ALPHA-1,3-GLUCAN GRAFT COPOLYMERS
Compositions are disclosed herein comprising a graft copolymer that comprises: (i) a backbone comprising dextran that has been modified with about 1%-25% alpha-1,2 branches, and (ii) one or more alpha-1,3-glucan side chains comprising at least about 50% alpha-1,3 glycosidic linkages. Further disclosed are reactions for producing such graft copolymers, as well as their use in derivatives, films and various other applications.
1 - 17 . (canceled)
18 . A composition comprising an ether-or ester-derivative of a graft copolymer, wherein said graft copolymer comprises:
(i) a backbone comprising a dextran, and
(ii) one or more alpha-1,3-glucan side chains comprising at least about 50% alpha-1,3 glycosidic linkages.
19 . The composition of claim 18 , wherein the dextran comprises 100% alpha-1,6 glycosidic linkages.
20 . The composition of claim 18 , wherein the weight-average degree of polymerization (DPw) of the backbone is at least about 10.
21 . The composition of claim 20 , wherein the DPw of the backbone is at least about 50.
22 . The composition of claim 21 , wherein the DPw of the backbone is at least about 500.
23 . The composition of claim 18 , wherein the dextran comprises a product of a dextransucrase enzyme that comprises an amino acid sequence that is at least 90% identical to SEQ ID NO:66.
24 . The composition of claim 18 , wherein the dextran comprises a product of a dextransucrase enzyme that comprises an amino acid sequence that is at least 90% identical to SEQ ID NO:67 or SEQ ID NO:68.
25 . The composition of claim 18 , wherein the dextran comprises a product of a dextransucrase enzyme that comprises an amino acid sequence that is at least 90% identical to SEQ ID NO:69.
26 . The composition of claim 18 , wherein the graft copolymer comprises at least two of said alpha-1,3-glucan side chains.
27 . The composition of claim 26 , wherein the graft copolymer comprises at least three of said alpha-1,3-glucan side chains.
28 . The composition of claim 27 , wherein the graft copolymer comprises at least four of said alpha-1,3-glucan side chains.
29 . The composition of claim 18 , wherein the alpha-1,3-glucan side chains comprise at least about 90% alpha-1,3 glycosidic linkages.
30 . The composition of claim 26 , wherein the alpha-1,3-glucan side chains comprise at least about 90% alpha-1,3 glycosidic linkages.
31 . The composition of claim 18 , wherein the DP or DPw of said one or more alpha-1,3-glucan side chains is at least about 10.
32 . The composition of claim 26 , wherein the DP or DPw of said at least two alpha-1,3-glucan side chains is at least about 10.
33 . The composition of claim 18 , wherein the composition comprises the ether-derivative of the graft copolymer.
34 . The composition of claim 18 , wherein the composition comprises the ester-derivative of the graft copolymer.
35 . The composition of claim 18 , wherein the composition is a household care product, personal care product, industrial product, pharmaceutical product, or food product.
36 . The composition of claim 18 , wherein the composition is a detergent composition.
37 . The composition of claim 18 , wherein the composition is a dishwashing detergent composition.
38 . The composition of claim 37 , wherein the dishwashing detergent composition is an automatic dishwashing detergent composition.
39 . The composition of claim 18 , wherein the composition is a fabric care composition.