BINDER FOR SECONDARY BATTERIES, SEPARATOR, SECONDARY BATTERY AND ELECTRICAL APPARATUS
The present application relates to the technical field of secondary batteries, and more particularly relates to a binder for secondary batteries, a separator, a secondary battery and an electrical apparatus. The binder for secondary batteries is in a ring shape, and includes an acrylate copolymer. The acrylate copolymer has good adhesion, and a contact point of the binder with the ring-shaped structure is a circle line of the ring-shaped binder. The ring-shaped binder has bonding points with larger areas than a spherical binder, such that good bonding performance can be achieved when the usage amount of the binder with the ring-shaped structure is reduced.
1 . A binder for secondary batteries, wherein the binder comprises an acrylate copolymer, and is in a ring shape.
2 . The binder for secondary batteries according to claim 1 , wherein the specific surface area of the binder ranges from 0.4 m 2 /g to 1.2 m 2 /g, and preferably, the specific surface area of the binder ranges from 0.6 m 2 /g to 0.9 m 2 /g.
3 . The binder for secondary batteries according to claim 1 , wherein a surface area to volume ratio of the binder is 0.1×10 6 m −1 to 20×10 6 m −1 , and preferably, the surface area to volume ratio of the binder is 0.5×10 6 m −1 to 16×10 6 m −1 .
4 . The binder for secondary batteries according to claim 1 , wherein the bulk density of the binder ranges from 0.3 g/cm 3 to 0.8 g/cm 3 , and preferably, the bulk density of the binder ranges from 0.4 g/cm 3 to 0.7 g/cm 3 .
5 . The binder for secondary batteries according to claim 1 , wherein the binder is in a circular ring shape.
6 . The binder for secondary batteries according to claim 1 , wherein the volume particle size distribution Dv50 of the binder ranges from 1 μm to 15 μm, and preferably, the volume particle size distribution Dv50 of the binder ranges from 3 μm to 12 μm.
7 . The binder for secondary batteries according to claim 1 , wherein constituent monomers of the acrylate copolymer comprise a first polymerized monomer, and the structure of the first polymerized monomer comprises:
wherein R1 comprises hydrogen or an alkyl group with 1-12 carbon atoms, and R2 comprises an alkyl group with 1-12 carbon atoms.
8 . The binder for secondary batteries according to claim 7 , wherein the first polymerized monomer comprises one or more of methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, tert-butyl acrylate, n-propyl acrylate, cyclohexyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, 2-ethylhexyl methacrylate, isobornyl methacrylate, lauryl methacrylate, 2-hydroxyethyl methacrylate and -2-hydroxypropyl methacrylate.
9 . The binder for secondary batteries according to claim 1 , wherein constituent monomers of the acrylate copolymer comprise a second polymerized monomer, and the structure of the second polymerized monomer comprises:
wherein R3 comprises hydrogen or an alkyl group with 1-6 carbon atoms.
10 . The binder for secondary batteries according to claim 9 , wherein the second polymerized monomer comprises one or more of acrylic acid, methacrylic acid, butenoic acid and heptenoic acid.
11 . The binder for secondary batteries according to claim 1 , wherein constituent monomers of the acrylate copolymer comprise a third polymerized monomer, and the structure of the third polymerized monomer comprises:
wherein R4 comprises hydrogen atoms or an alkyl group with 1-6 carbon atoms.
12 . The binder for secondary batteries according to claim 11 , wherein the third polymerized monomer comprises one or more of acrylonitrile and methacrylonitrile.
13 . The binder for secondary batteries according to claim 1 , wherein constituent monomers of the acrylate copolymer comprise a fourth polymerized monomer, and the structure of the fourth polymerized monomer comprises:
wherein R5 comprises hydrogen atoms or an alkyl group with 1-6 carbon atoms, and R6 comprises hydrogen atoms, a hydroxy-substituted alkyl group with 1-6 carbon atoms, or an alkoxy group with 1-6 carbon atoms.
14 . The binder for secondary batteries according to claim 13 , wherein the fourth polymerized monomer comprises one or more of acrylamide, N-hydroxymethyl acrylamide and N-butoxymethyl acrylamide.
15 . The binder for secondary batteries according to claim 1 , wherein constituent monomers of the acrylate copolymer comprise a first polymerized monomer, a second polymerized monomer, a third polymerized monomer and a fourth polymerized monomer, a mass ratio of the first polymerized monomer, the second polymerized monomer, the third polymerized monomer and the fourth polymerized monomer is 1:(0.01-0.8):(0.01-0.5):(0.01-0.3), and preferably, the mass ratio of the first polymerized monomer, the second polymerized monomer, the third polymerized monomer and the fourth polymerized monomer is 1:(0.1-0.5):(0.15-0.45):(0.1-0.22).
16 . A separator, wherein the separator comprises a substrate and a bonding layer arranged on at least one side of the substrate, and the bonding layer comprises the binder for secondary batteries according to claim 1 .
17 . The separator according to claim 16 , wherein the areal density of the bonding layer on the substrate ranges from 0.7 g/m 2 to 3 g/m 2 , and preferably, the areal density of the bonding layer on the substrate ranges from 0.8 g/m 2 to 2 g/m 2 .
18 . A secondary battery, comprising the separator according to claim 16 .
19 . An electrical apparatus, comprising the secondary battery according to claim 18 .