −H 2 )/H 1 , wherein H 1 is a fully discharged thickness of the positive electrode active substance layer, and H 2 is a fully charged thickness of the positive electrode active substance layer.
2 . The positive electrode active material according to claim 1 , wherein the high-lattice-volume-change positive electrode material comprises one or more of a high nickel ternary material and a polyanion-type positive electrode material, wherein:
the high nickel ternary material is LiNi m Co n N 1−m−n O 2 , wherein 0.7≤m<1, and N is selected from one or more of Al, Mn, Mg, and Ba; and
the polyanion-type positive electrode material is a lithium iron phosphate material or a lithium manganese phosphate material.
3 . The positive electrode active material according to claim 2 , wherein a chemical formula of the lithium iron phosphate material is LiFe α M2 β PO 4 , wherein α+β=1, 0.2≤α≤1, 0≤β≤0.8, and M2 is selected from one or more of Ti, Mg, V, Cr, Zr, Nb and W.
4 . The positive electrode active material according to claim 3 , wherein a surface of the polyanion-type positive electrode material has one or more electrically conductive cladding layers.
5 . The positive electrode active material according to claim 3 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material and the polyanion-type positive electrode material, wherein a mass percentage W3 of the polyanion-type positive electrode material in the positive electrode active material satisfies: 0<W3≤50%.
6 . The positive electrode active material according to claim 3 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material, the high nickel ternary material, and the polyanion-type positive electrode material, wherein 50%≤W1<100%.
7 . The positive electrode active material according to claim 2 , wherein a chemical formula of the lithium manganese phosphate material is Li 1+e Mn 1−f A f P 1−g R g O 4 , wherein 0.1≤e<1, 0.001≤f≤0.5, 0.001≤g≤0.1, A is selected from one or more of Zn, Al, Na, K, Mg, Mo, W, Ti, V, Zr, Fe, Ni, Co, Ga, Sn, Sb, Nb, and Ge, and R is selected from one or more of B, Si, N, S, F, Cl, and Br.
8 . The positive electrode active material according to claim 7 , wherein a surface of the polyanion-type positive electrode material has one or more electrically conductive cladding layers.
9 . The positive electrode active material according to claim 7 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material and the polyanion-type positive electrode material, wherein a mass percentage W3 of the polyanion-type positive electrode material in the positive electrode active material satisfies: 0<W3≤50%.
10 . The positive electrode active material according to claim 7 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material, the high nickel ternary material, and the polyanion-type positive electrode material, wherein 50%≤W1<100%.
11 . The positive electrode active material according to claim 2 , wherein a surface of the polyanion-type positive electrode material has one or more electrically conductive cladding layers.
12 . The positive electrode active material according to claim 11 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material and the polyanion-type positive electrode material, wherein a mass percentage W3 of the polyanion-type positive electrode material in the positive electrode active material satisfies: 0<W3≤50%.
13 . The positive electrode active material according to claim 11 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material, the high nickel ternary material, and the polyanion-type positive electrode material, wherein 50%≤W1<100%.
14 . The positive electrode active material according to claim 2 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material and the high nickel ternary material, wherein a mass percentage W2 of the high nickel ternary material in the positive electrode active material satisfies: 0<W2≤50%.
15 . The positive electrode active material according to claim 2 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material and the polyanion-type positive electrode material, wherein a mass percentage W3 of the polyanion-type positive electrode material in the positive electrode active material satisfies: 0<W3≤50%.
16 . The positive electrode active material according to claim 2 , wherein the positive electrode active material consists of the low-to-medium nickel ternary material, the high nickel ternary material, and the polyanion-type positive electrode material, wherein 50%≤W1<100%.
17 . A positive electrode plate, comprising a positive electrode current collector and a positive electrode active substance layer disposed on at least one side of the positive electrode current collector, wherein a material of the positive electrode active substance layer comprises the positive electrode active material according to claim 1 .
18 . The positive electrode plate according to claim 17 , wherein the high-lattice-volume-change positive electrode material comprises one or more of a high nickel ternary material and a polyanion-type positive electrode material, wherein:
the high nickel ternary material is LiNi m Co n N 1−m−n O 2 , wherein 0.75 m<1, and N is selected from one or more of Al, Mn, Mg, and Ba; and
the polyanion-type positive electrode material is a lithium iron phosphate material or a lithium manganese phosphate material.
19 . The positive electrode plate according to claim 18 , wherein a chemical formula of the lithium iron phosphate material is LiFe α M2 β PO 4 , wherein α+β=1, 0.2≤α≤1, 0≤β≤0.8, and M2 is selected from one or more of Ti, Mg, V, Cr, Zr, Nb and W.
20 . An electrode assembly, comprising a negative electrode plate, a separator, and the positive electrode plate according to claim 17 disposed in sequence.