POWER STORAGE DEVICE AND METHOD OF MANUFACTURING THE POWER STORAGE DEVICE
A power storage device includes a current collecting terminal, a case member having a terminal insertion hole, and an insulating resin member connecting the current collecting terminal with a hole periphery and a hole surrounding portion of the terminal insertion hole. The current collecting terminal and the case member have seal portions that ensure airtightness in a case, at connecting portions connecting with the insulating resin member, and each of the seal portions is a roughened surface. The insulating resin member has a thermoplastic resin material including high molecular weight particles with a molecular weight of 10,000 or more and low molecular weight particles with a molecular weight of 500 to 5,000, and the low molecular weight particles are included 5 to 15% by weight in the thermoplastic resin material and are unevenly distributed closer to the roughened surface.
1 . A power storage device comprising:
a current collecting terminal;
a case member having a terminal insertion hole through which the current collecting terminal is inserted; and
an insulating resin member that is molded with the current collecting terminal and the case member inserted, and is configured to connect a hole insertion portion of the current collecting terminal with a hole periphery and a hole surrounding portion of the terminal insertion hole,
wherein the current collecting terminal and the case member have seal portions that ensure airtightness in a case, at connecting portions that connect with the insulating resin member,
wherein each of the seal portions is a roughened surface on which an uneven surface is formed,
wherein the insulating resin member has a thermoplastic resin material including high molecular weight particles with a molecular weight of 10,000 or more and low molecular weight particles with a molecular weight of 500 to 5,000, and
wherein the low molecular weight particles are included 5 to 15% by weight in the thermoplastic resin material, and are unevenly distributed closer to the roughened surface.
2 . The power storage device according to claim 1 , wherein:
the uneven surface is formed with an arithmetic mean roughness of 30 to 500 nm; and
a resin surface layer adjacent to the uneven surface has an increased amount of the low molecular weight particles with a molecular weight of 500 to 1,500, as compared with a resin internal layer remote from the uneven surface.
3 . A method of manufacturing the power storage device according to claim 1 , using a molding die for injection molding the insulating resin member with the current collecting terminal and the case member inserted, the method including
injecting the insulating resin member into gaps between projections on the uneven surface, before injection of the molten insulating resin member into a cavity of the molding die is completed.
4 . A method of manufacturing the power storage device according to claim 2 , using a molding die for injection molding the insulating resin member with the current collecting terminal and the case member inserted, the method including
injecting the insulating resin member into gaps between projections on the uneven surface, before injection of the molten insulating resin member into a cavity of the molding die is completed.